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Effect of treating process on efficacy of CCA in a laboratory decay test
1990 - IRG/WP 3628
Test samples of Pinus radiata sapwood measuring 40x40x500 mm³ were treated with a range of concentrations of the copper-chrome-arsenate (CCA) formulation "Tanalith C" using Rueping (empty cell), Lowry (empty cell) and Bethell (full cell) treatment processes. Samples were then reduced to 40x40x7 mm³ test blocks and exposed to the decay fungus Coniophora puteana using an agar/block technique. Repl...
M E Hedley, K Nasheri, J G Van der Waals


Potential toxicants for controlling soft rot in preservative treated hardwoods. Part 1: Laboratory screening tests using a filter paper technique
1977 - IRG/WP 290
Thirty-one miscellaneous formulations have been screened using a filter paper assay technique, for their efficacy in controlling the growth of Chaetomium globosum, Cephalosporium acremonium, and a mixed inoculum of finely ground soft-rotted wood obtained from preservative treated transmission poles. The formulations consisted of various organic compounds and inorganic preparations made from differ...
H Greaves


Alternatives to CCA for ground contact protection of timber: a perspective from UK on performance and service life expectations
2002 - IRG/WP 02-30289
The proposed amendment to the European Union's Marketing and Use Directive (1976/769/EEC) in respect of arsenic in CCA wood preservatives seeks to restrict the use of CCA across the European Union. CCA is an extremely important wood preservative in the UK from the manufacturing of the product to the extent of use of CCA-treated timber. Based on our experience and judgement on the use of ...
E D Suttie, A F Bravery, T B Dearling


Studies on the preservative treatment of round bamboos by a new technique
1989 - IRG/WP 3536
Nature has offered a versatile and cheap material bamboo, which is generally found to grow principally in forest areas from sea level to about 400 m wherever suitable combination of ecological factors prevail. This potential renewable natural resource has been since times immemorial, exploited by mankind for a variety of purposes specially in developing countries like Asia, Africa and South Americ...
V R Sonti, S Sonti, B Chatterjee


Determination of ethanolamine in impregnated wood
2000 - IRG/WP 00-20198
Leaching of copper based preservatives from wood is usually prevented by adding chromium compounds to copper containing formulations. It seems that suitable substitutes for chromium fixation agents may be amines. In this paper, we report our results on interactions between copper(II) octanoate and ethanolamine (C2H7NO, 2-aminoethanole) with wood or its components. A part of ethanolamine from a woo...
M Humar, M Petric


The non-uniform uptake of chromium and copper during the impregnation of wood using the example of a CCB-salt
1998 - IRG/WP 98-20137
The correct impregnation of wood requires among other things a regular control of the concentration of the treating solution as this and/or its stoichometric composition can change as a result of the impregna-tion process and the treated wood. The preferential uptake of individual wood preservative components by the wood is of particular importance in this connection. Dipping and vacuum impregnat...
P Jüngel, E Melcher, R-D Peek


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Solvent extraction of CCA-C from out-of-service wood
1998 - IRG/WP 98-50107
Elimination of CCA from decommissioned wood prior to disposal is a major environmental issue. One approach is to extract CCA from treated wood, then reuse the 'clean' (may contain CCA, but below hazardous level) wood materials for manufacturing wood-based composites. In the present paper, we focus on effective leaching processes, selection of leaching agents and optimum leaching ...
K M F Kazi, P A Cooper


Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


Preservative treatment and field test monitoring of spruce pole stock: Pressure and diffusible chemical treatments
1990 - IRG/WP 3605
One hundred and forty four spruce (test species) and southern yellow pine (reference species) poles were variously treated by center boring, incising, or kerfing, followed by pressure treatment with CCA and/or diffusible preservatives. The diffusible preservatives included NaF/creosote, borax and ammonium bifluoride. The poles were set at a test site and evaluated for preservative distribution and...
B Goodell, A J Pendlebury


A study of the colonization of wood blocks in a laboratory unsterile soil test
1988 - IRG/WP 2318
CCA treated and untreated beech blocks were exposed to a defined horticultural loam using the method proposed for the collaborative soft rot test in the soft rot sub-group of Working Group Two. At intervals during the incubation wood samples were removed and fungal isolations were made using selective media. Fungi were identified and tested for their cellulolytic ability and their decay capacity i...
M T De Troya, S M Gray, D J Dickinson


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Discoloration of pressure impregnated wood caused by Amorphotheca resinae
1990 - IRG/WP 1438
Amorphotheca resinae Parbery with the anamorph Cladosporium resinae (Lindau) von Arx & de Vries is a cosmopolitan fungus known from aviation kerosene, hydrocarbon contaminated soil and creosoted timbers. In Denmark it causes heavy discoloration on wood treated with waterborne chromate-containing preservatives e.g. CCA-oxide type. The teleomorph produces small spherical fruitbodies widespread o...
F Rune, A P Koch


A laboratory technique to measure the performance of preservative treated hardwoods in ground contact
1982 - IRG/WP 2172
A laboratory technique to measure the performance of preservative treated timber in ground contact is described. It uses partially sealed blocks of timber which are treated, leached and sawn into small stakelets for soil exposure in a fungal cellar. Performance is monitored by the loss of static bending strength with time, and a simple apparatus for measuring the deflection of a stakelet under a l...
E F Baines


Effects of two wood preservatives and one water repellant on the settlement of fouling communities in a tropical marine environment
2002 - IRG/WP 02-30293
Observations made on recruitment of fouling organisms on treated panels exposed at an Indian harbour, Krishnapatnam on the east coast (Lat: 13028’ to 13059’ N; Long: 80010’ to 80016’ E) during November, 1997 to October, 1999 are reported and compared with fouling communities on control panels. Wooden panels of Erythrina variegata, Paraserianthus falcataria, Tetrameles nudiflora an...
B Tarakanadha, K S Rao


The field performance of CCA-C treated sawn refractory softwoods from North America
1997 - IRG/WP 97-40085
Approximately 15% of the total volume of wood treated in the United States consists of difficult to treat softwoods known as "refractory softwoods". The long term positive performance record of CCA treated sawn material is based upon the testing of yellow pine sapwood stakes with only limited field data available for sawn refractory softwoods. As a result, the existing North American wood preserva...
M J Richards, W S McNamara


Premature failure of treated timber in wharfs in Papua New Guinea, attributed to defects in design
1991 - IRG/WP 4158
The performance of timber in wharfs in Papua New Guinea has been monitored for a number of years. Premature failure of wharf structures was found in many cases to be due to defects in design rather than ineffective preservative treatment. Above-water timbers were found to be prone to severe checking followed by decay. Protection for the end grain of pile tops and the limiting of radial checking in...
S M Cragg


Comparative studies on the species effects of wood preservatives
1989 - IRG/WP 3521
For the examination of the resistance against fungal attack, wood blocks of 3 softwood species were treated with CCA (type 3), CFK, AAC and IF-1000 independently. The wood blocks were exposed to the fungal decay with Tyromyces palustris. The degradation of the wood blocks treated with these preservatives was quite widely different among wood species examined in this study. Hem-fir treated with CCA...
K Yamamoto, S Matsuoka


Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching. According to BPD hazard assessment has to be carried out f...
N Morsing


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Application of a novel strength evaluation technique during screening of wood preservatives
1986 - IRG/WP 2262
The effectiveness of CCA and ACA in treated aspen mini stakes tested using a novel bag procedure, with unsterile soil fortified with Chaetomium globosum and Ceratocystis albida, is reported. Good agreement between toxic limits determined using the standard weight loss procedure, and those determined by the strength technique were found, with some indication that the strength loss method is more se...
J N R Ruddick


Distribution of copper/chrome/boron preservative in light red meranti (Shorea leprosula) before and after exposure test for 72 months
1995 - IRG/WP 95-20073
Copper/chrome/boron (CCB) preservative at 6% w/w was impregnated into light red meranti (Shorea leprosula) by full cell process. The quantitative analysis for copper, chrome and boron contents in treated wood samples was carried out by Inductive Couple Plasma (ICP). Electron Probe Microanalyser (EPMA) was used to monitor the distribution of copper, chrome and boron in the various treated wood tiss...
S Salamah, S Ani


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