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A field trial to assess the potential of antisapstain chemicals for long-term protection of sawn radiata pine
1986 - IRG/WP 3375
Seven chemical formulations were tested as antisapstain treatments for freshly sawn radiata pine sapwood (90x50 mm²). Each formulation was used with and without a water-repellent additive and was sprayed on to 1 m long boards. The boards were then stacked into "mini" packets and stored unprotected from the weather for 6 months. Haipen 50w (at 0.2 or 0.4% active) and NaPCP (1% active) plus 1.5% bo...
J A Drysdale


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Effect of humidity and temperature on fastener withdrawal resistance from CCA and ACZA treated Douglas-fir
2000 - IRG/WP 00-20209
The effects of preservative treatment on fastener withdrawal was investigated in Douglas-fir lumber conditioned to two moisture regimes. In general, conditioning samples to 19% moisture content produced more substantial changes in withdrawal resistance of galvanized fasteners than did conditioning to 12%. Treatment had little or no effect on withdrawal resistance of stainless steel fasteners. With...
Sung-Mo Kang, J J Morrell


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Redistribution of boric acid in radiata pine during drying after preservative treatment
1993 - IRG/WP 93-40010
Samples of 100 x 50 mm² radiata pine were processed with a variety of options to produce dry, boron-treated wood. Concentrations of boric acid in the central one-ninth and in the whole of the wood cross-sections were determined by chemical analysis and compared. Diffusion treated material was dried by air, conventional kiln (70/60°C), or high temperature kiln (120/70°C). Four different predryin...
A J Bergervoet, D R Page, J A Drysdale


Analysis of the boron content of preservative treated oak and pitch pine heartwood before and after leaching
1992 - IRG/WP 92-3697
Studies to determine the effects, if any, of a variety of boron formulations on heartwood of English oak and American Pitch pine have been previously reported (King et al (1991)). Small wood blocks were treated, at 10°C or 45°C, with borax, polybor or Boracol 20 for periods of 1 month or 4 months then analysed or continuously leached with tap water for a period of 1 month. Reported results showe...
S McCutcheon, G M Smith, J W Palfreyman, B King


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


A novel method for evaluating the performance of water repellents
1987 - IRG/WP 2279
Application of water repellent formulations to timber surfaces offers protection from the weather, reducing degrade and movement. A novel test method has been developed to evaluate the comparative efficacy of such formulations when samples are exposed to weather. The method uses sapstain free sapwood of defect free, untreated, seasoned Radiata pine, (Pinus radiata D. Don.) Water Repellency was det...
A R Moffat


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


The effects of accelerated drying of green Pinus radiata on its attractiveness to Anobium punctatum as an egg-laying site
1984 - IRG/WP 1199
The methods and results are given for a series of experiments in drying Pinus radiata sapwood under a variety of conditions, then exposing the material to Anobium punctatum egg-laying. The results showed very clearly that the attractiveness of the wood to gravid females was drastically reduced when dried from green at temperatures much above 35°C. Both simple oven drying and steam kilning produce...
D J Cross


Susceptibility of heartwood of three Pinus species to attack by the subterranean termite Coptotermes acinaciformis (Froggatt)
1994 - IRG/WP 94-20026
Heartwood of plantation-grown Pinus elliottii (slash pine), Pinus caribaea (Caribbean pine) and Pinus radiata (radiata pine) was obtained from a range of locations throughout Australia and New Zealand for use in a field bioassey with subterranean termites. Timber stock was analysed for a number of stilbene and flavonoid heartwood extractive components which could contribute to variation in suscept...
M J Kennedy, L L Dixon, B C Peters


Leachability of active ingredients from some CCA treated and creosoted poles in service. A progress report after 10 years testing
1990 - IRG/WP 3627
CCA K33 TYPE B treated or creosoted poles, 10 pieces of each treatment type, have been monitored from the treatment plant to an electricity line, which was build up in Southern Finland in 1978. Preservative retention was determined by taking borings at four different levels: 1.5 m from the top end, 1 m above ground line, ground line and 0.5 m below ground. Determinations were made before setting u...
A J Nurmi


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 3. Effect of process variables on sapwood treatment and CCA fixation.
1998 - IRG/WP 98-40114
The Multiple-Phase Pressure (MPP) Process achieves treatment and fixation as combined process using hot CCA, within a 2-3 hour time-frame. Timber is treated to saturation with hot CCA using an empty cell process. During the pneumatic pressure phase, hot solution is held in the wood in an otherwise liquid-free treatment vessel until fixation is >95% complete. This report details a factorial des...
H Pearson, K Nasheri, J A Drysdale, G Durbin, M E Hedley


Bioefficacy of Cunapsol® treated western cedar and southern yellow pine
1996 - IRG/WP 96-30120
Western red cedar and southern yellow pine sapwood were dip treated with a new formulation of waterborne copper naphthenate (Cunapsol®) which complies with VOC regulations. Cunapsol dip treated samples were oven dried at 50°C for 48 hours and then water leached for two weeks. Decay resistance and leachability of preservatives from dip treated specimens were evaluated according to AWPA (American ...
D P Kamdem, M H Freeman, T L Woods


The influence of UV and IR radiation on leaching of copper and chromium from preservative-treated pine and spruce
1992 - IRG/WP 92-3687
The influence of artifical UV- and IR-radiation on the leaching of copper and chromium components of a CCB-preservative from freshly treated pine and spruce was evaluated. On small pinewood samples it could be shown, that the leaching of copper and chromium can considerabely be reduced by UV-radiation. A Philips HPA lamp type reduced the leaching most effective. IR-radiation lead to higher leachin...
H Militz


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Effects of the delay in the beginning of treatment on absorption and distribution of water-soluble salts in posts treated by sap-replacement method
1992 - IRG/WP 92-3719
One of the most important matters in green wood treatments, such as sap-replacement method, is knowing the longest time available for beginning treatment without losing efficacy. In this paper, the influence of this factor on absorptions and distribution of the preservative into the wood is analized. Tree start-up times were first chosen: 3-6 hours, 48 h and 120 h after being cut down. The treatme...
M V Baonza Merino


Diffusion treatment of gauged radiata pine timber using "Boracol 20"
1987 - IRG/WP 3437
Green gauged 100 x 50 mm radiata pine timber was preservative treated by brush application of "Boracol 20" followed by diffusion storage. Preservative retention analyses indicated that retention requirements in the core could be achieved within a six week diffusion period, thus representing a time saving of 25% over conventional boron treatment of rough-sawn radiata pine. Similar treatment of kiln...
D R Page, P Vinden, S Retter


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