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Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


Pre-treatment decay and strength loss of railroad ties, and their prevention
2013 - IRG/WP 13-30610
Evidence of fungal decay in air-drying, untreated railway crossties is referred to as ‘stack burn’ in the industry. The deleterious consequences of stack burn on tie mechanical properties was confirmed by evaluating the impact bending toughness of wood samples taken from untreated tie stock air dried in the southern United States. These results suggest that careful consideration should be give...
A M Taylor, B Jordan, J D Lloyd


Methylene Chloride compared with white spirit as a treatment solvent for wood preservation – results from decay and termite studies
2013 - IRG/WP 13-30611
Non-aqueous solvents have a long history in the treatment of wood products in various parts of the world. The most familiar solvent treatment is the ‘light organic solvent preservative’ (LOSP) treatment based on low density solvents such as white sprit. Until recently white spirit was the only non-aqueous solvent approved for use in wood preservation in New Zealand. Australia also permitted...
A Siraa, P Lobb, C Molloy


System treatments of Pinus sylvestris - influence on moisture, decay and discoloration
2013 - IRG/WP 13-30612
Biological activity can cause challenges for the use of wood in outdoor exposure. Decay and discolouring fungi influence the service life of wooden constructions, and the moisture content of the wood is often an important factor. The aim of this study was to evaluate the performance of different combinations of preservative/modified wood protection treatments and surface treatments for wooden deck...
A Schabacker, G Alfredsen, L Ross Gobakken, H Militz, P O Flæte


Performance testing of DMDHEU-modified wood in Australia
2013 - IRG/WP 13-30613
Chemical wood modification with dimethyloldihydroxy-ethyleneurea (DMDHEU) or its derivatives has been researched for many years and shown to be applicable to improve certain wood properties to both solid lumber and wood-based composites. Earlier research proved a high biological resistance of DMDHEU-modified wood against biological degradation in laboratory and field tests in Europe. Due to the ve...
H Militz, J Norton


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell


Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick


Copper Coating on Wood: a New Way of Protecting Wood
2013 - IRG/WP 13-30617
Thermal spray metal coating technology was used to apply a thin layer of copper on the surfaces of a number of wood species. The adhesion of metal coating to mahogany, oak, soft maple, spruce, white pine and medium density fibreboard (MDF) was evaluated by pull off adhesion test. The resistance of copper coated wood samples to mildew were assessed in the lab. Also, the decay resitance and water re...
M Nejad, R Shafaghi, L Pershin, J Mostaghimi, P Cooper


The effects of impregnation with secondary metabolite extracted from Ipe on durability of Japanese cedar and beech wood
2013 - IRG/WP 13-30618
Ipe wood is known for its high durability; it has been widely used in exterior structures that are exposed to the weather. In this paper, to increase the durability of less durable wood, Japanese cedar and beech specimens were impregnated with a secondary metabolite from Ipe. In a previous study, secondary metabolites extracted by a Soxhlet extraction method showed antifungal properties. Therefore...
T Iida, R Konuma, K Kawarada


Preparation of Copper Rosinate Emulsion and Its Resistance against Wood Decay Fungi
2013 - IRG/WP 13-30619
A leaching-resistant water-borne copper preservative was prepared by means of the following three steps: (1) Gum rosin was saponified with potassium hydroxide. (2) The soap reacted with copper sulfate to form copper rosinate. (3) The copper rosinate was emulsified with a mixture of Tween 20 and Span 80. Poplar (Populus ussuriensis) wood was impregnated with 0.5%, 1.0%, 1.5%, or 2.0% of the copper ...
Mingxin Zhang, Shujun Li, Qian Wang, Bo Li, Qiong Wu


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


Performance of untreated wood and wood impregnated with copper-ethanolamine based preservative solutions in Northern Adriatic Sea
2013 - IRG/WP 13-30623
Sea water applications of wood are among the most challenging ones. Impregnated wood is exposed to leaching and to variety of marine borers, Limnoria sp. and Teredo sp. being the most important. In the present research, durability of pine wood impregnated with copper-amine based preservative solution (Silvanolin) of different concentrations, exposed to the sea water, was investigated according to ...
M Humar, M Petrič, J Adamek, B Lesar


40 year results from the largest preservative in-ground stake trial conducted in Australia
2013 - IRG/WP 13-30624
The final results from Australia’s largest preservative in-ground stake trial are listed. There were eight test sites, six in Australia and two in Papua New Guinea. The preservatives tested include low and high temperature creosotes, PCP and various water-borne preservatives including CCA and copper chromate. The main timbers examined were sawn Pinus radiata sapwood, sawn Eucalyptus regnans hear...
L J Cookson


Effect of biodiesel on Performance of Isothiazolone
2013 - IRG/WP 13-30625
Biodiesel has a number of attractive properties, including the ability to readily solubilize a number of biocides and a tendency to reduce odors associated with other solvents such as petroleum-based diesel. Biodiesels, however, have also been implicated in reduced performance of some, but not all preservatives. It is important to assess the effects of biodiesel on each biocide. Soil block tests ...
Cheng Hua-Kang, L Jin, C Freitag, J J Morrell


Influence of selected additives on organic fungicides for control of bamboo mold fungi
2013 - IRG/WP 13-30626
In order to assess the long-term efficacy of supplemented organic fungicides in outdoor applications, additives - including the antioxidant butylated hydroxytoluene (BHT) and a UV absorber and free radical scavenger benzotriazole (BTA), were selected to mix with the fungicides propiconazole or tebuconazole. Freshly cut samples from four-year old bamboo stems were treated with combinations of the c...
Sun Fangli, B Goodell, Chen Anliang, Bao Binfu, Zhang Shaoyong


Antifungal properties and bonding of menthoxymethylimidazolium ionic liquids with Scots pine wood
2013 - IRG/WP 13-30627
Antifungal activities of five chiral ionic liquids - menthoxymethylimidazolium derivates against brown-rot decay fungus (Coniophora puteana), white-rot decay fungus (Trametes versicolor) and blue-stain fungus (Sclerophoma pithyophila) were determined using screening agar-plate method. Results from antifungal tests revealed that 1-butyl-3- menthoxymethylimidazolium chloride exhibited the stronges...
J Zabielska-Matejuk, J Feder-Kubis, A Stangierska


Performance of biocide-free preservative-protective systems modified with organosilicon compounds
2013 - IRG/WP 13-30628
The objective of the research was to determine the influence of organosilicon compounds in preservative-protective systems on the selected properties of pine wood aimed for outdoor use. The investigations were made for biocide-free systems based on alkyd resin and natural oils modified with alkylalkoxy-, amino- and glycidoxysilanes. The special attention was paid on the influence of hydrophobic pr...
B Mazela, P Hochmańska, T Krystofiak


Potential valorization of wood extractives from waste products of steam distillation of Aniba rosaeodora: antitermitic activity
2013 - IRG/WP 13-30629
Aniba rosaeodora, is a slow growing evergreens of the Lauraceae family which are indigenous over a wide range of the Greater Amazon Region (the Guianas and Venezuela, Brazilian Amazon…). The essential oil obtained from the wood has a characteristic aroma and is a long-established ingredient in the more expensive perfumes. The wood is also composed with alkaloid compounds like anibin. These compo...
N Amusant, A Digeon


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


Bioactivity of Eucalyptus camaldulensis essential oil against Microcerotermes diversus (Isoptera: Termitidae)
2013 - IRG/WP 13-30631
Microcerotermes diversus Silvestri (Isoptera: Termitidae) is the most economically destructive wood pest in structures in Khuzestan province (Iran). Chemicals such as essential oils and plant extracts that are compatible with the environment and that have high potential to be used in integrated pest management programs are extremely important. This study evaluated the repellency, contact and diges...
B Habibpour, E Shafiei Alavijeh, A Rasekh


CT scanning of decay in creosoted poles for overhead lines
2013 - IRG/WP 13-30634
Creosote-treated poles have been examined by means of CT scanning in order to investigate the nature of soft spots that have been found more frequently during the last five years in Sweden. CT scanning provides a very good picture of the interior of the poles and decay can easily be detected. It was concluded that the soft spots in most cases were caused by decay which in turn had to do with extre...
C-J Johansson, A Clang, I Johansson, G Berggren


Investigations concerning liquid absorption of six heartwood species
2013 - IRG/WP 13-40618
In order to determine the liquid absorption and the penetration different heartwood species were treated with a boric acid containing solution. Heartwood of six wood species (Fir, Spruce, Douglas fir, Scots Pine, Oak and Black locust) were used in these investigations whereby the dimension corresponds to the EN 252 format. One half of the stakes were end sealed before treatment. All stakes were im...
E Melcher, J Zwiefelhofer


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