IRG Documents Database and Compendium


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Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 6: Report of third inspection (24 months) in Australia
1980 - IRG/WP 456
This report presents the results of the third inspection of the IRG/COIPM International Marine Test specimens installed at the Goat Island Marine Biological Station of the Maritime Services Board of New South Wales, in Sydney Harbour. The inspection was completed on 5th December, 1979, after 24 months exposure. As on previous occasions, this inspection was carried out in conformity with the provis...
J Beesley


The effect of wood preservatives on the relation between the electric resistance and moisture content in scots pine (Pinus sylvestris L.) sapwood
1998 - IRG/WP 98-20142
The effect of two types wood preservatives (TBTO and CuHDO) on moisture content measurements with an electric resistance meter in pine sapwood is assessed. High and low concentration impregnated pine sapwood is climatized at different relative humidities. Once climatized the samples are weighed and the moisture content is measured with an electric resistance meter by fixed stainless steel, isolate...
B W Holleboom, W J Homan


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


The EWPMG proposal for the environmental risk assessment of wood preservatives
2001 - IRG/WP 01-50166-09
This paper reviews the protocol prepared by the European Wood Preservative Manufacturer's Group, which could be used by an applicant for product approval under the Biocidal Products Directive 98/8/EC, to produce a risk assessment for an active substance or product in the Product Type 8 Wood Preservatives, in support of the application. The background and scope of the protocol are reviewed...
E F Baines


Why did Japan replace CCA by alternatives?
2004 - IRG/WP 04-50215
Since chromated copper arsenate (CCA) was technically introduced into Japan in 1963, CCA was used for extending service life of various wood commodities, especially sill plates (dodai) in Japanese houses. However, the problem on the disposal of CCA-treated wood waste became public and related industry concern, and questionnaire survey conducted by Japan Wood Preservers’ Industry Association ind...
H Ishida, T Ito, M Yamai, H Matsusaka, K Tsunoda


A study on the pressure impregnation of Eucalyptus globulus fence-posts with CCA preservatives. Part 2
1989 - IRG/WP 3514
This paper describes the second part of a study on pressure impregnation of Eucalyptus globulus fence-posts with CCA preservatives presented at the IRG 19th Meeting. Fence-posts of three diameter classes, were treated, considering only one treatment schedule. The results show possibility of vacuum-pressure impregnation of blue gum fence-posts, with diameter less than 9 cm, though mainly by longitu...
L Nunes, D De Sousa Castro Reimão


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 14: Report of fifth inspection (48 months) in Australia
1982 - IRG/WP 484
This report presents the results of the fifth inspection of the IRG/ COIPM Internatlonal Marine Test specimens installed in Sydney Harbour in December, 1977. This inspection took place on 9th December, 1981, just 48 months after the specimens were installed. Earlier reports have contained full details of the treatment and installation of the specimens as well as results of all previous inspections...
J Beesley


Borates as wood preservatives - an environmental, health and safety perspective
1993 - IRG/WP 93-50001-03
Boron compounds are highly effective wood preservatives and have an established safe use in the timber treatment industry. Their widespread background occurrence in nature, low acute mammalian toxicity and useful properties make them versatile active ingredients within today's environmentally aware society. A critical review of health, safety and environmental data on the borates, their u...
J B Rainer


Influence of CCA and TnBTO on wood decay, under different oxygen levels and various initial moisture content
2001 - IRG/WP 01-10415
Fagus sylvatica (beech) and Pinus sylvestris (Scots pine) were impregnated by TnBTO (tributyl-tin oxide) and CCA (chromated copper arsenate). In wood blocks two levels of moisture content (50% and 100% of saturation point) were used. Three levels of oxygen concentrations (10, 21, and 50%) were chosen. Treated and untreated wood were exposed to three fungi (C. versicolor a white rot, C. puteana, a ...
S M Kazemi, R J Murphy, D J Dickinson


Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele


The Efficacy of Wood Preservative Treatments in Laboratory Soil-Bed Test
2004 - IRG/WP 04-20289
The efficacy of wood preservatives were determined in laboratory soil-bed test. Pine and alder wood samples (10 x 10 x 10 mm) were treated with CCA (1, 2%), ACQ-1900 (2, 3%), ACQ-2200 (1, 2%), Tanalith E 3491 (2, 2,8%), Wolmanit CX-8 (1, 2%). The leached and unleached samples were exposed 76 days at Simlångsdalen soil and determined mass loss. The results of this study showed that mass losses o...
A Temiz, T Nilsson, Ü C Yildiz, E D Gezer, S Yildiz


Leaching from CCA-impregnated wood to food, drinking-water and silage
1987 - IRG/WP 3433
During the last years The Norwegian Institute of Wood Technology (NIWT) has analysed different foodstuff for contamination by copper, chrome and arsenic from CCA-impregnated wood. There has been some interest for using CCA-impregnated wood in contact with food and drinking-water. Before giving their permission the Norwegian Health Authorities want results from experiments. NIWT therefore started t...
F G Evans


Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis


Co-incineration of CCA-treated wood and Municipal Solid Waste in MSWI plant
2005 - IRG/WP 05-50224-19
The Norwegian Association of Energy Users and Suppliers (Norsk Energi) have carried out incineration tests with addition of 10 % by weight CCA-treated wood waste to municipal solid waste in a MSWI plant. The objective with the test was to determine emissions and composition of bottom ash. The incineration test was done at the Klemetsrud plant in Oslo The main conclusions are: -No significant inc...
D Borgnes, B Rikheim


IUFRO rating system compares favourably to weight loss for soil-bed testing
1990 - IRG/WP 2343
The soil-bed/small stake test is commonly used for rapidly evaluating the performance of new, more environmentally acceptable, preservatives. In a 1.5 year experiment with three copper-based waterborne preservatives, visual evaluation and probing using the IUFRO performance rating scale (0-4) gave very similar toxic thresholds to those derived from measurement of weight loss at the end of the expe...
P I Morris


Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


Characterization of checks and cracks on the surface of weathered wood
2000 - IRG/WP 00-40153
The surface roughness of unweathered and untreated pine; unweathered copper chromium arsenate type C (CCA) - treated pine; weathered CCA-treated pine; and weathered CCA-plus-water-repellent (WR) - treated pine was evaluated by a stylus tracing method. Surface roughness parameters Ra, Rz, Rmax, Rk, Rpk, and Rvk were measured. Ra, Rpk, and Rvk were the most appropriate parameters for describing modi...
D P Kamdem, Jun Zhang


Recycling CCA-treated poles with Charterm
2005 - IRG/WP 05-50224-17
After 10 years of Research and Development, the first “Chartherm” industrial unit is now operating since nearly half a year, thanks to Thermya SA, engineering company, current owner of all the “Chartherm” process Patents and Rights. In accord with the recycling contracts signed with several French major companies, the “Chartherm” plant, located near Bordeaux, recycles every day severa...
J-S Hery


An example of media response to perceived environmental problems with CCA-treated wood
1990 - IRG/WP 3564
A recent study suggested that CCA-treated wood exposed to acidic precipitation could lose significant amounts of copper chromium and arsenic resulting in loss of efficacy and possible environmental contamination. The study received wide newspaper and radio coverage in Canada, thereby heightening public concern about CCA use. Subsequent studies in our laboratory confirmed that the high losses were ...
P A Cooper


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura


New conception for shortering the duration of fungitoxic test of wood preservatives. Part 2: Computer-assisted miniaturisation of wood specimens
1994 - IRG/WP 94-20052
The mass loss of wood used as a criterion in the standarised agar-block method of evaluation of toxic value of preservatives depends upon the relationship between volume of specimens, their outspread planes and ratio of areas of particular anatomic sections. Upon the computer-assisted mathematical basis the dimensions of miniaturized specimens which make 1/2, 1/4, and 1/8 part of standarized ones ...
J Wazny, K J Krajewski


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