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A laboratory technique to measure the performance of preservative treated hardwoods in ground contact
1982 - IRG/WP 2172
A laboratory technique to measure the performance of preservative treated timber in ground contact is described. It uses partially sealed blocks of timber which are treated, leached and sawn into small stakelets for soil exposure in a fungal cellar. Performance is monitored by the loss of static bending strength with time, and a simple apparatus for measuring the deflection of a stakelet under a l...
E F Baines


Inadequacies in preservative retention and formulation as contributory causes of premature failure of CCA-treated vineyard posts
1984 - IRG/WP 3280
Analyses of severely decayed or failed vineyard posts and examination of stake test data on effectiveness of copper-chrome-arsenate (CCA) preservatives have suggested two contributory causes of premature failure of vineyard posts: 1. Preservative retentions in posts are such that after 15 years' exposure some decay is inevitable. 2. The high arsenic, low chrome formulations with which the...
M E Hedley


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Multiple-Phase Pressure (MPP) Process: Pilot plant trials for disposal of kickback using reverse osmosis membrane filtration
2001 - IRG/WP 01-40202
The MPP Process (a one-stage CCA treatment and accelerated fixation process) generates ~ 250 litres of kickback per cubic metre of timber treated. Composition of kickback is mainly wood sugars and traces of copper, chromium and arsenic. In pilot plant scale trials, MPP process kickback was filtered through a Reverse Osmosis (RO) membrane of a type found from earlier small-scale trials to be the mo...
H Pearson, G Durbin, M E Hedley


Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis


Characterization of checks and cracks on the surface of weathered wood
2000 - IRG/WP 00-40153
The surface roughness of unweathered and untreated pine; unweathered copper chromium arsenate type C (CCA) - treated pine; weathered CCA-treated pine; and weathered CCA-plus-water-repellent (WR) - treated pine was evaluated by a stylus tracing method. Surface roughness parameters Ra, Rz, Rmax, Rk, Rpk, and Rvk were measured. Ra, Rpk, and Rvk were the most appropriate parameters for describing modi...
D P Kamdem, Jun Zhang


Performance of preservative-treated timber against biodeterioration in Indian waters
1984 - IRG/WP 4106
Results on the investigation on the durability of panels of 32 timber species, pressure-treated with various preservatives and exposed along the Indian coast for varying periods upto a maximum of 15 years, are summarised. Panels of even non-durable timber gave excellent results against biodeterioration after treatment. Their life was comparable to that of treated durable timber. The preservative t...
L N Santhakumaran, J C Jain, M C Tewari


Preservative treatment of Golpata (Nypa fruticans) using CCA (Chromated Copper Boric Acid)
1999 - IRG/WP 99-40131
Golpata (Nypa fruticans) leaves provide a cheap but practical source of roof thatches. This study was carried out to determine whether the life span of Golpata could be extended by using CCB (Chromated Copper Boric Acid) treatment. Both leaves and midribs of Golpata , with different moisture contents ranging 16.63% to 70.67%, at the start of the experiment were treated with four different concentr...
G N M Ilias, F Abdullah, M O Hannan, S M Feroz


Future Directions Regarding Research on the Environmental Impacts of Preservative-Treated Wood: Environmental Impacts of Preservative-Treated Wood. February 8-11, 2004, FL, USA Workshop – Research Needs
2004 - IRG/WP 04-50222
This paper presents a series of documents that focus on research needs for potential future work focusing on the environmental impacts of preservative-treated wood. These documents were developed through a conference sponsored by the Florida Center for Environmental Solutions (FCES), located in Gainesville, Florida. The conference was held in Orlando, Florida, February 8 – 11, 2004 and the tit...
H M Solo-Gabriele, J D Schert, T G Townsend


A note on te seasoning, preservative treatment and suitability of debdaru (Polyalthia longifolia Benth & Hooker.) for poles
1995 - IRG/WP 95-40056
The main work is to determining the suitability of Debdaru (Polyalthia longifolia Benth.) as poles from Government and Village forests are investigated. The poles of Debdaru are easily treatable with CCA preservative by full-cell pressure method, but difficult to dry (air & kiln). Proper quality control must be maintain from procurement to treatment, specially during physical selection & d...
G N M Ilias, M D Rokib-ul-Hafiz


Soluble nutrient influences on toxicity and permanence of CCA preservatives in wood
1980 - IRG/WP 3144
The influence of soluble carbohydrate and nitrogenous components concentrated at evaporative surfaces of wood on the toxicity and permanence of CCA preservatives has been examined using soil-burial techniques. Nutrient concentrations in lime (Tilia vulgaris Hayne) have been shown to be associated with reduction of toxic limits of preservatives to an extent in which a 100% increase in preservative ...
B King, G M Smith, A Bruce


Losses of CCA components and creosote from treated timber to soil
1997 - IRG/WP 97-50098
Components of creosote and CCA preservatives can migrate within the wood and move into surrounding soil. However, at present, the ecological significance of such losses is uncertain. This paper examines the distribution of four target polyaromatic hydrocarbons (PAHs ) and of copper, chromium and arsenic in treated stakes and surrounding soil after long term exposure in field trials. Concentrations...
N J Hudson, R J Murphy


Comparison of methods for monitoring CCA fixation
1994 - IRG/WP 94-40023
The CCA fixation status in the outer 12.5 mm of pole sections of southern pine (Pinus sp.), red pine (Pinus resinosa) and lodgepole pine (Pinus contorta var. latifolia) were followed during fixation at 21°C under non-drying conditions by the following procedures: - Qualitative CrVI indication by the chromotropic acid spot test. - Quantitative CrVI in the expressate by the diphenylcarbazide method...
P A Cooper, Y T Ung, G Zanjani


On the occurrence of Phialophora species in preservative treated wood in ground contact
1977 - IRG/WP 163
Phialophora is a fairly large genus comprising about thirty described species. They are widespread in very diverse environments, such as soil, sea water, wood and wood pulps. Some species are known as parasites on plants and animals, including man. Phialophora species were early known for their ability to produce blue stain in timber. Later it was discovered that several species were able to produ...
T Nilsson, B Henningsson


A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Rainfall simulation to assess CCA permanence
1991 - IRG/WP 2373
During experimental work on accelerated fixation of chromium containing preservatives a method has been developed which compares the degree of preservative levels of contamination of simulated preservative fixation in timber with the levels of simulated rainfall. This method uses commercial sized wood sections wetted in a way that simulates actual rainfall and relates the associated run-off contam...
P Warburton, J A Cornfield


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


Preservative treatment of green timber by diffusion
1984 - IRG/WP 3291
The preservative treatment of green timber by diffusion is reviewed together with criteria which influence the economics of the process. New process options are described which should overcome some of the technical and economic disadvantages of double diffusion. These include the use of coagulating agents which increase the viscosity of the preservative solution and facilitate treatment by momenta...
P Vinden


Effect of test site, preservative and wood species on decay type Glenbervie pastoral and radiata pine forest sites
2000 - IRG/WP 00-30248
Pinus radiata stakes were treated with 0.8, 1.2, 1.8, 2.7 and 4.1 kg/m3 of CCA and Fagus sylvatica with 2.7, 4.1 and 6.1 kg/m3 of CCA. Both wood species were also treated with equivalent retentions of a copper plus triazole preservative (CT) (0.89, 1.3, 2 and 3 kg/m3 of copper for pine & 2.5 and 4 for beech) and chlorothalonil plus chlorpyriphos in oil (CC) (1.4, 2.1, 3.2 and 4.8 kg/m3 of chlo...
R N Wakeling


The effect of composition on the effectiveness and fixation of CCA and copper/chrome preservatives. Part 1: Effectiveness. Part 2: Selective absorption and fixation
1973 - IRG/WP 324
A preliminary study of a wide range of copper-chrome-arsenic formulations indicates that the most effective are in the region, CuSO4 · 5H2O - 35 to 45 per cent; K2Cr2O7 - 40 per cent and above; As2O5 · 2H2O - 25 to 15 per cent or less. Effectiveness appears to depend more on the copper content than the copper - arsenic. Observations on selective absorption and leaching suggest that the chromium ...
D N R Smith, A I Williams


The relationship between the electrical resistance and fixation of water-borne CCA salts and pressure-treated wood
1991 - IRG/WP 3657
Two investigations at 22°C and 30°C have been carried out. The electrical resistance in the treated wood and chemical analyses of the remaining amount of unfixed copper, chromium and arsenic were investigated. Samples impregnated with water were used as references. To hold the samples moist during the investigation, each sample was wrapped in a polyethylene plastic foil immediately after impregn...
F G Evans, B Nossen


Sphaeroma terebrans Bate: A note on distribution and preservative tolerance in Florida coastal waters
1987 - IRG/WP 4135
Treated test panels were installed in January 1984 in a Florida estuary where Sphaeroma terebrans had severely damaged pilings treated with copper chromate arsenate (CCA). Test treatments were CCA at three retentions, coal-tar creosote at three retentions, creosote with chlorpyrifos, dual treatment with CCA and creosote, and three types of chemical modification of the wood test panels. We describe...
B R Johnson, E D Estevez, S A Rice


Effect of water repellents on leaching of CCA from treated fence and deck units - An update
1997 - IRG/WP 97-50086
In an earlier study, it was shown that CCA leaching losses could be reduced over an accelerated leaching and short term natural weathering exposures by post treatment application of a commercial water repellent. In this report, the effects of this coating and two commercial CCA solution water repellent additives are evaluated after two years of natural weathering. Wood boards were pressure treated...
P A Cooper, Y T Ung, R M Vicar


Susceptibility of CCA treated North American hardwoods to Chaetomium globosum decay
1998 - IRG/WP 98-10278
Seven species of hardwood, Beech (Fagus grandifolia), Basswood (Tilia americana), Maple (Acer rubrum), Oak (Quercus rubra), Trembling Aspen (Populus tremuloides), White birch (Betula papyrifera) and Yellow poplar (Liriodendron tulipifera) were vacuum or pressure impregnated with CCA, at four retention levels. The CCA was allowed to fix in the wood at 35°C. Red pine (Pinus resinosa) was also inclu...
U Srinivasan, Y T Ung, P A Cooper


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