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Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura


Future Directions Regarding Research on the Environmental Impacts of Preservative-Treated Wood: Environmental Impacts of Preservative-Treated Wood. February 8-11, 2004, FL, USA Workshop – Research Needs
2004 - IRG/WP 04-50222
This paper presents a series of documents that focus on research needs for potential future work focusing on the environmental impacts of preservative-treated wood. These documents were developed through a conference sponsored by the Florida Center for Environmental Solutions (FCES), located in Gainesville, Florida. The conference was held in Orlando, Florida, February 8 – 11, 2004 and the tit...
H M Solo-Gabriele, J D Schert, T G Townsend


Bacteria are important degraders of cooling tower timbers: New Zealand experience
1995 - IRG/WP 95-10128
Microscopic examinations of CCA-treated Pinus radiata timbers in industrial cooling towers in New Zealand showed bacteria and soft rot fungi to be primarily responsible for the decay of these timbers. Of these micro-organisms, erosion bacteria appeared to be most widespread, attacking wood cell walls independently as well as together with tunnelling bacteria and soft rot fungi. Tunnelling bacteria...
A P Singh, R N Wakeling


Termites in Uruguay; control, prevention and environment
1991 - IRG/WP 1474
When Prof. La Fage's questionaire on termites was received by 1987, few were aware of termite damage in Uruguay and infestations were not much reported. Further contacts between scientists, operators and homeowners, are now shaping the real threat of termite attack. Before letting the problem faIl in the hands of the layman, with all ist environmental risks, it seemed reasonable to: 1) re...
A Aber, G Baillod


Treatment application method and CCA efficacy in Corsican pine - Assessment by serial exposure and soil burial tests
1993 - IRG/WP 93-40006
A previous report on this research (Newman and Murphy, 1992) identified possible variation in the efficacy of a CCA preservative applied to Corsican pine (Pinus nigra var. maritima) dependant upon the treatment application method (Bethel, Lowry or Steam/Bethel). This paper presents further data from biological testing of CCA treated Corsican pine using serial exposure and unsterile soil techniques...
P R Newman, R J Murphy


A note on te seasoning, preservative treatment and suitability of debdaru (Polyalthia longifolia Benth & Hooker.) for poles
1995 - IRG/WP 95-40056
The main work is to determining the suitability of Debdaru (Polyalthia longifolia Benth.) as poles from Government and Village forests are investigated. The poles of Debdaru are easily treatable with CCA preservative by full-cell pressure method, but difficult to dry (air & kiln). Proper quality control must be maintain from procurement to treatment, specially during physical selection & d...
G N M Ilias, M D Rokib-ul-Hafiz


An evaluation of the efficacy of a chlorothalonil formulation and a chlorothalonil plus chlorpyrifos formulation in the field
1993 - IRG/WP 93-30005
Details on the treatment of Pinus radiata D. Don and Eucalyptus regnans F. Muell. sapwood specimens to three retentions of each of two preservative formulations (chlorothalonil in oil; chlorothalonil plus chlorpyrifos in oil) and their installation below ground at three field test sites in Australia are given. Specimens were treated with each formulation to achieve 3.2, 6.4 and 12.8 kg/m³ of chlo...
J W Creffield, N Chew


Soluble nutrient influences on toxicity and permanence of CCA preservatives in wood
1980 - IRG/WP 3144
The influence of soluble carbohydrate and nitrogenous components concentrated at evaporative surfaces of wood on the toxicity and permanence of CCA preservatives has been examined using soil-burial techniques. Nutrient concentrations in lime (Tilia vulgaris Hayne) have been shown to be associated with reduction of toxic limits of preservatives to an extent in which a 100% increase in preservative ...
B King, G M Smith, A Bruce


Effects of deck washes and brighteners on the leaching of CCA components
1999 - IRG/WP 99-50128
Small CCA treated Southern pine decks were exposed to natural weathering and the CCA leaching characteristics determined by analyzing the collected rain drippage over several rain events. The decks were then treated with a number of commercial deck washes/brighteners and the CCA components in the wash solution compared to that from water wash only. Washes containing phosphoric acid, citric acid an...
A Taylor, P A Cooper, Y T Ung


Losses of CCA components and creosote from treated timber to soil
1997 - IRG/WP 97-50098
Components of creosote and CCA preservatives can migrate within the wood and move into surrounding soil. However, at present, the ecological significance of such losses is uncertain. This paper examines the distribution of four target polyaromatic hydrocarbons (PAHs ) and of copper, chromium and arsenic in treated stakes and surrounding soil after long term exposure in field trials. Concentrations...
N J Hudson, R J Murphy


Treatment of poplar plywood with solvent and water-borne preservatives
1989 - IRG/WP 3538
Poplar as a light hardwood is appropriate for plywood production. Owing to its low natural durability it is generally recommended to preserve it in all conditions where risks of fungal attack may be present. A research project has been carried out on preservative treatments of plywood commodities. Parameters studied were various treatment cycles, three types of plywood, and a number of solvent and...
J Van Acker, M Stevens


Comparison of methods for monitoring CCA fixation
1994 - IRG/WP 94-40023
The CCA fixation status in the outer 12.5 mm of pole sections of southern pine (Pinus sp.), red pine (Pinus resinosa) and lodgepole pine (Pinus contorta var. latifolia) were followed during fixation at 21°C under non-drying conditions by the following procedures: - Qualitative CrVI indication by the chromotropic acid spot test. - Quantitative CrVI in the expressate by the diphenylcarbazide method...
P A Cooper, Y T Ung, G Zanjani


Remediation of a large CCA-impregnation plant
1998 - IRG/WP 98-50101-13
During 1949-85 the Swedish Telecom ran a plant for pressure impregnation of poles in Hjältevad, 80 km east of Jönköping in the southern part of Sweden. About one million poles were treated with CCA-preservaties. Leaks and accidential spills have contaminated soil and groundwater within the 5 ha large site. The total amount of released arsenic, the main pollutant, is estimated to 6-7 metric tons...
P Englöv


Effect of humic acid on leaching of CCA from treated wood
2000 - IRG/WP 00-50151
Laboratory studies indicate that relatively high concentrations (1.000 - 10.000 ppm) of humic acids can increase the leaching of chromium and copper from CCA-C treated wood, and that copper is most affected. They also show that leaching with natural water samples can result in higher leaching of all components than leaching with distilled water. Evaluation of CCA component retentions and mass bala...
P A Cooper, D Jeremic, J L Taylor, Y T Ung


Marine trials with water-borne salts and organotin compound
1986 - IRG/WP 4128
Pinus sylvestris blocks treated with water-borne salts (CCA, CCB, CCF) and organotin compounds (TBTO, TBTCl) were submerged in the sea at Follonica station. The results obtained after 12 years of immersion are presented. The samples treated with CCA, CCB and CCF at the lowest concentration (2%) were destroyed after 7-9 years and the samples treated with CCB and CCF at the highest concentrations (4...
A Gambetta, E Orlandi


On the occurrence of Phialophora species in preservative treated wood in ground contact
1977 - IRG/WP 163
Phialophora is a fairly large genus comprising about thirty described species. They are widespread in very diverse environments, such as soil, sea water, wood and wood pulps. Some species are known as parasites on plants and animals, including man. Phialophora species were early known for their ability to produce blue stain in timber. Later it was discovered that several species were able to produ...
T Nilsson, B Henningsson


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 18. Report of seventh inspection (72 months) in Australia
1984 - IRG/WP 4108
This report includes the results for the 72 month inspection of the IRG/COIPM International Marine Test installed in Sydney Harbour. Although, overall, attack by teredinid and limnorid borers have been most commonly encountered in test specimens at this site, slight attack, mainly by sphaeromatids, has recently been initiated on some hitherto unattacked treated Alstonia scholaris and Pinus sylvest...
L J Cookson, J E Barnacle


A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Rainfall simulation to assess CCA permanence
1991 - IRG/WP 2373
During experimental work on accelerated fixation of chromium containing preservatives a method has been developed which compares the degree of preservative levels of contamination of simulated preservative fixation in timber with the levels of simulated rainfall. This method uses commercial sized wood sections wetted in a way that simulates actual rainfall and relates the associated run-off contam...
P Warburton, J A Cornfield


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


Preservative treatment of green timber by diffusion
1984 - IRG/WP 3291
The preservative treatment of green timber by diffusion is reviewed together with criteria which influence the economics of the process. New process options are described which should overcome some of the technical and economic disadvantages of double diffusion. These include the use of coagulating agents which increase the viscosity of the preservative solution and facilitate treatment by momenta...
P Vinden


Chemical treatment of ten Amazonian timber species of low natural durability
1991 - IRG/WP 3640
The objective of this work was to evaluate the performance of 10 amazonian wood species of low natural durability, to treatment with CCA preservative (2% concentration): it was concluded that all species studied are easily treated with this preservative. The sapwood showed high absorption and total penetration. The heartwood is relatively easy to preserve, exception to Parkia nitidae (Fava), Quale...
C S Neta, B F Vianez


Effect of test site, preservative and wood species on decay type Glenbervie pastoral and radiata pine forest sites
2000 - IRG/WP 00-30248
Pinus radiata stakes were treated with 0.8, 1.2, 1.8, 2.7 and 4.1 kg/m3 of CCA and Fagus sylvatica with 2.7, 4.1 and 6.1 kg/m3 of CCA. Both wood species were also treated with equivalent retentions of a copper plus triazole preservative (CT) (0.89, 1.3, 2 and 3 kg/m3 of copper for pine & 2.5 and 4 for beech) and chlorothalonil plus chlorpyriphos in oil (CC) (1.4, 2.1, 3.2 and 4.8 kg/m3 of chlo...
R N Wakeling


The effect of composition on the effectiveness and fixation of CCA and copper/chrome preservatives. Part 1: Effectiveness. Part 2: Selective absorption and fixation
1973 - IRG/WP 324
A preliminary study of a wide range of copper-chrome-arsenic formulations indicates that the most effective are in the region, CuSO4 · 5H2O - 35 to 45 per cent; K2Cr2O7 - 40 per cent and above; As2O5 · 2H2O - 25 to 15 per cent or less. Effectiveness appears to depend more on the copper content than the copper - arsenic. Observations on selective absorption and leaching suggest that the chromium ...
D N R Smith, A I Williams


The relationship between the electrical resistance and fixation of water-borne CCA salts and pressure-treated wood
1991 - IRG/WP 3657
Two investigations at 22°C and 30°C have been carried out. The electrical resistance in the treated wood and chemical analyses of the remaining amount of unfixed copper, chromium and arsenic were investigated. Samples impregnated with water were used as references. To hold the samples moist during the investigation, each sample was wrapped in a polyethylene plastic foil immediately after impregn...
F G Evans, B Nossen


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