IRG Documents Database and Compendium


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Ecotox Testing of Leachates as an Alternative Approach for Environmental Impact Assessment of Wood Preservatives
2002 - IRG/WP 02-50185
Driven by the implementation of the EU Biocidal Product Directive (BPD) in the environmental assessment of treated wood different methodologies and test strategies are at present under discussion within industry, regulatory authorities and standardizing comittees. Test procedures for the analytical determination of emissions to different environmental compartments according to exposure scenario...
H-W Wegen


Future insecticidal treatments for wood products
1980 - IRG/WP 3140
Protective measures involving chemical treatment of wood use only a narrow range of toxic materials which are divisible into two groups, (i) those that are water-soluble, (ii) those that are soluble only in organic solvents. It is generally true to say that, as far as protection against insects is concerned, the former are stomach poisons while the latter are largely (though not exclusively) conta...
D J Cross


Method to determine the depth of penetration of the biologically active components of wood preservatives
1978 - IRG/WP 2108
A time-saving method for determining the depth of penetration of the biologically active components of wood preservatives is described. The test specimens were obtained by cutting thin slices from the wood either parallel or perpendicular to the treated surface. The slices were then exposed to fungal attack. A good correlation was found between the test results obtained by the modified German Stan...
H-P Sutter


International standardisation: a hypothetical case study with stand-alone borate wood preservatives
1998 - IRG/WP 98-20147
The possibility of developing wood preservation standards with a global remit has a number of obvious advantages as well as far reaching ramifications, many of which are undefined as yet. The commercial implications of adopting international standards are clearly considerable, but equally, such a development is likely to focus attention on the conceptual differences in the way that different regio...
M W Schoeman, J D Lloyd


The wood preservative performance of biocide mixtures containing chlorpyrifos
1994 - IRG/WP 94-30055
Chlorpyrifos (O,O-diethyl[3,5,6trichloro-2-pyridyl]phosphorothioate) was evaluated as a wood preservative insecticide in two long term field tests. In the first project, pine sapwood blocks treated with chlorpyrifos (CPF) were exposed to Coptotermes formosanus using an above-ground test format. CPF is effective in protecting wood from attack by this termite, but its activity appears to decrease wi...
P E Laks


Administration of wood preservative usage in New Zealand
1977 - IRG/WP 395
Principal administration of the preservative treatment of timber in New Zealand is by the Timber Preservation Authority (TPA). The TPA was established in 1955 by Act of Parliament and is under the jurisdiction of the Minister of Forests who appoints its members. Its field staff are Forest Service employees. The Authority comprises twelve members and includes representatives of timber trade associa...
M E Hedley


A comparison of fungal strains used in the bioassay of wood preservatives
1984 - IRG/WP 2220
Previously published data are presented relating to a number of strains of wood-destroying basidiomycetes (Coniophora puteana, Coriolus versicolor, Gloeophyllum abietinum, Gloeophyllum sepiarium, Gloeophyllum trabeum, Lentinus lepideus, Poria placenta, Fibroporia vaillantii and Serpula lacrymans) commonly used as test fungi in the bioassay of wood preservatives. The data, which has not been statis...
J Wazny, H Greaves


Microdistribution of water-borne preservatives in blue gum treated by full-cell process
1990 - IRG/WP 3617
The present work deals with the study of the microdistribution of copper, chrome and arsenic elements in Eucalyptus globulus Labill. sapwood, treated with a CCA water-borne preservative by full-cell process, with the help of scanning electron microscopy together with energy dispersion X-ray analysis technique. The work shows that the retention of CCA elements is high in vessels and vasicentric par...
D De Sousa Castro Reimão, J M Palacios


Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Šentjurc


Influence of water-borne preservatives on water repellency and the impact of addition of water repellent additives
1992 - IRG/WP 92-3704
The primary goal of a desirable wood preservative system is to effectively control decay fungi and other biodeteriogens in service. The water repellent nature of a given system may play an important role in the protection of wood. In this study, the water repellency of several water-borne preservative systems has been evaluated by measurements of tangential swelling during immersion. The systems i...
L Jin, D M Roberts, A F Preston


Evaluation of a laboratory soft rot test on basis of weight loss and residual strength
1989 - IRG/WP 2336
Based on the principles of different previously reported experimental procedures dealing with laboratory soft rot testing, a study was conducted on treated poplar and beech. Preservatives used were CCA, CCF, AAC, Azaconazole and TCMTB. Treated samples were exposed for three months in a vermiculite substrate to Chaetomium globosum. Evaluation was based on absolute mass loss, percentage weight loss ...
W Verbeke, J Van Acker, M Stevens


Treatment groups and remedies for CCA treated hardwood and softwood poles
1999 - IRG/WP 99-40142
Different hardwood and softwood species from Bangladesh and Bhutan was investigated regarding density, green fiber stress, natural durability of heartwood and CCA treated sapwood, CCA treatability grades, sapwood thickness, and kiln-drying properties for long term use as electric poles. These properties along with the past service records for nineteen years, separated ten heardwood and five softwo...
A K Lahiry


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


CCA-treated Wood Disposed in Landfills and Life-cycle Trade-Offs With Waste-to-Energy and MSW Landfill Disposal
2005 - IRG/WP 05-50231
CCA-treated wood as a solid waste is managed in various ways throughout the world. Although some wood is combusted for the production of energy in the U.S., more often than not, CCA-treated wood is disposed in landfills. In other countries, wood, often including CCA-treated wood, is combusted for the production of energy. This paper is presented in two parts. Part I evaluates the impact of CCA-tre...
J Jambeck, K Weitz, T G Townsend, H M Solo-Gabriele


A technique for measuring preservative loss or redistribution during leaching
1983 - IRG/WP 2199
Radiata pine sapwood stakes were treated with benzalkonium chloride (AAC) or copper-chrome-arsenate (CCA). After fixation and drying the outer 2 mm and 2-4 mm layers were removed from one radial longitudinal face. The planed face was coated with a waterproof coating and AAC-treated stakes were leached for 6, 12 or 18 weeks; 12 weeks for the CCA-treated stakes. After airdrying three 2 mm layers (0-...
J A Drysdale


Wood preservatives treatment of black spruce
1997 - IRG/WP 97-40092
A representative sample of black spruce logs from Central Newfoundland was harvested and processed to dressed 2"x4" lumber. Over 400 pieces of lumber were then incised and treated with ACQ preservative in a semi-industrial retort. 9 charges of 20 samples were used to determine treating parameters and 11 charges of 20 pieces were treated using the optimized process. This material was inspected by a...
A R Zahora, J P Hösli


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Preservation of coppice wood for the fabrication of glued beams or panels
1987 - IRG/WP 3427
In this survey we will examine the specific problems concerning the conservation and the preservation of timber (issued from trunks of small diameter corresponding to products of clearings or coppices) destined for the fabrication of solid reconstituted elements. Thus for six metropolitan species of wood, we first characterized the biological deteriorations which occur after felling and their kine...
G R Y Déon, R Schwartz


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Experiences with environmental risk assessment within the Biocidal Products Directive
2005 - IRG/WP 05-50224-21
The Biocidal Products Directive (98/8/EC, the BPD) aims to authorize biocidal products based on risk assessment for both man and the environment. Active substances for wood preservation products and rodenticides were selected for the first list under the review program (Regulations EC 1896/2000 and EC 2032/2003) because several member states had experience with the evaluation and authorization of ...
P Blancquaert


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


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