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Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


Microwave Surface Modification of Radiata Pine Peeler Cores for Preservative Treatment
2009 - IRG/WP 09-40453
Radiata pine peeler cores are classified as a by-product derived from the cores of logs left over after the veneer peeling process. The core can be potentially developed for value added solid wood products as it is abundantly available and has a constant diameter. However, the core needs to be preservative treated because of low durability in ground contact. An additional problem is that the wood ...
K Sugiyanto, G Torgovnikov, P Vinden


Utilidad práctica de mini estacas en ensayos de campo
2008 - IRG/WP 08-20395
For testing chemicals for the wood against degradation agents of biotic, known as preservatives, both testing in the laboratory and in the fields are used. Field trials (Cemetery stakes) are often accepted as more "real" whose frequency of observation is set to more or less a year in temperate climates and six months or less in tropical situations, taking into accounts the aggressiveness of the so...
O Encinas, J V Puentes, N K Sarmiento, N Mora


The natural durability and preservative treatability of 11 bamboo species
2010 - IRG/WP 10-10708
Tests on the natural durability and preservative treatability of 11 common bamboo species were conducted. The results showed that there was a linear relation between bamboo density and its preservative retention by mass, and the preservative retention of bamboo reduced while its density increased. The test also showed that there were significant differences in the natural durability of bamboos, bu...
Chen Lifang, Su Haitao, Zhang Yanjun, Wang Yuxia, He Xuexiang, Ma Hongxia, Xie Guijun


Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


Glued laminated poles - Progress report after 30 years testing
2010 - IRG/WP 10-20427
In 1979 a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse at Uppsala, at the Simlångsdalen test field in southern Sweden and in a power lane in Vuollerim in northern Sweden in order to study their resistance against biological degradation. The tests have shown that the best performance will be obtained if each lamination is treated with a water-borne pre...
Ö Bergman, J Jermer


The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston


Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher


Mould growth on wood-based materials – a comparative study
2010 - IRG/WP 10-20455
Ten different wood-based materials - preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce - were tested for mould growth according to SP method 2899 during 42 days at 90% RH and 22°C. Even though the results must be interpreted carefully, they indicate significant differences in mould resistance between the materials tes...
P Johansson, J Jermer


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Antifungal and wood preservative efficacy of IPBC is enhanced by α - aminoisobutyric acid
2010 - IRG/WP 10-30544
There is currently a need to reduce the biocide content of wood preservatives, without decreasing efficacy. The nonmetabolised amino acid analogue α-aminoisobutyric acid (AIB) acts as a translocated inhibitor of mycelial spread in basidiomycete wood decay fungi, although it does not kill the organism. Factorial combinations of AIB with either the azole fungicide tebuconazole, or 3-iodo-2-...
P Bota, E Baines, A Mead, S C Watkinson


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick


Preservative Treatment of simul (Bombax ceiba) Veneers with Hot and Cold Water Solution of borax-boric acid by Soaking Process
2010 - IRG/WP 10-40528
Veneers of simul (Bombax ceiba) were treated with different concentrations of water- borne preservatives borax-boric acid (BB) by soaking process for different time periods. In the case of hot water treatment, it was found that the average retention of preservative chemicals increased gradually with the increasing treatment period from 20 minutes to 60 minutes. Similar trend was observed in the ca...
K Akhter, Md Abul Hashem, S Akhter


Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans


Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Chapter 8 - Episode of bamboo
2007 - IRG/WP 07-10635-08
In this chapter 7 (seven) poems entitled “The Bamboo’s Preface”, “The Bamboo’s Interim”, “The Fast Growing Grass”, “The Wild Grasses”, “The Bamboo’s Episode”, “The Bamboo’s Outlook”, “The Commitment” have been composed based on the habit, nature, introduction, properties, values, outlooks, importance, uses and melodies of bamboos in Asia. The conservation a...
A K Lahiry


Chapter 10 - Preservation of muli bamboo
2007 - IRG/WP 07-10635-10
Environmentally and economically very important mulibamboo (Melocanna baccifera) grown in Bangladesh was fond to be easily pressure treatable with CCA-C at green and air dry conditions. The green and air-dried bamboo treated at same treating conditions and concentration showed 110 per cent (2.10-times) higher retention in air-dried bamboo than green one. Adequate lower retention equivalent t...
A K Lahiry


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