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An alternative method for the determination of lignocellulolytic enzymatic activities of white rot fungi
1998 - IRG/WP 98-10261
Some lignocellulolytic activities of wood decay fungi can be evaluated in an indirect way through the study of the decolorization that white rot fungi produces in culture media in the presence of dyes. In this assay, ten dyes were selected, which were added in concentrations of 0.00 1% - 0.003% (P/V) to four-day cultures of Trametes versicolor containing 1% of beech sawdust in a basal salt medium...
D Muñoz-Mingarro, F Llinares, F Rubio, M Yuste, C Rodríguez-Borrajo, J Jiménez, M T De Troya


Analysis of volatile organic compounds (VOC's) from Trichoderma spp.: effect of media composition on VOC production and level of inhibition of wood decay fungi
1997 - IRG/WP 97-10207
Production of volatile organic compounds (VOC's) by two Trichoderma isolates grown on either malt extract or minimal media was examined and statistically assessed to identify which VOC's were predominantly produced on each of the two media types. The VOC's were captured onto chromatographic absorbent from above the cultures of the fungi before being analysed by integrate...
A Bruce, R E Wheatley, C Hackett, A Kundzewicz


Environmentally benign wood preservatives based on organic biocide antioxidant combinations: A brief review of laboratory and field exposure results and discussion of a proposed mechanism
2004 - IRG/WP 04-30335
The combination of various organic biocides with commercial antioxidants generally increased the biocides’ efficacy 2-3 fold against wood-destroying fungi in short-term laboratory decay tests, and some positive results have been obtained after 2-4 years of outdoor exposure. The two antioxidants principally examined, propyl gallate and butylated hydroxytoluene, are low cost and, since both are f...
T Schultz, D D Nicholas, W Henry, C Pittman, D Wipf, B Goodell


Performance of copper-chrome formulations in ground contact in five test sites in New Zealand
1996 - IRG/WP 96-30113
Copper-chrome-arsenate (CCA), copper-chrome-boron (CCB), copper-chrome-fluoride (CCF) and copper-chrome-phosphate (CCP) have been tested at four retentions each in ground contact (25 x 50 x 500 mm³ radiata pine sapwood stakes) for 16 years in five test sites in New Zealand. Results to date show that test site characteristics have a marked effect on relative performance. In a warm and wet site (an...
M E Hedley, R N Wakeling, J Foster, B E Patterson


Defacement of freshly sawn Corsican pine lumber by sapstain and mould fungi and the influence of arthropods
1997 - IRG/WP 97-10227
In a trial to study the arthropods associated with sapstain and mould fungi, freshly sawn Corsican pine (Pinus nigra var. maritima (Aiton) Melville) boards were block stacked at a local sawmill. Each stack was constructed in a nest arrangement with smaller boards in experimental tanks, positioned in the centre of the stacks. Boards were converted from a stock of sawlogs at monthly intervals, to pr...
N J Strong, J F Webber, R A Eaton


Properties of particleboard made from recycled CCA-treated wood
2000 - IRG/WP 00-50146
Recovery of chromated copper arsenate (CCA)-treated wood for reuse ha s been the focus of several international research groups due to the imminent disposal problem created when large quantities of CCA-treated wood ultimately come out of service. Bioleaching with Bacillus licheniformis CC01 and oxalic acid extraction are two methods known to remove significant quantities of metals from CCA-treated...
C A Clausen, S N Kartal, J H Muehl


The potential application of rapid gas-chromatographic assay of microbial respiration to the monitoring of wood decay in field trial situations
1983 - IRG/WP 2196
Gas chromatographic detection of microbial activity (C02 production) within stakes in a field trial situation would appear to provide a sensitive, non-destructive and relatively rapid method for the quantitative assessment of preservative treatments. Most consistent results were obtained when stakes were removed from the soil, washed, saturated with water and incubated in sealed PVC tubes at 25°C...
M A Line


Differences and their causes of CCA and CCB efficacay among some softwoods and hardwoods
1991 - IRG/WP 3656
Wood blocks from two softwoods and two tropical hardwoods species treated with different concentrations of CCA, CCB, and combinations of CrO3, CuS04, H3BO3 were subjected to the decay by brown rot fungus, Tyromyces palustris. CCA maintained good effect both in softwoods and hardwoods, while CCB and the other combinations lost their effectiveness after leaching. Chemicals leached from CCA treated w...
K Yamamoto, M Rokova


The efficacy of preservatives into the glue-line of plywood
1993 - IRG/WP 93-30002
This research is anti-termite/decay preservatives mixed with resin to produce the plywood. Thereafter, anti-decay/termite plywood were produced by the ordinary methods. To produce suitable plywood in the utilization and certified performance, the preservatives should be 0.3 to 0.4 kg/m³ of Chlorpyrifos; 0.88 and 1.10 kg/m³ of mix preservatives of Chlorpyrifos + IF-1000. Laboratories decay test (...
S Fushiki, T Saito, Y Katuzawa, Y Imamura, S Yusuf, B Subiyanto


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


Preliminary results from the field experiment to determine the performance of preservative treated hardwoods with particular reference to soft rot. The four reference timber
1980 - IRG/WP 3164
The results given in the Tables 1-4 each refer to one of the four reference species treated with four solution concentrations of CCA as recorded from each test site. The species are: Alstonia scholaris, Betula pendula, Fagus sylvatica, Pinus sylvestris. The treatments were: Untreated, 0.66% CCA, 1.53% CCA, 3.01% CCA, 5.60% CCA. Each figure is an average of the ratings recorded for each replicate o...
J F Levy, D J Dickinson


Hardwood Field Experiment: Progress Report 1977-1986
1986 - IRG/WP 3391
The international hardwood field experiment was planned in l976 and set up in same 30 different sites around the world. The test stakes include 4 reference species common to each site and in most cases at least 2 species of local importance. It was hoped that a picture of performance of a range of economically important species would be built up and at the same time provide vital background inform...
D J Dickinson, S M Gray


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Effect of Pseudomonas cepacia on the activity of a mixture of wood staining fungi on ponderosa pine sapwood
1995 - IRG/WP 95-10107
There are major incentives for limiting the degree of fungal discoloration which occurs during wood processing. Most lumber producers apply prophylactic fungicides which limit microbial growth, but increasing restrictions on the use of these chemicals have encouraged the search for alternative stain prevention strategies. Among the possible strategies for stain prevention is biological control. Wh...
J J Morrell, R K Velicheti


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


Database of sapstain fungi affecting lumber, logs and trees
2004 - IRG/WP 04-10534
Sapstain fungi discolour lumber, logs and tree sapwood and are often mistaken for moulds, which cause a superficial discoloration. Stained wood has a lower market value. Further, because stained wood products can potentially carry pathogenic fungi, such products may be refused by importing countries. Addressing these issues involves developing ways for accurately identifying staining fungi, docume...
S Lee, F de Giuli Vallverdu, S Alamouti, Jae-Jin Kim, A Uzunovic, C Breuil


The production of extracellular hydrogen peroxide by some brown-rot fungi
1990 - IRG/WP 1446
The role of hydrogen peroxide (H2O2) has been discussed in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by detecting the oxidation of the chromogen 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horse radish peroxidase (HPR). ABTS and HPR were added to a solid wood based culture media. In this study ...
A-C Ritschkoff, L Paajanen, L Viikari


The effects of preservative treatment and exposure to wood degrading fungi on fiber reinforced polymer (FRP) materials used for structural wood reinforcement
2001 - IRG/WP 01-40204
Glass fiber reinforced phenolic (GFRP) composite materials are becoming increasingly accepted for use in the construction industry because they combine advantages of both wood and advanced polymeric materials. Addition of only 1-3% FRP in the tension zone, for example, can typically improve the strength of the hybrid system by 200%. As more applications are found for wood/FRP hybrids, (e.g. lamina...
C Tascioglu, B Goodell


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


A laboratory evaluation of tributyltin ethanesulphonate as an aqueous fungicide in wood preservation
1983 - IRG/WP 3229
Toxic limit data, using both leached and unleached wood test blocks, are reported for aqueous solutions of tributyltin ethanesulphonate against four Basidiomycete fungi, Poria placenta, Gloeophyllum trabeum, Coriolus versicolor and Coniophora puteana. An in situ study of the tributyltin compound in Scots pine and ponderosa pine sapwood has been carried out, using the technique of 119mSn Mössbauer...
R Hill, P J Smith, J N R Ruddick, K W Sweatman


Evaluation of the efficiency of industrial kiln type CCA fixation chambers
1996 - IRG/WP 96-40063
Six commercial CCA treating plants in Canada were assessed for the fixation efficiency of their hot air fixation chambers. The wood temperature was measured with thermocouples over the fixation period at different locations in the chamber and at the end of the fixation cycle, the degree of chromium fixation was determined by a boring leaching procedure. There was a great variation in the effective...
A Taylor, P A Cooper


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