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Mineralization of European oak with various ionic salt solutions to achieve an in situ precipitation of calcium oxalate
2019 - IRG/WP 19-40861
Thin specimens of European oak (Quercus spp.) with the dimensions of 4 × 20 × 50 mm3 were treated with various aqueous ionic salt solutions of calcium chloride, potassium oxalate and calcium acetate. Additionally, the oak was treated with combinations of calcium chloride and potassium oxalate, as well as calcium acetate and potassium oxalate with the aim to precipitate in situ the water insolubl...
T Franke, T S Volkmer


Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


Glued laminated poles - Progress report after 43 years of testing
2023 - IRG/WP 23-20692
In 1979, a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse in Uppsala, in the Simlångsdalen test field in south-western Sweden and in a power lane in Vuollerim in northern Sweden, in order to study their resistance against biological degradation. The test poles were treated in a two-step process. All laminations of Scots pine (Pinus sylvestris) were first...
J Jermer, M Westin, N Terziev


A six-year ground proximity trial of TRU-CORE treatments at Innisfail, Queensland
2023 - IRG/WP 23-30775
This article describes an H3 (above ground outdoor) ground proximity field trial that compares the performance against decay fungi of TRU-CORE (also known as the Buffered Amine Oxide Enhancement System) Copper Quat (CQ) with CCA and commodity Alkaline Copper Quat (commodity-CQ) treatments, all in Pinus radiata. The retentions achieved reflected commercial practice, where higher mean retentions are...
L Cookson


Challenges in managing very long-term field tests
2023 - IRG/WP 23-30779
Field testing of wood preservatives has been on-going in Petawawa, Ontario, Canada since at least 1937. Many of the treated roundwood posts from these early experiments are still in test, and include preservatives still used today, including creosote, copper naphthenate, pentachlorophenol and CCA. Performance data from selected experiments more than 50 years old are reported and we discuss some of...
R Stirling, D Wong


Outdoor performance of Tanalith® K treated timber: Dimensional stability and corrosivity towards metal fasteners
2023 - IRG/WP 23-30798
This study was carried out to investigate dimensional stability and corrosivity towards metal fasteners in radiata pine (Pinus radiata D. Don) treated with Tanalith® K to Hazard class 4 (H4) retentions in comparison with chromated copper arsenic (CCA) treated timber. For corrosion test, untreated and treated matched specimens were prepared from Australian-grown radiata pine, tested with mild stee...
G Rassam, J Hague, D Humphrey


Multi-scale Experimental Study on Self-sustained Smouldering of CCA-treated Timber Poles
2023 - IRG/WP 23-40988
While it is accepted that appropriate treatment with chromated copper arsenate (CCA) will extend the design life of wood markedly, there are concerns regarding the effect of treatment on fire performance. Smouldering combustion in CCA-treated timber infrastructure can self-sustain, destroying the timber elements, as the chromium and copper present in the CCA can act as catalysts of the smouldering...
W Wu, L Yerman, J J Morrell, F Wiesner


The potential of Wacapou (Vouacapoua americana) extracts to develop new biobased protective solutions for white woods
2024 - IRG/WP 24-20724
The valorisation of Amazonian wood residues into active chemical compounds could be an eco-friendly, cost effective and valuable way to develop wood preservatives formulations in order to enhance the decay and termite resistances of low durable wood species, by impregnation processes. Wacapou (Vouacapoua spp., Fabaceae) is a well-known Guianese wood species for its use in local wood construction ...
E Kieny, K Candelier, L Milhe, Y Estevez, C Sophie, R Lehnebach, J Damay, D Florez, E Hoël, M-F Thevenon, J Bossu


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


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