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Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Comparison of permeability at different levels of moisture content in Bornmullerian fir (Abies bornmulleriana Mattf.) and Eastern spruce (Picea orientalis L.) impregnated under vacuum/pressure through full-cell method by using CCA and CCB of different concentrations
2007 - IRG/WP 07-40366
In this study, a comparison has been made in terms of the combined, longitudinal, tangential, and radial permeability of the species of Bornmullerian fir (Abies bornmulleriana Mattf.) and Eastern spruce (Picea orientalis L.) with moisture contents of 50 % and 15 %, which were impregnated under vacuum/pressure through full-cell method by using water-borne wood preservatives (impregnation materials)...
I Usta


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Utilidad práctica de mini estacas en ensayos de campo
2009 - IRG/WP 08-20395
For testing chemicals for the wood against degradation agents of biotic, known as preservatives, both testing in the laboratory and in the fields are used. Field trials (Cemetery stakes) are often accepted as more "real" whose frequency of observation is set to more or less a year in temperate climates and six months or less in tropical situations, taking into accounts the aggressiveness of the so...
O Encinas, J V Puentes, N K Sarmiento, N Mora


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Impregnación de durmientes de quebracho blanco (Aspidosperma quebracho blanco) con preservadores cromocuproarsenicales (CCA)
2008 - IRG/WP 08-40428
CCA impregnation of railroad ties is a recent process in Argentina which has not been optimized in a commercial scale. This study analyzed the influence of treatment pressure on final retentions to optimize the impregnation process. Results showed that a 3.2% m/v solution resulted in 10.8 kg/m3 CCA retention. At 1187 kPa (12 kgf/cm2) quebracho blanco wood had an average absorption of 338 l/m3. Als...
D Gherscovic, Z Cataldi, J M Languasco


Preservación de madera en Uruguay
2008 - IRG/WP 08-30492
Uruguay has a temperate climate and predominantly gently undulating landscape which is naturally suitable for farming activities. Therefore, its economy has always been based upon them and the related industries. In the sixties, the government decided it was necessary to increase forested areas in the country. Based on different consultancies, the legal frame was built in order to promote a sustai...
S Böthig


Rehabilitación del Portón del templo parroquial de San Juan Vicario de Comanja, Michoacán, México
2008 - IRG/WP 08-40431
The pine gate of the San Juan Vicario parochial temple in the city of Comanja, Michoacan, Mexico was rehabilitated. The gate was damaged by termites, worms, fungi and weathering. Gate metallic bearings were rusted. The lower parts of the gate were the most deteriorated. For rehabilitation, galvanized steel bearings were designed and manufactured and then implemented into the building. Replacement ...
J Reséndiz Sánchez, J Cruz de León


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem


Accelerated H3 above-ground decay trials in Australia
2009 - IRG/WP 09-20411
An above-ground H3 fungal field trial was installed at five sites (3 in Australia, 2 in New Zealand), with the aim of finding a method that would shorten the time required for evaluating new preservatives and protection systems. One-quarter of the H3 preservative retentions were mostly installed, as first results suitable for registration occur when these reach 70% soundness. Chemical analysis of ...
L J Cookson, J Carr


Laboratory test of some formulations against stain and mould fungi isolated from bamboo wood
2009 - IRG/WP 09-30508
To screen the effective anti-mould formulations, fungicides such as carbendazim, tebuconazole, fludioxonil, difenoconazole, prochloraz, benomyl and 8-hydroxy-quinoline copper (copper oxine) were selected to conduct the laboratory test of fungicidal activity by method of inhibition zone against Botryodiplodia theobromae Pat., Fusarium sp., Alternaria tenuis Nees., Penicillium purpurogenum Stoll, Tr...
Xingxia Ma, Airui Sun, Mingliang Jiang, Daochun Qin


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


Tensile stress relaxation of wood impregnated in different ACQ formulations at various temperatures
2009 - IRG/WP 09-40456
The reactions between ammoniacal copper quat (ACQ) constituents and wood components were investigated by tensile stress relaxation approach. Small wood samples were stressed and impregnated in ACQ solutions with different formulation including the ethanolamine (MEA) to copper molar ratio, copper (as copper oxide) to quat (as DDAC) weight basis, treatment temperature and also the solution concentra...
Lili Yu, Jinzhen Cao


Utilidad práctica de mini estacas en ensayos de campo
2008 - IRG/WP 08-20395
For testing chemicals for the wood against degradation agents of biotic, known as preservatives, both testing in the laboratory and in the fields are used. Field trials (Cemetery stakes) are often accepted as more "real" whose frequency of observation is set to more or less a year in temperate climates and six months or less in tropical situations, taking into accounts the aggressiveness of the so...
O Encinas, J V Puentes, N K Sarmiento, N Mora


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Glued laminated poles - Progress report after 30 years testing
2010 - IRG/WP 10-20427
In 1979 a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse at Uppsala, at the Simlångsdalen test field in southern Sweden and in a power lane in Vuollerim in northern Sweden in order to study their resistance against biological degradation. The tests have shown that the best performance will be obtained if each lamination is treated with a water-borne pre...
Ö Bergman, J Jermer


Comparison of Bifenthrin Formulations for Their Skin and Eye Irritation Potential Using the Pollen Tube Growth Test
2010 - IRG/WP 10-30521
The Pollen Tube Growth Test (PTGT) is an effective screening method for measuring the potential of a chemical formulation to affect living cells. The PTGT has been compared against other types of testing, and it shows a good correlation with, for example, the Draize rabbit eye test and the human skin patch assay. It measures the EC50, which is the effective concentration at which 50% growth is o...
S Millward, P Lobb


EVIPOL® and EVIPOL®10TK - Lab and field data on the efficacy of cyproconazole and its formulations
2010 - IRG/WP 10-30539
EVIPOL® (= cyproconazole) is one of the triazoles commercially used in wood preservation. Although this active is well established in some geographical regions, little information on its efficacy against decay fungi is published yet. Therefore, threshold values derived from EN113 (after EN73 and EN84) as well as field test data (L-joint and lap-joint) are compiled. The paper focus on water diluta...
H Leithoff


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