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Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


Residual CCA levels in CCA treated poles removed from service
2000 - IRG/WP 00-50152
Fifty-two CCA treated poles removed from service after 1 - 50 years were sampled at different depths from their below ground and above ground zones and the preservative levels and mass balances related to the location in the pole and pole age. Generally CCA retentions were still well above the toxic threshold for decay in even the oldest poles. This confirms the good leach resistance of CCA and th...
P A Cooper, D Jeremic, J L Taylor


Leachability of active ingredients from some CCA treated and creosoted poles in service. A progress report after 10 years testing
1990 - IRG/WP 3627
CCA K33 TYPE B treated or creosoted poles, 10 pieces of each treatment type, have been monitored from the treatment plant to an electricity line, which was build up in Southern Finland in 1978. Preservative retention was determined by taking borings at four different levels: 1.5 m from the top end, 1 m above ground line, ground line and 0.5 m below ground. Determinations were made before setting u...
A J Nurmi


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Use of the enzyme-linked immunoassay (ELISA) and immunocytochemistry to detect soft rot in preservative treated and untreated wood
1990 - IRG/WP 2347
A polyclonal antibody was raised against mycelial extracts from the soft rot fungus Phialophora mutabilis. In ELISA assays, the antibody showed strong reactions with its own antigen and strong to moderate cross reactions with 6 other Phialophora soft rot species. With the exception of Ceratocystis albida, the antibody gave only weak or negative reactions with 11 other mold, blue stain and rot fung...
G F Daniel, T Nilsson


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


The results of detection on CCA components of the soils contacted with CCA-treated woods - A trial study for the availability of the burial Method as a disposal CCA treated wood waste
1993 - IRG/WP 93-50005
The objecteve of this experiment is to get a knowledge that, when CCA treated wood wastes were buried in a soil as a disposal, the soil would be or not be contaminated by the components of CCA preservatives in wood wastes. The specimens used were cutting logs and chips made of the CCA treated electric pole waste. The soil was buried to the 15 cm depth and the log specimens were set in the soil for...
K Suzuki, H Sonobe


Variation in field test performance of untreated and CCA-treated lesser-known Surinamese wood species
2000 - IRG/WP 00-20213
In Suriname three different field test sites have been used to verify the biological durability of CCA-treated wood and a range of wood species including lesser-known and lesser-used wood species. In total 37 tropical wood species were tested untreated and for 17 of the less durable species CCA-treatments were included as well. Although the three sites are located in the tropical region they diffe...
J Van Acker, M Stevens, L Comvalius


Performance of Preservative Treated Parallel Strand Lumber in Marine Exposures.
2006 - IRG/WP 06-30407
The performance ACZA treated Douglas-fir and CCA southern pine parallel strand lumber (PSL) was studied in marine exposures in Florida or Oregon. While materials treated to retentions below the recommended levels for marine exposure were attacked in Oregon, properly treated panels of either species performed well. Panels treated with these same chemicals and exposed in Florida experienced attack ...
J J Morrell, C S Love, P Merrick


Exposure of CCA and ACZA treated parallel strand lumber to marine borer attack in northeastern and southeastern waters of the United States of America
2006 - IRG/WP 06-30400
Southern pine and Douglas fir Parallel Strand Lumber (PSL) panels were treated with chromated copper arsenate (CCA) or ammoniacal copper zinc arsenate (ACZA), respectively and exposed in a marine environment in Massachusetts (northeastern USA coast) for 7 years. Similarly treated panels were also exposed to a site on the Atlantic coast Florida (southeastern USA) for the same period. In the northe...
B Goodell, P Merrick, J Jellison, Y Qian


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Laboratory Leaching Tests to Study the Effects of Post-Treatment Storage Periods on CCA Leachability and Fixation in Treated Permeable and Refractory Malaysian Hardwoods
2006 - IRG/WP 06-50240
The biological resistance and environmental safety of CCA-treated wood relies on the extent of post-treatment storage fixation of CCA in wood prior to being utilized. A study on the comparative leachability (fixation) of CCA-treated refractory and permeable heartwoods of 3 Malaysian hardwoods subjected to different post-treatment storage (fixation) periods of up to 4 weeks, at 2 laboratory leachin...
A H H Wong, H C Lai, N P T Lim


A Prediction of Arsenic Groundwater Concentrations Influenced by Construction and Demolition Debris Landfills in Florida Containing CCA-Treated Wood
2006 - IRG/WP 06-50242
Groundwater fate and transport models can provide an indication of the potential impacts of arsenic from the infiltration of leachate from unlined C&D debris landfills containing CCA-treated wood. A solute transport model, Migration of Organic/Inorganic Chemicals (MYGRT), was chosen to predict groundwater contaminant concentrations at specified locations from a hypothetical source (C&D lan...
J Jambeck, T Townsend, H Solo-Gabriele


Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai


Relationship between coating properties and their performance on treated wooden decks
2008 - IRG/WP 08-30454
Preservative treated wood benefits from the application of a surface coating to protect it from weathering (UV and rain). Different preservative formulations may affect surface properties of treated wood differently; therefore compatibility of coatings with different preservative treated wood types should be considered. This paper examines coatings characteristics and their weathering performance ...
M Ahmadinejad, P A Cooper


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Barefoot-heat-impact of oil-heat-treated wood: An important thermal property of decking boards
2009 - IRG/WP 09-40458
In this study the phenomenon of sensual heat impression was examined, when walking with bare feet on sun exposed wood based decking boards. A suitable method for measuring the heat flux from decking boards into an artificial foot was developed. The method and measuring device is described as well as results from measuring three different decking board materials: Oil-heat-treated spruce (OHT), untr...
A O Rapp, C R Welzbacher, C Brischke


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