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Assessment of the ease of preservative treatment in the less-valuable Nigerian-grown Ceiba pentandra wood
2006 - IRG/WP 06-40330
The hardwood Ceiba pentandra locally known as “araba“ in Nigeria is rarely used for structural and construction works due to its high dimensional instability, low strength and durability values. Samples (25 x 50 x 600mm) were removed from four green boards (25 x 200 x 3000mm) of this species originating from a natural forest stand in Nigeria. The sapwood and heartwood were differentiated by me...
L Awoyemi, A J Pitman


Furfurylated wood - An alternative to Preservative-treated wood
2006 - IRG/WP 06-40349
Chemically modified wood is currently being marketed as a non-toxic alternative to traditional preservative treated wood (wood impregnated with biocides). Over the last decade the authors have developed modernised processes for wood modified by furfurylation. These new systems do not add metals or halogens to the product, which is important for an environmentally acceptable product. This presentat...
S Lande, M H Schneider, M Westin, J Phillips


Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Permethrin: A Critical Review of an Effective Wood Preservative Insecticide
2007 - IRG/WP 07-30413
Permethrin is a synthetic pyrethroid used in the wood preservation industry. The generally favorable environmental profile of pyrethroids coupled with their high efficacy led to their wide substitution of the chemically resistant organochlorines dieldrin, lindane, and chlordane formerly used for protection of buildings against wood destroying organisms. Much of the research on performance of perm...
M H Freeman, D N Obanda, T F Shupe


Efficacy of chitosan in combination with GRAS (Generally Recognised As Safe) compounds as a potential wood preservative
2007 - IRG/WP 07-30414
In vitro studies were undertaken to evaluate the synergy between chitosan and selected GRAS (Generally Recognised As Safe) compounds against two sapstain fungi Sphaeropsis sapinea and Leptographium procerum. Bioassays performed on nutrient medium suggested that some of the GRAS compounds tested including sodium benzoate, potassium sorbate and ascorbic acid had a synergistic effect when combined w...
C Chittenden, K Thämelt, T Singh


Some textile auxiliaries as wood protective agents
2007 - IRG/WP 07-30417
This study evaluated some textile auxiliaries applicable for wood protection. Commercial alkoxysilane quarternary ammonium formulation and fluorocarbon based water-oil repellent were tested for their ability to provide hydrophobicity and antifungal effect to solid wood samples. Scots pine (Pinus sylvestris L.) sapwood samples were impregnated with 25, 50 and 100 % concentrations of the above menti...
E Dizman, A Temiz, N Terziev, Ü C Yildiz


Silver – The Next Generation Wood Preservative
2007 - IRG/WP 07-30419
The successful introduction and commercial use of products designed to have controlled release of silver ion over long time periods prompted the Silver Research Consortium and the US Forest Products Laboratory to undertake research to see if silver could also be an effective wood preservative to be used in place of chromated copper arsenate (CCA) now prohibited for use in the United States and els...
J R Ellis, K Jayachandran, D Nicholas


Silver as a Wood Preservative Environmental Requirements and Concerns
2007 - IRG/WP 07-30420
The pesticide uses of silver and its compounds fall under the jurisdiction of the United States Environmental Protection Agency (USEPA) under the US Federal Insecticide Fungicide and Rodenticide Act. In addition, many other national and international organizations maintain close observance of the effects of silver in different environments. The US EPA has also issued a specific announcement that t...
J R Ellis


Electrokinetic Accelerated Ingress of Boron After Surface Treatment of Wood
2007 - IRG/WP 07-40372
In this work electrokinetic acceleration of boron penetration after surface treatment is proposed in order to offer an alternative to the often low penetration rates based on diffusion. Electrodialytic experiments showed that boric acid could be transported as negatively charged complexes with tartaric acid in aqueous solutions at pH 4-5. Boric acid could not be transported when tartaric acid was ...
I V Christensen


Preservative treatment of Golla cane (Daemonorops jenkinsiana) by pressure process
2007 - IRG/WP 07-40379
The feasibility of preservative treatment of golla cane (Daemonorops jenkinsiana (Griff) Mart). by pressure process has been studied using water borne preservatives CCB (copper-chrome-boron). Cane samples of three different lengths 1m, 2m and 3 m. were treated at different pressure and time period to evaluate the extent of penetration and retention of preservative chemicals. It was observed that t...
K Akhter, M Hoque Chowdhury


Use of Moisture Meters with Treated Wood
2007 - IRG/WP 07-40382
Drying wood treated with waterborne preservatives after treatment to near outdoor EMC conditions improves its physical performance characteristics. This is primarily due to the reduced checking, splitting and warping which can occur when wet wood, particularly if restrained from shrinking by being nailed or otherwise fastened, shrinks in use. Monitoring of the drying process, rate, and end point...
W B Smith, Hwan Myeong Yeo, C Stark, B Morey, C Tascioglu, P Schneider, D Herdman, M Freeman


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


The effect of wood moisture content and rod dosage on movement of boron through Douglas-fir heartwood
2007 - IRG/WP 07-30431
The potential for moisture sorption by boron rods following application to wood to affect subsequent boron diffusion was investigated in small Douglas-fir blocks conditioned to 30, 60 or 90% moisture content (MC). MCs tended to decline over the 180 day test period, but there was no evidence that the rods acted to draw moisture away from the wood. As expected, boron movement tended to increase with...
Y Cabrera, J J Morrell


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Tropical In-Ground Durability of CCB-treated Keruing and other Structural Sarawak Timbers after 8 – 10 Years Exposure
2007 - IRG/WP 07-30439
The heartwood of 12 mainly low-durability native timber species of Sarawak [4 Dipterocarpus (Keruing) species, Anisoptera grossivenia (Mersawa kunyit), Canarium apertum (Seladah), Dacryodes incurvata (Seladah laut), Dryobalanops oblongifolia (Kapur kelansau), Mesua macrantha (Mergasing), Podocarpus micropedunculatus (Kayu cina), Shorea compressa (Engkabang langgai), and Pterospermum javanicum (Ba...
A H H Wong, Ling Wang Choon


The effect of brighteners on wood surface aesthetics – exploring the use of various organo-phosphonates based precursors
2007 - IRG/WP 07-30441
Freshly cut hardwood lumber such as white oak, red oak, beech, or redwood are rich in mineral stain (mostly iron and calcium), which provides a strong discoloration of the wood surface significantly influencing the aesthetic of the wood surface and strongly affecting the cost of this lumber. The influence of mineral stain on soft wood discoloration (Southern Yellow Pine, Douglas fir, etc.) is les...
R Craciun, P Mitchell


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating. Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi


Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj


Preliminary evaluation of efficacy of copper in combination with boron and NHA (N'-N-(1, 8-naphthalyl) hydroxylamine) against wood decay
2008 - IRG/WP 08-30452
In this study, efficacy of various combinations of copper sulfate with either boric acid or calcium precipitating agent, NHA-Na (N'-N-(1, 8-naphthalyl) hydroxylamine) was evaluated. Wood specimens were treated with either 1%, 0.5%, or 0.1% concentrations of copper sulfate, boric acid, NHA-Na, copper sulfate + boric acid, or copper sulfate + NHA-Na mixtures. Treated specimens were subjecte...
E Terzi, C Köse, S N Kartal


Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


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