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Retention and distribution of copper/chrome/arsenic (CCA) in pressurised sap-displaced UK grown spruce and pine
1986 - IRG/WP 3366
Increment cores were taken from UK grown Scots pine (Pinus sylvestris L.), Corsican pine (Pinus nigra var. maritima Ait), Sitka Spruce (Picea sitchensis (Bong) Carr), and Norway spruce (Picea abies (L) Karst) distribution poles treated by pressurised sap-displacement using a 1.8% copper, chrome, arsenic (CCA) solution. Each increment core was sectioned radially and the copper, chrome, and arsenic ...
P D Evans, G M Smith, B King


Examination of the Pilodyn as a non-destructive test method for detecting decay in CCA treated eucalypt poles
1982 - IRG/WP 2177
Below groundline condition of 274 CCA treated eucalypt poles comprising 13 different species was examined using 6 and 12 Joule Pilodyn units with 2 and 2.5 mm diameter pins. The data obtained was used to calculate regressions of density on pin penetration. A decrease in density was accompanied by an increase in pin penetration. The best correlation was found using the 6 Joule, 60 x 2.5 mm² diamet...
L E Leightley


The volatilization of arsenic on burning copper-chrome-arsenic (CCA) treated wood
1978 - IRG/WP 3111
Small scale burning experiments are described involving copper-chrome-arsenic treated wood. Approximately 20 per cent of the arsenic was volatilised when the wood was burned in air but 60 per cent when burned in an oxygen-enriched atmosphere, this increase is attributed to an increase in combustion temperature. Although a small increase in arsenic evolution was found with an increased concentratio...
A-J Dobbs, C Grant


Balance of arsenic and recycling
2002 - IRG/WP 02-50189
Instead of importing considerable quantities of arsenic to Europe, it would be sensible to utilize the arsenic recovered in the recycling process in the manufacture of CCA-wood, in the metallurgical industry as well as in other ways. When copper is also processed into a form easy to utilize, it may be possible to utilize chrome as well. When these developments are implemented, it can be said th...
L Lindroos


Laboratory bioassay on the termiticidal efficacy of two ACQ formulations
1999 - IRG/WP 99-30199
The termiticidal efficacy of two ammoniacal copper quaternary ammonium formulations (ACQ) was evaluated in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Five retentions (1.0, 2.0, 4.0, 6.0 and 8.0 kg/m3 of active ingredient) of each ACQ formulation (MitrexACQ and ACQ97) were assessed in sapwood specimen...
J W Creffield, A F Preston, N Chew


Initial microbial colonisation of CCA-treated, creosote-treated and untreated Pinus sylvestris L. blocks in seawater
1996 - IRG/WP 96-10171
CCA-treated, creosote-treated and untreated Pinus sylvestris sample blocks were immersed in a seawater through-flow system for periods of between 1 and 265 hours. Samples were fixed immediately on removal and examined both qualitatively and quantitatively using the scanning electron microscope. This study of primary microbial colonisation showed differences between treatments in the diversity of m...
K Sturgess, A J Pitman


Bioassays for rapid assessment of heavy metal toxicity in seawater
1998 - IRG/WP 98-50112
In evaluating the effect of CCA leachate on the establishment of fouling communities on wood exposed in the sea, three organisms were assessed as biological indicators of heavy metal toxicity. These were two macroalgae, Fucus serratus and Undaria pinnatifida. and the motile protist thraustochytrid, Schizochytrium aggregatum. The choice of these organisms for the tests carried out was based on the ...
C J Brown, R L Fletcher, R A Eaton


Ultrastructure of degraded, CCA-treated Pinus radiata wood from a marine pile
1990 - IRG/WP 1461
During an inspection of marine piles, 12 years after installation, severe degradation was noted on one of them in the vicinity of a corroded eye-bolt. The wood was dark brown in colour and tended to crumble easily. Wood fragments were examined by light microscopy and scanning and transmission electron microscopy and were also analysed for carbohydrates and lignin. Light microscopy showed numerous ...
A P Singh, M E Hedley


An evaluation of CCA, CCB and CCP preservatives using a "sandwich test"
1991 - IRG/WP 2370
The last two years has seen some important changes in standards and preservative types used in Scandinavia, which have led to a wider choice for specifiers. In order to identify those treatments suitable for replacement or reinforcement of decayed constructional timbers, it was felt necessary to modify the standard EN 113 test. Impregnated blocks were sandwiched between two untreated blocks, previ...
A P Koch, L B Sheard


The performance of CCA treatment in bamboo against decay fungi
1993 - IRG/WP 93-30027
Samples of culm wall material from young (< 6 month age) and mature (> 3 years age) culms of the bamboo, Phyllostachys virideglaucescens were treated to equivalent% w/w retentions of a CCA preservative. After fixation and leaching the treated samples were exposed to decay by Chaetomium globosum FPRL S70K, Coriolus versicolor FPRL 28A and Coniophora puteana FPRL 11E. Thin section samples of u...
O Sulaiman, R J Murphy


The effect of felling time of year on CCA fixation rate and quality of selected hardwoods
1998 - IRG/WP 98-40116
White birch (Betula papyrifera), poplar (Populus sp.) and red maple (Acer rubrum) trees were harvested in winter, in spring, before the leaves flushed, after leaf flush and later in the summer. Sapwood discs were cut from the freshly felled trees, dried and cut into 25 mm and 19 mm cubes. The cubes were pressure impregnated with CCA-C and fixed under high relative humidity and at 50°C or at room ...
Y T Ung, A Taylor, P A Cooper, D P Kamdem


Fungal colonization of CCA-treated decking
2003 - IRG/WP 03-10491
The identification of fungi isolated from CCA treated decking in Vancouver is reported. About two thousands locations were sampled from over sixty boards recovered from six decks. Wood chips from each location were placed onto four different types of media. Of the large number of isolates obtained, around 15% were obtained from the interior of the boards. The succession of colonization in CCA-...
S Choi, J N R Ruddick, P I Morris


Preliminary field and laboratory findings regarding the efficacy of a novel anti-marine wood borer agent
2000 - IRG/WP 00-10380
Blocks of sapwood of Pinus nigra were treated by vacuum impregnation with Biocide A to retentions of 0.5, 1 and 2 kg m-3. Similar blocks were vacuum-pressure impregnated with CCA to retentions of 2, 24 and 38kg m-3. The blocks were exposed subtidally in Mourilyan Harbour (Queensland, Australia). After 5 and 10 months exposure, blocks were removed, examined for superficial signs of attack by wood b...
A Praël, S M Cragg, R A Eaton


Moisture condition in treated wood exposed outdoors. A progress report after 5 years
1992 - IRG/WP 92-3720
Wood treated with water-borne preservatives, mainly CCA (copper, chromium and arsenic) and CCB (copper, chromium and boron) is often said to absorb more water than untreated wood. In laboratory tests this statement has not been confirmed (Johansson 1977). In 1986 a project was started to compare water absorption during outdoor exposure between wood stakes of pine, Pinus sylvestris L, and spruce, P...
M-L Edlund


A Soil Bed Test of the Effect of CCA Penetration on the Performance of Hem-fir Plywood
2004 - IRG/WP 04-30332
An accelerated decay test was set up to compare the performance of CCA-treated Western hemlock/amabilis fir plywood treated to meet the preserved wood foundation (PWF) retention standard with various patterns of preservative penetration. Short lengths of treated plywood and comparable untreated material were installed in a soil bed. After eleven years of exposure, the CCA treatments were all sou...
P I Morris, J K Ingram


Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH&apos;s of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are repor...
A Pizzi, W E Conradie, A Jansen


Mechanical resistance of Pinus radiata CCA treated and face jointed with PVA adhesive
1999 - IRG/WP 99-40140
Due to the increased use of Pinus radiata timber composites (laminated structural members, panels, etc), its low natural durability and the toxicity of phenol-formaldehyde type adhesives, a PVA (polyvinyl acetate) adhesive was evaluated in machined and rough CCA treated and untreated face joint samples under DIN 68602 (EN 204-205) standard for groups of requirement 3 and 4. The results showed that...
M C Rose, L Reyes, P León


A comparative study of CCA type C and B treated poles in service
1993 - IRG/WP 93-50001-05
CCA K33 type B and C treated utility poles, 9 pieces of each treatment type, were analyzed for preservative retention after 11 years in use. Borings were taking 1 m above and 0.3 m below the ground line. Also total amount of copper, chromium and arsenic was determined in soil surrounding the poles. The solubility of these active components in soil was monitored by using different leaching procedur...
A J Nurmi


Premature decay of CCA-treated pine posts in horticultural soils - An overview
1984 - IRG/WP 1241
The recent discovery in New Zealand of early decay in CCA-treated pine posts set in horticultural soils led to the establishment of a comprehensive research programme. The objectives and outline of this programme are presented together with an overview of research progress to date. Results suggest that premature decay of CCA-treated timber is restricted to material placed in highly cultivated soil...
J A Butcher


High CCA retentions and the protection of eucalypt power poles
1983 - IRG/WP 3226
Tasmanian power pole material treated to high retentions, was analysed to accurately determine the amount of CCA preservative in the timber. Material from the same disc was subsequently exposed in unsterile soil in order to determine the effectiveness of treatment. Results showed that even at high retention levels, soft-rot attack was not prevented. Fourteen further poles were sampled, but this ti...
L E Leightley, J Norton


Issues Facing Wood Preservation in New Zealand Today
2003 - IRG/WP 03-30326
In New Zealand, the three major issues facing the wood preservation industry today are: Extension of use of LOSP preservatives, chiefly tributyltin naphthenate, for treatment of products in Hazard Class H3 exposed to the weather for which LOSP have not been traditionally used. Concerns have been expressed about the long-term durability of such products. Restrictions on the use of CCA preservativ...
M E Hedley


Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


Effect of treatment process on performance of copper-chrome-arsenate. Part 2: Field stake tests
1995 - IRG/WP 95-40046
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation stakes were installed in a randomised plot in the Whaka graveyard located on the FRI campus. Stakes were inspected at yearly interval...
M E Hedley, J Anderson, J B Foster, B E Patterson


Preliminary study on relation of wood structure to copper/chrome/arsenic (CCA) distribution in kempas (Koompassia malaccensis)
1995 - IRG/WP 95-40054
Kempas had been treated with copper/chrome/arsenic (CCA) preservative using full cell process. Analysis of preservative distribution at the micro level in relation to wood structure was carried out using scanning electron microscope (SEM) and energy dispersive X-ray (EDXA) analysis. The results showed that CCA elements were detected in all wood tissues at different ratios. Distribution of chemical...
S Ani, S Salamah


Correlation between different international standard assessment procedures with termites. Part 1: Field exposure
1983 - IRG/WP 1198
Ramin treated with copper-chrome-arsenic (CCA), pentachlorophenate and lindane, each at three retentions, and three other untreated timbers were assessed in the field against Coptotermes lacteus and Nasutitermes exitiosus. Replicate specimens were exposed around five mounds of each termite species over a period of five years in south-eastern Australia. The field results provided the basis for judg...
M Lenz, C D Howick, N Tamblyn, J W Creffield, M Westcott


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