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Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Laboratory Leaching Tests to Study the Effects of Post-Treatment Storage Periods on CCA Leachability and Fixation in Treated Permeable and Refractory Malaysian Hardwoods
2006 - IRG/WP 06-50240
The biological resistance and environmental safety of CCA-treated wood relies on the extent of post-treatment storage fixation of CCA in wood prior to being utilized. A study on the comparative leachability (fixation) of CCA-treated refractory and permeable heartwoods of 3 Malaysian hardwoods subjected to different post-treatment storage (fixation) periods of up to 4 weeks, at 2 laboratory leachin...
A H H Wong, H C Lai, N P T Lim


Leaching of CCA from Paraserianthus falcataria panels exposed to field conditions at Krishnapatnam harbour, Andhra Pradesh
2006 - IRG/WP 06-50241
This study assessed the leaching of copper, chrome and arsenic (CCA) from Paraserianthus falcataria (=Albizia falcataria) panels exposed to marine condition at Krishnapatnam harbour on the east coast of India. Metal loss was assessed in test panels after 6, 12, 24 and 36 months of exposure using Atomic Absorption spectrophotometer (AAS). The metal loss was found slightly higher in panels treated ...
B Tarakanadha, K S Rao


A Prediction of Arsenic Groundwater Concentrations Influenced by Construction and Demolition Debris Landfills in Florida Containing CCA-Treated Wood
2006 - IRG/WP 06-50242
Groundwater fate and transport models can provide an indication of the potential impacts of arsenic from the infiltration of leachate from unlined C&D debris landfills containing CCA-treated wood. A solute transport model, Migration of Organic/Inorganic Chemicals (MYGRT), was chosen to predict groundwater contaminant concentrations at specified locations from a hypothetical source (C&D lan...
J Jambeck, T Townsend, H Solo-Gabriele


An Investigation of the use and Durability of some Industrial and Domestic woods of Iran against Destructives factor in Caspian Sea
2007 - IRG/WP 07-10613
Use of domestic and commercial woods of the Caspian Sea forest fringes and evaluation of their durability against marine destructive factors were investigated. The samples of species of elm (Zelkova carpinifolia), oak (Quercus castanifolia), beech (Fagus orientalis), Maple (Acer insgin), Alder (Alnus subcordata), and horn beech (Carpinus betulus) were impregnated with CCA (Chrome–Cupper-Arsenic)...
S M Kazemi


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Eucalyptus saligna and Acacia mearnsii
2007 - IRG/WP 07-40383
Penetration, retention, and leaching of CCA (C) in relation to grain orientation were tested in small (50mm x 50mm x 200mm) sapwood and heartwood samples of Eucalyptus saligna and Acacia mearnsii. In both sapwood and heartwood of the two species, the results showed a consistent pattern: Transverse > Radial > Tangential. Whereas penetration, retention, and leaching were significantly high i...
R Venkatasamy


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Cupressus lusitanica and Pinus patula
2007 - IRG/WP 07-40384
The influence of grain orientation on penetration, retention, and leaching of CCA (C) was tested on small samples of sapwood and heartwood of Cupressus lusitanica and Pinus patula. Samples measuring 50mm x 50mm, and 200mm in the longitudinal axis were sealed to expose only transverse, or radial, or tangential faces, pressure treated with 6% CCA (C), and penetration, retention and leaching of the ...
R Venkatasamy


Antifungal activity of plant derived extracts against G. trabeum
2007 - IRG/WP 07-30433
While synthetic chemicals have provided excellent protection to woods used in adverse environments, the general public remains interested in naturally derived wood protectants. There are diverse arrays of possible candidates, but many of these compounds are not readily water soluble and efforts to render them soluble often reduce biological activity. In this report, we describe efforts to enhance ...
M Maoz, I Weitz, M Blumenfeld, C Freitag, J J Morrell


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai


Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo


An Investigation on Use and Durability of Some Industrial and Domestic Woods of Iran against Destructive Factors in Caspian Sea
2008 - IRG/WP 08-10636
In this study the use of domestic and commercial woods of the Caspian Sea forest fringes and evaluation of their durability against marine destructive factors were investigated. The samples of elm (Zelkova carpinifolia), oak (Quercus castanifolia), beech (Fagus orientalis), Maple (Acer insgin), Alder (Alnus subcordata), and horn beech (Carpinus betulus) species were impregnated with CCA (Chrome–...
S M Kazemi


Relationship between coating properties and their performance on treated wooden decks
2008 - IRG/WP 08-30454
Preservative treated wood benefits from the application of a surface coating to protect it from weathering (UV and rain). Different preservative formulations may affect surface properties of treated wood differently; therefore compatibility of coatings with different preservative treated wood types should be considered. This paper examines coatings characteristics and their weathering performance ...
M Ahmadinejad, P A Cooper


Validity of above ground testing according to ENV 12037
2008 - IRG/WP 08-20379
The standard ENV 12037 for testing of treated and untreated wood (lap-joint) exposed above ground was issued in 1996 by The European Committee for Standardization. A draft for the development of the standard was presented by CEN-TC 38/WG 25/DOC N 076 in 2002. For a test to become valid the median rating of decay for untreated control replicates (Scots pine sapwood) must be equal or greater than ...
Ö Bergman, U Råberg, N Terziev


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Effect of CCA and Tanalith E on the performance of surface finishing
2008 - IRG/WP 08-40405
Effect of CCA and Tanalith E treatment on the performance of surface finishing properties was the objectives of this study. Sapwood of scots pine, (Pinus sylvestris L.) and oriental beech (Fagus orientalis Lipsk.) specimens (300 x 100 x 15 mm along the grain) were impregnated with aqueous solution of CCA 2% and Tanalith E 2%. Surface roughness, dry film thickness, adhesion strength, gloss measur...
T Ozdemir, A Temiz, I Aydin


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Utilidad práctica de mini estacas en ensayos de campo
2009 - IRG/WP 08-20395
For testing chemicals for the wood against degradation agents of biotic, known as preservatives, both testing in the laboratory and in the fields are used. Field trials (Cemetery stakes) are often accepted as more "real" whose frequency of observation is set to more or less a year in temperate climates and six months or less in tropical situations, taking into accounts the aggressiveness of the so...
O Encinas, J V Puentes, N K Sarmiento, N Mora


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Impregnación de durmientes de quebracho blanco (Aspidosperma quebracho blanco) con preservadores cromocuproarsenicales (CCA)
2008 - IRG/WP 08-40428
CCA impregnation of railroad ties is a recent process in Argentina which has not been optimized in a commercial scale. This study analyzed the influence of treatment pressure on final retentions to optimize the impregnation process. Results showed that a 3.2% m/v solution resulted in 10.8 kg/m3 CCA retention. At 1187 kPa (12 kgf/cm2) quebracho blanco wood had an average absorption of 338 l/m3. Als...
D Gherscovic, Z Cataldi, J M Languasco


Rehabilitación del Portón del templo parroquial de San Juan Vicario de Comanja, Michoacán, México
2008 - IRG/WP 08-40431
The pine gate of the San Juan Vicario parochial temple in the city of Comanja, Michoacan, Mexico was rehabilitated. The gate was damaged by termites, worms, fungi and weathering. Gate metallic bearings were rusted. The lower parts of the gate were the most deteriorated. For rehabilitation, galvanized steel bearings were designed and manufactured and then implemented into the building. Replacement ...
J Reséndiz Sánchez, J Cruz de León


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