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The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley


Water-Borne Copper Naphthenate: An Emerging Wood Preservative
2002 - IRG/WP 02-30280
Waterborne copper naphthenate (WB Cu-N) was used to treat southern yellow pine (Pinus spp) and red maple (Acer rubrum) stakes. The treated stakes were exposed in test sites located in Florida, Michigan and Mississippi for 3 to 6 years. Copper Chromium Arsenate (CCA), Ammoniacal Copper Quat (ACQ) and Oil-borne Copper Naphthenate (OB Cu-N) were also used to treat some stakes for comparison. Results...
P Nzokou, D P Kamdem, M H Freeman


Durability of heat-treated wood
1999 - IRG/WP 99-40145
Heat-treated wood from the French process were laboratory tested against decay using agar block test and a modified soil block test. Water absorption, bending strength, lignin content and acid number were also determined to evaluate the effect of heat treatment. Heat treated samples exhibit a higher lignin content and a lower acid number compared to untreated control indicating the degradation of ...
D P Kamdem, A Pizzi, R Guyonnet, A Jermannaud


Susceptibility of CCA treated North American hardwoods to Chaetomium globosum decay
1998 - IRG/WP 98-10278
Seven species of hardwood, Beech (Fagus grandifolia), Basswood (Tilia americana), Maple (Acer rubrum), Oak (Quercus rubra), Trembling Aspen (Populus tremuloides), White birch (Betula papyrifera) and Yellow poplar (Liriodendron tulipifera) were vacuum or pressure impregnated with CCA, at four retention levels. The CCA was allowed to fix in the wood at 35°C. Red pine (Pinus resinosa) was also inclu...
U Srinivasan, Y T Ung, P A Cooper


The effect of water storage on the cell-structure of Sitka spruce (Picea sitchensis) with reference to its permeability and preservation
1970 - IRG/WP III 3A
Commercial treatment trials with full sized transmission poles have shown that water storage considerably improves the permeability of Sitka and Norway spruce. These results were confirmed by laboratory measurements which showed that in the sapwood of ponded Sitka spruce there is a vast improvement in permeability in all three grain directions. Heartwood permeability does not seem to be affected t...
J A Dunleavy, A J McQuire


Susceptibility of painted wood to discolouring fungi - influence of binder, solvent and surfactant
1992 - IRG/WP 92-3714
Previous studies have shown that the basic composition of paints, without fungicide addition, can significantly contribute to the varying microbial susceptibility of painted wood. Previously, non-weathered water-borne acrylic paints applied to wood without a primer were shown to be more susceptible to mould attack than solvent-borne alkyd paints. The present study was initiated to reveal if this d...
J Bjurman, C Herder


A methodology for the life-cycle assessment of treated timber products
1993 - IRG/WP 93-50001-01
Using case studies of CCA-treated motorway fenceposts and creosote-treated electricity transmission poles, the paper suggests an approach to evaluation of the overall environmental impact of treated timber products, utilising the emerging systems analysis method of life-cycle assessment (LCA). The development and application of LCA methodologies to date is reviewed and the key features identified....
S R Smith, R J Murphy, D J Dickinson


Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


Factors affecting decay rates in a fungus cellar II
1986 - IRG/WP 2259
Tests were initiated to investigate the influence of various factors on the decay rate in a "Fungus Cellar". Birch and pine stakes treated with chromated copper arsenate and didecyldimethyl ammronium chloride, as well as untreated control stakes, were incubated in two soils in a Fungus Cellar test and installed at two field sites for comparative purposes. The visual rating vs actual stake weight l...
P A McKaig


Waterborne preservative treatability of tamarack (Larix laricina (Du Roi) K.Koch)
1998 - IRG/WP 98-40112
Eastern larch or tamarack (Larix laricina (Du Roi) K.Koch) lumber from New Brunswick, Canada was evaluated for preservative treatability with chromated copper arsenate (CCA-C) and ammoniacal copper arsenate (ACA). The fixation and leaching characteristics of CCA-C treated tamarack sapwood and heartwood were also evaluated. CCA-C penetration into both sapwood and heartwood was poor. ACA fully penet...
A Taylor, Y T Ung, P A Cooper


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Relative tolerance of CCA by larvae and adults of the common shipworm, Bankia gouldi
1992 - IRG/WP 92-4174
Southern pine sapwood "2 x 4´s" were created by bolting together four panels 13 mm thick by 89 mm wide by 457 mm long. The two outer laminates were untreated and the two inner laminates were each treated to different CCA retentions, ranging from 8.0 to 43.2 kg/m³. Test specimens were exposed from May to October in a tributary of the Chesapeake Bay. Larvae were unable to settle on and burrow into...
B R Johnson


Effect of soil type and moisture content on soft rot testin
1986 - IRG/WP 2270
Several soils of different types were tested at a range of moisture contents for their suitability for use in a soil burial soft rot test. Their effectiveness was assessed by weight loss in CCA treated and untreated beech and birch outerwood. A horticultural loam (John Innes No. 2) was the most appropriare soil in terms of amount of weight loss caused, tolerance to changes in soil moisture content...
S M Gray


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 6: The length of the primary precipitation period
1975 - IRG/WP 359
The end of the primary precipitation fixation period of CCA preservatives coincides with the first peak in pH versus time. This offers a simple way of estimating the duration of the period. The duration is determined by a number of factors and their interactions, the most important of which are: wood species (anatomy, natural pH, accessibility of reducing agents), preservative type, preservative c...
S-E Dahlgren


Leaching amount of wood preservatives from treated wood in different size during outdoor exposure for 6 months
2000 - IRG/WP 00-50160
Eighteen impregnated specimens with CCA, ACQ, and BAAC preservatives were subjected to a outdoor leaching test. Test specimens, 10 x 10 x 25 cm3, 5 x 10 x 25 cm3, 2 x 10 x 25 cm3 in size, were cut from Japanese cedar (Cryptomeria japonica). Both of end surfaces were sealed with a silicone sealer in the half number of specimens. Total leaching amounts of copper from the open-end ACQ specimens of 10...
K Yamamoto, S Motegi, A Inai


Water-borne DNBP wood preservatives - Preparation and performance
1987 - IRG/WP 3407
Three waterborne wide-spectrum ground-contact DNBP (2-sec-butyl-4,6-dinitrophenol) wood preservative formulations and their performance are presented. Two are double-treatment formulations in which insolubilization and precipitation of the preservative is attained by salt formation or by formation of a water insoluble Cu/NH3/DNBP complex of formula [DNBP]2 [Cu(NH3)2]2 the clarified structure of wh...
W E Conradie, A Pizzi


Heat transfer and wood moisture effects in moderate temperature fixation of CCA treated wood
1994 - IRG/WP 94-40022
Practical aspects of heat transfer and fixation of wood exposed to drying conditions after CCA treatment are considered. The rates of heat transfer and CCA fixation are substantially influenced by the cooling effect of water evaporating from the wood surface when drying occurs during fixation. At least in the early stages of fixation, the wood temperature approaches the wet bulb temperature, rathe...
J Chen, M Kaldas, Y T Ung, P A Cooper


The fate of salt preservatives in facility yard soils and decontamination of soils and drainage waters
1993 - IRG/WP 93-50001-25
Extensive studies during the past 10 to 15 years revealed that noticeable amounts of preservative components may be released in the environment by dripping off or by rain prior to fixation unless adequate precautions are taken. Therefore, soil and groundwater contamination especially from chromium-VI compounds but also from other inorganic and organic constituents exist in impregnation plants, pos...
R-D Peek, H Klipp, K Brandt


Comparative natural resistance of eighty-two timber species to damage by marine borers at Goa (India)
1996 - IRG/WP 96-10139
Natural bioresistance of eighty-two species of Indian timbers to attack by marine wood-borers has been presented based on data collected from test panels exposed in Goa waters (west coast of India) for periods ranging from five to thirteen months. All the timber species, except Artocarpus gomeziana and Pterocarpus santalinus, were completely destroyed within a short period of three to six months. ...
L N Santhakumaran


Water-based silicones on wood
1997 - IRG/WP 97-30144
Five waterbased silicones commonly used on masonry where tested as water repellents for wood. The Water Repellent Effectiveness was determined by swellometer-tests and by measuring the water uptake of samples after 24 hours complete immersion and by immersion in a water level of 4 mm for 24 hours. The different methods are compared and discussed. Artificial and natural weathering was performed to ...
D Lukowsky, R D Peek, A O Rapp


Observations on preservative penetration in poplar
1991 - IRG/WP 3662
In the course of studies on the CCA treatment and durability of poplar timber a zone of refractory wood at the sapwood/heartwood boundary was observed. Further studies were conducted to investigate the causes of this refractory behaviour. The initial results have suggested that the presence of lipid storage products in the ray tissue may lead to impermeability, either by directly blocking pits or ...
R J Murphy, S U Din, M J Stone


Status of wood preservation industry in India
2005 - IRG/WP 05-30388
The paper traces the history of wood preservation industry in India, listing various mile stones for creation of treating capacity. The preservation industry developed with the development of rail road system on the line of most other developed countries. The most popular wood preservatives are CCA, CCB, ACC, Creosote and recently LOSP have also appeared in the market. The major users of CCA is th...
S Kumar


Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process. In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Settlement of fouling organisms on CCA-treated Scots pine in the marine environment
1997 - IRG/WP 97-50094
As part of an EU project to investigate the effects of CCA loading on non-target marine fouling animals, exposure panels of Scots pine treated to 12, 24 and 48 kgm-3 CCA and untreated controls were submerged at seven coastal sites (Portsmouth, UK: Kristineberg, Sweden: La Tremblade (2 sites), France: Ria Formosa, Portugal: Sagres, Portugal: Athens, Greece). Inspections were made at 6 and 12 months...
C J Brown, R A Eaton


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