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Effects of pre-harvest girdling on selected properties of red pine, red maple and Eastern larch
1999 - IRG/WP 99-40137
Trees of three species - tamarack (Larix laricina), soft maple (Acer rubrum) and red pine (Pinus resinosa) - were girdled immediately below the crown,one to two years before felling. The wood from these trees was compared with wood taken from un-girdled control trees felled at the same. Sapwood and heartwood, from the controls, and from above and below the girdle of treated trees, were examined fo...
A Taylor, P A Cooper


Removing Cu, Cr and As from CCA treated yellow pine by oleic acid
2003 - IRG/WP 03-50202
In this study, CCA treated yellow pine utility poles were cut into three different dimensions and 4 different pH levels (2, 2.5, 3.5 and 5) of Oleic acid was used. The leached wood samples were collected at the end of the 1, 3, 7 and 14 days to determine the remaining Cu, Cr and As concentrations. The concentrations of Cu, Cr and As were determined by X-RF. The effects of pH, dimension and duratio...
E D Gezer, Ü C Yildiz, S Yildiz, E Dizman, A Temiz


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


Development of a commercial-scale CCA chemical sludge recycling system
1993 - IRG/WP 93-50001-19
The occurrence of fixation reactions in Copper Chromium Arsenate (CCA) treatment solutions is increased where the treatment of unseasoned and partially seasoned timbers in hot climates occurs. The by-products of the fixation reactions are predominantly insoluble chromium arsenate compounds, commonly referred to as CCA sludge. Historically, this material has been disposed of into toxic waste landfi...
A J B Butler


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


A simple field apparatus for measuring relative gaff penetration and assessing the effect of additives for improving pole climbability
2000 - IRG/WP 00-20187
A simple apparatus for measuring and comparing the relative "hardness" of utility poles is described. This "slide-hammer" gaff penetration apparatus was designed as a field testing unit to measure the depth of gaff penetration into test poles after application of a uniform and reproducible force to the gaff. The apparatus is simple to use in both the laboratory and field. Data is provided for resu...
A R Zahora


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


Effect of humidity and temperature on fastener withdrawal resistance from CCA and ACZA treated Douglas-fir
2000 - IRG/WP 00-20209
The effects of preservative treatment on fastener withdrawal was investigated in Douglas-fir lumber conditioned to two moisture regimes. In general, conditioning samples to 19% moisture content produced more substantial changes in withdrawal resistance of galvanized fasteners than did conditioning to 12%. Treatment had little or no effect on withdrawal resistance of stainless steel fasteners. With...
Sung-Mo Kang, J J Morrell


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Borate diffusion from fused borate rods in douglas-fir transmission poles
1994 - IRG/WP 94-30042
Pressure-treated utility poles have given many years of excellent service, but their lifetime is often shortened by internal decay of the untreated heartwood center, particularly in refractory species, such as Douglas-fir. This paper reports the distribution of boron from fused borate rods installed in CCA-treated Douglas-fir transmission poles. The boric acid equivalent was roughly monitored by t...
T L Highley, W Finney, F Green III


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


CCA type C depletion of Southern yellow pine utility poles
1995 - IRG/WP 95-50049
Depletion and redistribution of preservative components were evaluated on five CCA-C treated poles in service for over six years in Conley, Georgia. A statistical approach was taken in which retentions below ground were compared to retentions above ground due to a lack of initial data on individual poles. It was hypothesized that the below ground retentions should be lower than the corresponding a...
P D Osborne, R F Fox


Conforming to European standards on preservative treatment
1998 - IRG/WP 98-20150
New European standards require that specifications for the preservative treatment of timber are written in terms of the penetration and retention of preservative within the treated commodity that result from the treatment process. In order to check compliance with this type of specification, suitable methods of quantitative analysis must be available. This paper presents the results of a study by ...
E D Suttie, R J Orsler


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


The potential of high pressure pulsation processes to treat white spruce lumber with water-borne preservatives
1988 - IRG/WP 3471
Laboratory work using end sealed 4x8x46 cm³ white spruce samples has been done to explore the suitability of three variants of a 2.1 MPa pulsation process for the impregnation of white spruce with CCA. The results showed that the process improved significantly the penetration of the preservatives and reduced significantly cell collapse, when compared with the results of treatment using a 2.1 MPa ...
J P Hösli, J N R Ruddick


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