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The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Natural durability transfer from sawmill residues of white cypress (Callitris glaucophylla). - Part 4: Analysis of extracts and treated wood for active components
2000 - IRG/WP 00-20215
In order to facilitate the commercial implementation of a large project aimed at recovering 'waste' durability components from sawmill residues of Callitris glaucophylla, it has been essential to develop analytical methodology for the important bioactive components of the heartwood extract. This methodology will be used 1) to standardise the activity of successive production batc...
Hui Jiang, M J Kennedy, L M Stephens


Effect of climate, species, preservative concentration and water repellent on leaching from CCA-treated lumber exposed above ground
2001 - IRG/WP 01-50178
Few studies have examined leaching of chromated copper arsenate (CCA) from treated wood in above ground exposures due to the assumption that leaching is less severe compared to wood in continuous contact with soil or water. However, a significant portion of CCA treated wood is used for above ground applications, exposing considerable volumes of the preservative to precipitation and potential leach...
J L Taylor, P A Cooper


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 6: The length of the primary precipitation period
1975 - IRG/WP 359
The end of the primary precipitation fixation period of CCA preservatives coincides with the first peak in pH versus time. This offers a simple way of estimating the duration of the period. The duration is determined by a number of factors and their interactions, the most important of which are: wood species (anatomy, natural pH, accessibility of reducing agents), preservative type, preservative c...
S-E Dahlgren


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


The use of preservative containing waste wood as substrate for growing greenhouse crops
1993 - IRG/WP 93-50011
In the Netherlands a large amount of waste wood and wood waste is produced every year. An important part of this amount comes from the pallet and packaging industries. One of the possibilities to re-use this relatively clean material is to convert it into substrates for growing crops in glass houses instead of the commonly used materials such as rock wool and glass wool. In this research, the infl...
W J Homan,H Militz


Test methods for wood preservatives against Lyctus: (1) Testing of treated veneer. (2) Testing of glue-line treated plywood. (Laboratory methods)
1977 - IRG/WP 293
Powder-post beetles destroy large quantities of veneer and plywood. Two test procedures are described which can be used to support application-oriented research into veneer and plywood preservatives. These procedures simulate practical conditions on a laboratory scale. Their characteristic feature is that wood species of special susceptibility are used for the tests; the susceptibility of the spec...
S Cymorek


Aboveground Microbial Decay Test of Biocide Treated and Untreated Wood Exposed to Danish and Humid Tropical Climates
2004 - IRG/WP 04-20306
A co-operative study was initiated to compare the aboveground field decay test of untreated and preservative-treated timbers under Nordic (Danish) and a representative humid tropical (Malaysian) environment according to CEN standard method. Matched specimens of untreated and both preservative-impregnated and surface-treated wood were simultaneously exposed at The Danish Technological Institute (DT...
A H H Wong, N Morsing, K H Henriksen, S Ujang


Difference of CCA efficacy among coniferous wood species
1990 - IRG/WP 3601
Wood blocks of Cryptomeria japonica, Tsuga heterophylla, and Pinus radiata successively extracted with n-hexane, ether, and methanol were treated with various concentrations of CCA type 3, which were subjected to the decay by Tyromyces palustris. The weight loss were different among species and kinds of extraction. Cryptomeria japonica treated with CCA had higher fungal resistance than Tsuga heter...
K Yamamoto, M Inoue


Status of wood preservation industry in India
2005 - IRG/WP 05-30388
The paper traces the history of wood preservation industry in India, listing various mile stones for creation of treating capacity. The preservation industry developed with the development of rail road system on the line of most other developed countries. The most popular wood preservatives are CCA, CCB, ACC, Creosote and recently LOSP have also appeared in the market. The major users of CCA is th...
S Kumar


The difficult choice of the preservation industry when changing to more environmentally acceptable products
2000 - IRG/WP 00-50156
Until recent years the preservation industry in Norway had no problems with the environmental authorities. However, during the last three years the pressure has increased, and the authorities' solution to restrict hazardous chemicals is to introduce green (environmental) taxes for the products containing these chemicals, and also for the pressure-treated wood. The preservation industry ac...
F G Evans


Settlement of fouling organisms on CCA-treated Scots pine in the marine environment
1997 - IRG/WP 97-50094
As part of an EU project to investigate the effects of CCA loading on non-target marine fouling animals, exposure panels of Scots pine treated to 12, 24 and 48 kgm-3 CCA and untreated controls were submerged at seven coastal sites (Portsmouth, UK: Kristineberg, Sweden: La Tremblade (2 sites), France: Ria Formosa, Portugal: Sagres, Portugal: Athens, Greece). Inspections were made at 6 and 12 months...
C J Brown, R A Eaton


Fundamentals on steam fixation of chromated wood preservatives
1988 - IRG/WP 3483
Weathering of treated wood directly after impregnation leaches up to 2% of copper-chromate-containing wood preservatives. Almost total fixation of Cr+6 is achieved by steaming the treated wood at 100°C to 120°C, preferably 110°C. To initiate such spontaneous fixation 85°C to 90°C inside the wood are essential, which requires heating times ranging from 20 to 80 min, depending on timber species...
R-D Peek, H Willeitner


Solidification - A viable option for the safe disposal of CCA treatment plant wastes
1993 - IRG/WP 93-50001-21
Treatment plant operations generate small quantities of waste materials contaminated with wood preservatives - for example, sludges, contaminated sawdust, yard dirt. A practical system involving the immobilisation of such wastes has been established to assist the operators to safely dispose to landfill sites. The results of cold water and hot dilute acid leaching regimes are described, which simul...
M R Gayles, D Aston


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski


Field evaluation of the above-ground susceptibility of Pinus heartwood and untreated or treated sapwood to two species of Australian subterranean termites
1996 - IRG/WP 96-10147
Plantation-grown Pinus elliottii, Pinus caribaea and Pinus radiata specimens containing heartwood and untreated or preservative-treated sapwood were exposed above ground to the subterranean termites Coptotermes acinaciformis or Mastotermes darwiniensis near Sydney (NSW), Brisbane and Townsville (Qld), and Darwin (NT), using a variety of exposure techniques. Heartwood of Pinus elliottii and Pinus c...
M J Kennedy, J W Creffield, R H Eldridge, B C Peters


Determination of boron levels in solution and in treated wood
1994 - IRG/WP 94-20041
Four methods of measuring boron levels in solutions were investigated. The methods compared included the azomethine-H method which is commonly used in soils and plant tissues, the methods outlined in the Australian Standard AS 1605 (1974) and in Wilson (1958), and the atomic absorption spectrophotometry method. Defect-free radiata pine (Pinus radiata D. Don) sapwood and wood flakes were treated to...
F J Romero, P Vinden, P Kho


Patterns of decay in CCA-treated horticultural post populations - A fungus cellar simulation
1986 - IRG/WP 1286
The distribution of decayed posts in 10-, 14-, and 18-year-old vineyards supported a hypothesis to explain variability in intensity of decay found among posts in New Zealand horticultural properties. The development of decay patterns between samples in a simulated vineyard plot established in the Forest Research Institute fungus cellar gave additional support to the hypothesis that decay within la...
M E Hedley


Premature failure of CCA treated vineyard posts from brown rot
1993 - IRG/WP 93-10016
A survey of CCA (AWPA Type C) treated posts used as grape vine trellis supports, to determine the extent and type of decay was carried out at a terraced vineyard in the Hawkes Bay region of the North Island of New Zealand. Of 357 posts examined out of a total of 970 in the vineyard, 47% had moderate to severe decay or had failed, 20% had established decay, 10% had a trace of decay and 23% had no s...
R N Wakeling, A P Singh


A soil-less test of treated wood
1978 - IRG/WP 2105
The objective of this work is to devise an accelerated test for preservatives to be used in places away from soil contact. There may be compounds or mixtures which will protect wood or wood derived materials from decay in such articles as sash and doors, boardwalks, steps, laminated arches and the like, and possess properties that make them preferable to the heavy-duty preservatives used for poles...
E A Behr


Status of Work on OECD Test Guidelines for Emissions of Wood Preservatives to the Environment
2005 - IRG/WP 05-50224-3
In April, 2003, OECD published an ESD on wood preservatives that provides guidance on how to estimate emissions: 1) during the wood preservative application processes and storage of treated wood prior to shipment; and 2) from treated wood-in-service. The ad hoc Expert Group that developed the wood preservatives ESD identified the need to develop Test Guidelines to estimate the amount of biocides ...
W Jakob


Influence of acidification on decay processes of CCB treated wood
2004 - IRG/WP 04-10514
The phenomenon of copper tolerance by brown rot fungal strains has been known for a long period but the complete mechanism of copper tolerance by these fungi is not understood yet. Copper tolerance has previously been linked to oxalic acid excreted by copper tolerant brown rot fungal strains. This acid reacts with copper in the wood to form an insoluble and therefore less toxic copper oxalate. The...
M Humar, S A Amartey, M Šentjurc, F Pohleven


Durability aspects of (hydro)thermal treated wood
2000 - IRG/WP 00-40160
Samples of several wood species were treated in a two steps process, subsequently hydrothermal and dry heat-treated, by the so-called PLATO-process and analysed for their resistance against fungal attack. Both PLATO-treated and dry heat-treated specimen were prepared and analysed, in order to study the influence of moisture during hydrothermal treatment of wood. The resistance against all of the s...
B F Tjeerdsma, M Stevens, H Militz


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