IRG Documents Database and Compendium


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Soluble nutrient influences on toxicity and permanence of CCA preservatives in wood
1980 - IRG/WP 3144
The influence of soluble carbohydrate and nitrogenous components concentrated at evaporative surfaces of wood on the toxicity and permanence of CCA preservatives has been examined using soil-burial techniques. Nutrient concentrations in lime (Tilia vulgaris Hayne) have been shown to be associated with reduction of toxic limits of preservatives to an extent in which a 100% increase in preservative ...
B King, G M Smith, A Bruce


Effects of deck washes and brighteners on the leaching of CCA components
1999 - IRG/WP 99-50128
Small CCA treated Southern pine decks were exposed to natural weathering and the CCA leaching characteristics determined by analyzing the collected rain drippage over several rain events. The decks were then treated with a number of commercial deck washes/brighteners and the CCA components in the wash solution compared to that from water wash only. Washes containing phosphoric acid, citric acid an...
A Taylor, P A Cooper, Y T Ung


Losses of CCA components and creosote from treated timber to soil
1997 - IRG/WP 97-50098
Components of creosote and CCA preservatives can migrate within the wood and move into surrounding soil. However, at present, the ecological significance of such losses is uncertain. This paper examines the distribution of four target polyaromatic hydrocarbons (PAHs ) and of copper, chromium and arsenic in treated stakes and surrounding soil after long term exposure in field trials. Concentrations...
N J Hudson, R J Murphy


Treatment of poplar plywood with solvent and water-borne preservatives
1989 - IRG/WP 3538
Poplar as a light hardwood is appropriate for plywood production. Owing to its low natural durability it is generally recommended to preserve it in all conditions where risks of fungal attack may be present. A research project has been carried out on preservative treatments of plywood commodities. Parameters studied were various treatment cycles, three types of plywood, and a number of solvent and...
J Van Acker, M Stevens


Comparison of methods for monitoring CCA fixation
1994 - IRG/WP 94-40023
The CCA fixation status in the outer 12.5 mm of pole sections of southern pine (Pinus sp.), red pine (Pinus resinosa) and lodgepole pine (Pinus contorta var. latifolia) were followed during fixation at 21°C under non-drying conditions by the following procedures: - Qualitative CrVI indication by the chromotropic acid spot test. - Quantitative CrVI in the expressate by the diphenylcarbazide method...
P A Cooper, Y T Ung, G Zanjani


Remediation of a large CCA-impregnation plant
1998 - IRG/WP 98-50101-13
During 1949-85 the Swedish Telecom ran a plant for pressure impregnation of poles in Hjältevad, 80 km east of Jönköping in the southern part of Sweden. About one million poles were treated with CCA-preservaties. Leaks and accidential spills have contaminated soil and groundwater within the 5 ha large site. The total amount of released arsenic, the main pollutant, is estimated to 6-7 metric tons...
P Englöv


Effect of humic acid on leaching of CCA from treated wood
2000 - IRG/WP 00-50151
Laboratory studies indicate that relatively high concentrations (1.000 - 10.000 ppm) of humic acids can increase the leaching of chromium and copper from CCA-C treated wood, and that copper is most affected. They also show that leaching with natural water samples can result in higher leaching of all components than leaching with distilled water. Evaluation of CCA component retentions and mass bala...
P A Cooper, D Jeremic, J L Taylor, Y T Ung


Trials of new treatments for prevention of kiln brownstain of white pine (Pinus strobus)
1995 - IRG/WP 95-30068
White pine (Pinus strobus) often develops a surface brown oxidative stain when kiln dried. Such stain downgrades high quality lumber and is most likely to occur when fresh, unseasoned lumber is stacked during warm weather prior to kiln drying. Use of reducing agents or pH alteration has been successful, but may have some practical limitations for general use. This study attempted to prevent browns...
E L Schmidt, E Christopherson, T L Highley, M H Freeman


Marine trials with water-borne salts and organotin compound
1986 - IRG/WP 4128
Pinus sylvestris blocks treated with water-borne salts (CCA, CCB, CCF) and organotin compounds (TBTO, TBTCl) were submerged in the sea at Follonica station. The results obtained after 12 years of immersion are presented. The samples treated with CCA, CCB and CCF at the lowest concentration (2%) were destroyed after 7-9 years and the samples treated with CCB and CCF at the highest concentrations (4...
A Gambetta, E Orlandi


On the occurrence of Phialophora species in preservative treated wood in ground contact
1977 - IRG/WP 163
Phialophora is a fairly large genus comprising about thirty described species. They are widespread in very diverse environments, such as soil, sea water, wood and wood pulps. Some species are known as parasites on plants and animals, including man. Phialophora species were early known for their ability to produce blue stain in timber. Later it was discovered that several species were able to produ...
T Nilsson, B Henningsson


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 18. Report of seventh inspection (72 months) in Australia
1984 - IRG/WP 4108
This report includes the results for the 72 month inspection of the IRG/COIPM International Marine Test installed in Sydney Harbour. Although, overall, attack by teredinid and limnorid borers have been most commonly encountered in test specimens at this site, slight attack, mainly by sphaeromatids, has recently been initiated on some hitherto unattacked treated Alstonia scholaris and Pinus sylvest...
L J Cookson, J E Barnacle


A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Rainfall simulation to assess CCA permanence
1991 - IRG/WP 2373
During experimental work on accelerated fixation of chromium containing preservatives a method has been developed which compares the degree of preservative levels of contamination of simulated preservative fixation in timber with the levels of simulated rainfall. This method uses commercial sized wood sections wetted in a way that simulates actual rainfall and relates the associated run-off contam...
P Warburton, J A Cornfield


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


Preservative treatment of green timber by diffusion
1984 - IRG/WP 3291
The preservative treatment of green timber by diffusion is reviewed together with criteria which influence the economics of the process. New process options are described which should overcome some of the technical and economic disadvantages of double diffusion. These include the use of coagulating agents which increase the viscosity of the preservative solution and facilitate treatment by momenta...
P Vinden


Chemical treatment of ten Amazonian timber species of low natural durability
1991 - IRG/WP 3640
The objective of this work was to evaluate the performance of 10 amazonian wood species of low natural durability, to treatment with CCA preservative (2% concentration): it was concluded that all species studied are easily treated with this preservative. The sapwood showed high absorption and total penetration. The heartwood is relatively easy to preserve, exception to Parkia nitidae (Fava), Quale...
C S Neta, B F Vianez


Effect of test site, preservative and wood species on decay type Glenbervie pastoral and radiata pine forest sites
2000 - IRG/WP 00-30248
Pinus radiata stakes were treated with 0.8, 1.2, 1.8, 2.7 and 4.1 kg/m3 of CCA and Fagus sylvatica with 2.7, 4.1 and 6.1 kg/m3 of CCA. Both wood species were also treated with equivalent retentions of a copper plus triazole preservative (CT) (0.89, 1.3, 2 and 3 kg/m3 of copper for pine & 2.5 and 4 for beech) and chlorothalonil plus chlorpyriphos in oil (CC) (1.4, 2.1, 3.2 and 4.8 kg/m3 of chlo...
R N Wakeling


The effect of composition on the effectiveness and fixation of CCA and copper/chrome preservatives. Part 1: Effectiveness. Part 2: Selective absorption and fixation
1973 - IRG/WP 324
A preliminary study of a wide range of copper-chrome-arsenic formulations indicates that the most effective are in the region, CuSO4 · 5H2O - 35 to 45 per cent; K2Cr2O7 - 40 per cent and above; As2O5 · 2H2O - 25 to 15 per cent or less. Effectiveness appears to depend more on the copper content than the copper - arsenic. Observations on selective absorption and leaching suggest that the chromium ...
D N R Smith, A I Williams


The relationship between the electrical resistance and fixation of water-borne CCA salts and pressure-treated wood
1991 - IRG/WP 3657
Two investigations at 22°C and 30°C have been carried out. The electrical resistance in the treated wood and chemical analyses of the remaining amount of unfixed copper, chromium and arsenic were investigated. Samples impregnated with water were used as references. To hold the samples moist during the investigation, each sample was wrapped in a polyethylene plastic foil immediately after impregn...
F G Evans, B Nossen


The effect of chemical treatment on the moisture distribution of Pinus radiata D.Don subjected to wick action
1999 - IRG/WP 99-40135
Radiata pine sapwood stakes were treated with a range of chemicals, including an ammoniacal copper quaternary ammonium compound (ACQ), a copper-chrome and arsenic (CCA) solution and a CCA-oil treatment, potassium linoleate copper linoleate, a paraffin wax and a proprietary alkyd resin. The effect of these treatments on the extent of water absorption and moisture movement through the stakes was inv...
J Hann, P Vinden


Sphaeroma terebrans Bate: A note on distribution and preservative tolerance in Florida coastal waters
1987 - IRG/WP 4135
Treated test panels were installed in January 1984 in a Florida estuary where Sphaeroma terebrans had severely damaged pilings treated with copper chromate arsenate (CCA). Test treatments were CCA at three retentions, coal-tar creosote at three retentions, creosote with chlorpyrifos, dual treatment with CCA and creosote, and three types of chemical modification of the wood test panels. We describe...
B R Johnson, E D Estevez, S A Rice


Corrosion of fasteners in treated wood
1971 - IRG/WP 303
Surveying tests for determining the corrosion rates of some metals and alloys in wood untreated as well as treated have been made. It is shown that ordinary steel corrodes faster than other common fastener metals such as copper, brass, aluminium and stainless steel do. Zinc coatings, however, will prevent the steel corrosion effectively provided that the coatings are thick sufficiently. Catalytic ...
T Wallin


Non leachability of arsenic, copper and chromium from 15 years old CCA-C treated southern pine poles used in brackish water as jetty piles in Bangladesh
1998 - IRG/WP 98-50103
Revealed that chromated copper arsenate type C (CCA-C) treated southern pine poles used in Central Warehouse Jetty of REB, Khulna are stable and resistant to chemical and biological attack without loss of any component from outer 0-12.5 mm zone after 15y of use. Slightly reduced retention (4.44% less) was noted in above water location of piles (bottom end of tree) which would be due to continuous ...
A K Lahiry


Notes on a wood preservation industry in Medan, North Sumatera, Indonesia
1987 - IRG/WP 3405
This paper deals with a descriptive account on the development of a wood preservation industry in Medan, North Sumatera (Indonesia). The industry was established in 1974 when the State Owned Electicity Corporation decided to use wooden power poles for their distribution network in North Sumatera province. However, the use of wooden power poles was discontinued in 1981, so as the preservation indus...
N Supriana, A Murad


The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley


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