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Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


Preliminary results from the field experiment to determine the performance of preservative treated hardwoods with particular reference to soft rot. The four reference timber
1980 - IRG/WP 3164
The results given in the Tables 1-4 each refer to one of the four reference species treated with four solution concentrations of CCA as recorded from each test site. The species are: Alstonia scholaris, Betula pendula, Fagus sylvatica, Pinus sylvestris. The treatments were: Untreated, 0.66% CCA, 1.53% CCA, 3.01% CCA, 5.60% CCA. Each figure is an average of the ratings recorded for each replicate o...
J F Levy, D J Dickinson


Hardwood Field Experiment: Progress Report 1977-1986
1986 - IRG/WP 3391
The international hardwood field experiment was planned in l976 and set up in same 30 different sites around the world. The test stakes include 4 reference species common to each site and in most cases at least 2 species of local importance. It was hoped that a picture of performance of a range of economically important species would be built up and at the same time provide vital background inform...
D J Dickinson, S M Gray


The new method of detecting decay in poles
1984 - IRG/WP 2229
In 1982 the Swedish Telecoms Administration in corporation with the Swedish Dog Training Centre started to investigate the possibility of using dogs for detecting decay in poles. At present two German Sheppheards and two Labrador Retrievers are in operation and the results have up to now well fulfilled our expectations. The following results have been obtained: 1.) The dogs can with high reliabili...
A Ammer, B Svedberg


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Evaluation of the efficiency of industrial kiln type CCA fixation chambers
1996 - IRG/WP 96-40063
Six commercial CCA treating plants in Canada were assessed for the fixation efficiency of their hot air fixation chambers. The wood temperature was measured with thermocouples over the fixation period at different locations in the chamber and at the end of the fixation cycle, the degree of chromium fixation was determined by a boring leaching procedure. There was a great variation in the effective...
A Taylor, P A Cooper


Kerfing and center-boring reduce checking in CCA-treated slash pine posts
1997 - IRG/WP 97-40082
Single and double kerfing, center-boring and incising were applied to green, peeled, slash pine posts. Posts were air dried for ten weeks and assessed for the number of surface drying checks greater than 1.0 mm in width. Posts were then pressure treated with a chromated-copper-arsenate (CCA-C) preservative and exposed outdoors in a horizontal position. The number of surface weathering checks in th...
P D Evans, R Wingate-Hill, R B Cunningham


Development of software to automate the quantification of checking occurring in preservative treated wood exposed to weathering
2001 - IRG/WP 01-20228
Surface checking often disfigures the appearance of wood treated with water-borne preservatives and treatments designed to reduce such checking have been receiving increasing attention. Progress in this area has however been slowed by the lack of a method of rapidly and accurately quantifying checking at treated wood surfaces. A software package has therefore been developed which identifies, measu...
A G Christy, P D Evans


Mechanical properties of CCA-treated southern pine after post-treatment kiln drying
1989 - IRG/WP 3543
This report reviews current research dealing with the effects of waterborne preservative treatment and redrying on the mechanical properties of wood. In general, waterborne preservative treatments reduce average mechanical properties. This effect is exaggerated when treated wood is kiln-dried after treatment, especially at elevated temperatures. For lumber, recently completed research at the Missi...
H M Barnes, J E Winandy


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


Study of modulus of rupture, circumference taper, sapwood thickness and CCA treatment of Norwegian origin Pinus sylvestris poles
1994 - IRG/WP 94-20054
Nondestructive strength testing with Pilodyn (6J) of Norwegian Pinus sylvestris poles revealed effective modulus of rupture (MOR) of 54.39 N/mm² at wet conditions after CCA-C treatment and circumference measurement revealed circumference taper of 0.021 m/n. Sapwood thickness or penetration of CCA-C study revealed that 77% poles were with sapwood thickness equivalent to 39.6% of radius of poles an...
A K Lahiry, S Begum, G N M Ilias, M A B Fakir, R U Hafiz


Effect of post-treatment drying schedule on the modulus of elasticity of CCA-treated southern pine dimension stock using nondestructive methods
1987 - IRG/WP 3413
This paper describes the results from the nondestructive testing for modulus of elasticity (MOE) of southern pine (Pinus sp.) 2 x 6's treated with chromated copper arsenate and redried using three commercial kiln schedules. The data indicate that redrying CCA-treated southern pine dimension stock treated to above-ground retentions (4 kg/m³) has no deleterious effect on the MOE, regardles...
H M Barnes, S Moore


Evaluation of impact of CCA-treated wood on the marine environment
1995 - IRG/WP 95-50040-15
This paper reviews the literature relating to the potential of CCA-treated wood to affect the marine environment and outlines the compounds required for a model which could be used to predict the environemental impact of maritime construction using such timber. Marine pilings require high loadings of CCA to provide protection from marine borers. Though loadings of 32-48 kg/m³ provide long-term pr...
R M Albuquerque, S M Cragg


Effect of treatment process on performance of copper-chrome-arsenate. Part 1: Fungus cellar tests
1995 - IRG/WP 95-40045
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation, fungus cellar stakelets, 5 x 10 x 180 mm³ were cut from treated material and after leaching were exposed in unsterile soil beds in ...
M E Hedley, J Anderson, J B Foster, B E Patterson


Evaluating the performance of wood preservatives against fungi
1974 - IRG/WP 247
A compilation is made of results published by various workers for agar/block laboratory tests of the effectiveness of wood preservatives against 11 species of wood destroying Basidiomycetes and one species of soft rot fungus. Preservatives include creosote, boron, metal/arsenic mixtures, metallic naphthenates, chlorinated naphthalene, chlorinated phenols and tri-n-butyl tin oxide. The results are ...
R Cockcroft


Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling


The Disposal of CCA-Treated Wood in Simulated Landfills: Potential Impacts
2003 - IRG/WP 03-50198
Landfills are typically where CCA-treated wood is currently disposed, and will likely continue to be the primary form of management in the future. It has been shown that arsenic, copper and chromium leach from CCA-treated wood in certain situations; however, the impact of the disposal of CCA-treated wood on landfill leachate is currently unknown. The objective of this research is to examine the po...
J Jambeck, T G Townsend, H M Solo-Gabriele


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Environmental situations on wood preservation industries in Japan
1995 - IRG/WP 95-50040-21
Because of environmental civil oppinions, Ministry of Agriculture, Forestry and Fisheries in Japan, reviesed "the standards for sawn lumber" in 1994. For the possibilities of the use of preservatives out of CCA, by the using of the hazard levels, new products like ACQ, DDAC and emulsified zinc-naphthenate can be used in the standards. Since 1994, the permitable limit of the arsenic in the waste wa...
K Suzuki


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