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Fire resistance of wood treated with potassium carbonate and silanes
2014 - IRG/WP 14-30657
This paper reports on the effect that organosilicon compounds and potassium carbonate and urea (PCU) have on wood flammability. The study focus on reducing wood flammability by promoting char formation through manipulation of the condensed phase decomposition chemistry. Potassium carbonate is known as an effective fire retardant, however it is easily leached out from wood and increases its hygrosc...
B Mazela, M Broda, W Perdoch


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


Copper and chromium leaching from wood impregnated with chromium-copper containing preservatives: Results of different studies
2014 - IRG/WP 14-50300
Copper and chromium based wood preservatives remained one of the most important ingredients for wood protection solutions for protection of wood in demanding applications all-over the world. Leaching of heavy metals from treated wood is important from two different aspects; firstly from performance point of view, and secondly from environmental issues. However, the importance of these studies is i...
M Humar, N Thaler, E Melcher


Influence of Exposure Direction on Leaching of a Biocide from Painted Wood Surfaces
2014 - IRG/WP 14-50303
The objective of this project was to investigate the influence different exposure directions – North, East, South and West on the cumulative quantity of a biocide leached from painted wood surfaces due to rainfall and the consequences for the risk assessment. The study included a solvent-borne primer without biocides and a topcoat protected with a biocidal active substance. Both products were a...
M Klamer


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Leachability and Dimensional Stability of Nanosilver-Steamed Densified Poplar
2014 - IRG/WP 14-40684
This study was aimed to investigate leachability and dimensional stability of nanosilver impregnated poplar (Popolus alba), steamed before hot compression. Wood samples were impregnated with nanosilver suspension (200 and 400 ppm) under pressure of 4 bar for 20 minutes. Steam treatment was carried out at 150°C for 2 hours. Then samples were compressed (33%) radially in a hot press at 170°C for 3...
G Rassam, A Talaei, A Ahmadi


Durability of treated wood Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla against subterranean termite
2015 - IRG/WP 15-20563
This work aimed to analyze the durability of woods against termite Nasutitermes corniger Motsch. Fence posts from this study were collected in Pinheiros, north of Espírito Santo state, Brazil. Used the Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla species with 11 and 9 years, respectively and plant spacing of 3.00 x 2.00 m. Were used 72 samples from discs removed the 0.50 m of...
D Junior Verly Lopes, J Benigno Paes, P N de Medeiros Neto, G dos Santos Bobadilha


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


Evaluating the Effects of Post Dip-Treatment Laser Marking on Resistance to Feeding by Subterranean Termites
2016 - IRG/WP 16-10854
Dip-treatment of wood packing materials is often used instead of pressure treatment mainly because of issues relating to simplicity and cost. Packaging boxes fabricated for the United States Army are required to be dip-treated for at least one minute in an approved preservative solution prior to use. These boxes are expected to have a service life of up to 20 years in a wide variety of environment...
R A Arango, B Woodward, S Lebow


CCA Treated Wood, Will It Last 100 Years?
2016 - IRG/WP 16-20575
Copper, chrome and arsenate (CCA) treated wood has a very successful history of use in New Zealand, for at least 60 years. In many parts of the world, CCA has been used for timber treatment since the mid-1930s. In this report, data are presented on the performance of CCA treated pine stakes and poles. Results from ground contact durability tests at Scion and other overseas test performance data su...
T Singh, D Page


Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


Enhancing wood properties through bio-based and non-biocidal co-polyesters
2016 - IRG/WP 16-40740
The commonly used wood preservation treatments are nowadays facing huge environmental issues, as well as increasing public concern. As regards those concerns, legislation tends to regulate the use of biocidal preservation chemicals. Thus, it does appear crucial to provide alternatives to the use of biocides to allow different outdoor uses of wood such as for, posts, decking, and cladding or even ...
C L’Hostis, M-F Thévenon, E Fredon, P Gérardin


Creosote leaching from timber bridges in Norway – a practical classification approach
2016 - IRG/WP 16-40744
Creosote is widely used as a wood preservative for highway timber bridges in Norway. However, excessive creosote leaching at various highway timber bridge sites leads to a bad reputation for the use of creosote treated timber constructions and the use of wood in general. Macro- and micro anatomical factors such as amount of heartwood, annual ring width, annual ring orientation, ray- height and com...
A Treu, K Zimmer


Properties of Wood Plastic Composites Made of Recycled HDPE and Remediated Wood Flour from CCA/CCB Treated Wood Removed from Service
2016 - IRG/WP 16-40747
Chromated copper arsenate (CCA) and copper, chromium and boron (CCB) have been widely used in pressure treated wood as a heavy duty preservative to protect wood against insects and fungi for more than 60 years. Although many attempts have been done to solve the problems related to out-service treated wood, the problem still remains. Only a few studies were done to utilize the out-of service treate...
E D Gezer, S Akbaş, M Tufan, A Temiz


10 year Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2017 - IRG/WP 17-30718
A round robin involving 15 European participants was set up in 2006. The round robin consisted of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. The laboratory test results were reported in an earlier IRG paper (IRG/WP13-20535) but are included also in this paper in order to facilitate the comparison with the field test...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, E Melcher, R Moeller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


The Effects of Pre-Microwave Treatment on Retention Levels And Some Mechanical Properties of Spruce Wood Treated with CCA
2017 - IRG/WP 17-40800
Microwave (MW) treatment of wood has been evaluated in recent years for different purposes by several scientists. Microwave conditioning improves permeability, reduces density and heat conductivity and changes dimensional stability. Furthermore, it could even improve the permeability of refractory wood species such as spruce and Douglas fir. In this study, MW pre-treatment was applied to spruce wo...
E D Gezer, S Kuştaş, S Durmaz


Uncertainty in life cycle assessment of preservative treated wood – copper and freshwater ecotoxicity
2017 - IRG/WP 17-50331
Life cycle assessment (LCA) is a method for quantifying the environmental impacts of a product over the life cycle. In the last years, there have been a growing application of LCA in developments of environmental product declaration (EPD), which is utilised by professional procurement of materials for buildings. For legislative issues, LCA have also been used to assess application of creosote to t...
L G F Tellnes


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


Effects of wood protecting biofinish and linseed oil on fire behaviour and leachability of the fire retardant
2018 - IRG/WP 18-30728
A wood protecting biofinish is based on a protective and decorative fungal-based coating and a linseed oil impregnation (called Xyhlo biofinish). This biofinish enables the long-term use of wood in outdoor applications without using toxic chemicals. The fire resistant properties of materials used in buildings are very important. Since Xyhlo biofinish is relatively new, only little information is ...
S Rensink, E J van Niewenhuijzen, M F Sailer


Selection of heat flux value for wood fire retardants testing using MLC
2018 - IRG/WP 18-40846
One of more crucial elements of investigating treated wood combustion properties with the use of a cone calorimeter is a proper selection of heat flux (HF). The HF level is directly reflected in time to ignition and a thermal degradation degree. The ignition of raw wood or of wood ineffectively protected against fire occurs at a low HF level, i.e. 10-20 kW/m2. By contrast, the ignition of wood whi...
B Mazela, W Perdoch, W Grześkowiak, A Batista


Influence of different triazoles as co-biocides in wood preservatives on efficacy and the environmental impact
2018 - IRG/WP 18-50333
In this study we investigated the efficacy and impact on the environment of different co-biocide triazoles in wood preservatives. Four different formulations (all containing 9.5% Copper) contained individual and combinations of cyproconazole, tebuconazole, propiconazole as co-biocides. Four formulations were tested according to EN 113 and EN 84 (ageing) to determine the brv for each formulation. T...
M Klamer, T Jensen, S Bang-Achton, E Morsing


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