IRG Documents Database and Compendium


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Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Second update
1995 - IRG/WP 95-10117
As was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthen...
J R J French


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Accelerated termicidal performance data for new water-based copper linoleate formulations
1996 - IRG/WP 96-30104
An organic solvent based copper linoleate (Culin) has proved itself as an effective wood preservative in long term field trials in South Africa over a period of 30 years. Whilst the organic solvent based product offers good wood preservative performance, primary industrial interest has been in an emulsified version of the product. The objective of this study was to evaluate the influence of two di...
D Conradie, P Turner


Influence of variable lignin content amongst hardwoods on soft-rot susceptibility and performance of CCA preservative
1982 - IRG/WP 1151
This paper presents the outline of an argument, based on both new and established data, which relates varying lignin content to variation of soft-rot susceptibility between hardwood species and of performance of CCA preservatives in controlling soft-rot. Although more data need to be generated to prove this relationship, sufficient evidence exists for the hypothesis to be given close attention, pa...
J A Butcher, T Nilsson


Leaching of arsenic, copper and chrome from preservative-treated timber in playground equipment
1984 - IRG/WP 3149
Samples were taken from CCA-treated timber in sand play boxes and other play ground equipment. Sand was also sampled. Sand and wood samples were analysed for copper, chrome and arsenic by AAS. About 20-25% of the arsenic had leached from the timber after 2-4 year's exposure in the playgrounds. Very little of the copper and chrome had been leached. Sand collected in the close vicinity of t...
B Henningsson, B Carlsson


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Soft rot decay in CCA treated eucalypts in Queensland - A comment
1986 - IRG/WP 1301
A survey has been completed concerned with the distribution and severity of groundline soft rot decay in the CCA treated sapwood of eucalypt poles in Queensland. The survey encountered some 1000 poles of which 55% were slightly, 28% moderately and 17% severely decayed. Soft rot decay was more severe in urban than rural locations. Embedment of poles in concrete resulted in severe soft rot. No signi...
L E Leightley


Remedial ground-line treatment of CCA poles in service. A progress report after 28 months' testing
1988 - IRG/WP 3481
Remedial treatments of CCA-treated poles in service with incipient soft rot were carried out with boron rods, boron/glycol solution, boric acid paste, copper/creosote paste and a commercial product (DFCK paste) respectively. The micro-flora before remedial treatment and 6 months after as well as the spread of chemicals in the poles were reported in Document No: IRG/WP/3388. In this progress report...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Marine performance of preservative treated Southern pine panels. - Part 1: Exposure in Newport, Oregon
2000 - IRG/WP 00-10368
The ability of selected wood preservative to protect southern pine sapwood against marine borer attack was evaluated over a 6 year period in Yaquina Bay, Oregon. The site exposed the wood to potential attack by both Teredo navalis and Limnoria spp. Both creosote and CCA provided excellent protection at moderate retentions, while ACQ produced slight differences in performance depending on the coppe...
R G Rhatigan, J J Morrell, A R Zahora


Fouling assemblage development on copper-chromium-arsenic-treated timber submerged in European waters
2002 - IRG/WP 02-50181
The effect of the anti-marine-borer timber preservative CCA on community development of non-target marine fouling animals was investigated. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m3 of wood, plus untreated controls were submerged at seven coastal sites (Portsmouth, UK; La Tremblade (2 sites), France; Ria Formosa, Portugal; Sagres, Portugal; Kristineberg, Swed...
C Brown, R J Eaton, S M Cragg, P Goulletquer, A Nicolaidou, M J Bebianno, J Icely, G F Daniel, T Nilsson, A J Pitman, G Sawyer


Performance of copper-chrome formulations in ground contact in five test sites in New Zealand
1996 - IRG/WP 96-30113
Copper-chrome-arsenate (CCA), copper-chrome-boron (CCB), copper-chrome-fluoride (CCF) and copper-chrome-phosphate (CCP) have been tested at four retentions each in ground contact (25 x 50 x 500 mm³ radiata pine sapwood stakes) for 16 years in five test sites in New Zealand. Results to date show that test site characteristics have a marked effect on relative performance. In a warm and wet site (an...
M E Hedley, R N Wakeling, J Foster, B E Patterson


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Evaluation of the efficiency of industrial kiln type CCA fixation chambers
1996 - IRG/WP 96-40063
Six commercial CCA treating plants in Canada were assessed for the fixation efficiency of their hot air fixation chambers. The wood temperature was measured with thermocouples over the fixation period at different locations in the chamber and at the end of the fixation cycle, the degree of chromium fixation was determined by a boring leaching procedure. There was a great variation in the effective...
A Taylor, P A Cooper


Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


Working plan: Second international collaborative field trial
1995 - IRG/WP 95-20056
This paper describes the scope, objectives, and approaches to be used in the second international collaborative field trial approved by the Scientific Programme Committee for partial funding in 1994. The trial is designed to develop a broad data base on causal mechanisms, interactions, and factor affecting the performance of treated wood in ground contact. The trial encompasses 12 different field ...
H M Barnes, T L Amburgey


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


Comments on soft rot attack in timbers treated with CCA preservatives: A document for discussion
1982 - IRG/WP 1167
This paper is not based on any particular results but rather on several observations of soft-rot during many years of studies, and on a review of the existing literature. The short time available has unfortunately not permitted a detailed review of the literature. Data and knowledge of important facts are lacking for several aspects of soft-rot attack and for reactions occurring in the wood as a r...
T Nilsson


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


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