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The impact of catalyst on the properties of furfurylated beech wood
2016 - IRG/WP 16-40748
European beech (Fagus sylvatica L.) is a major tree species of European forest that is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic ...
P S Sejati, A Imbert, C Gérardin, S Dumarçay, E Fredon, E Masson, D Nandika, T Priadi, P Gérardin


Prevention of fungal damage of oil and date palm wood by organic acids
2017 - IRG/WP 17-10877
Felled palm trunks are susceptible to fungi as long as their moisture content is above fibre saturation. During this period, palm wood has to be protected against mould and rot fungi. Environmental-friendly organic acids are suitable. Small samples of oil palm (Elaeis guineensis) and date palm (Phoenix dactylifera) wood were treated with 1 to 10% solutions of acetic acid and propionic acid, respec...
M Bahmani, O Schmidt


Evaluating the role of Actinobacteria in the gut of wood-feeding termites (Reticulitermes spp.)
2017 - IRG/WP 17-10880
Nitrogen has been shown to be a limiting nutrient across a range of xylophagous insects. These insects often rely on symbiotic microorganisms in the gut for nitrogen acquisition, via fixation of atmospheric nitrogen or break down of other available nitrogenous substances. In phylogenetically lower, wood-feeding termites, the role of nitrogen fixing bacteria has been well studied. However, there is...
Evaluating the role of Actinobacteria in the gut of wood-feeding termites (Reticulitermes spp.)


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Encapsulation of chlorothalonil with polylactic acid using nanoprecipitation method for rubberwood preservation
2018 - IRG/WP 18-30722
Wood is a very beneficial material for humankind. The current trend is employing organic biocides as wood preservatives to inhibit the wood from biodeterioration caused by fungi and termite. However, these organic biocides are facing some shortcomings when being introduced into the wood using conventional water-based treatment due to their poor water solubility. Polylactic acid (PLA) was employed ...
T-J Teng, M N M Arip, R Kadir, E-P Ng, H-L Lee


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


A summary of decay performance with citric acid and sorbitol modification
2020 - IRG/WP 20-40898
Application of wood-based products as construction materials is one piece of the big puzzle to mitigate climate change. Wood is susceptible to biological deterioration. Environmentally motivated legislation is making the use of biocides less attractive from a commercial perspective. Ideally, a wood modification technology should be of low cost, water based and make use of thermal curing. This rese...
G Alfredsen, E Larnøy, G Beck, J Biørnstad, L R Gobakken, C A S Hill, A Treu


Macro biological degradation of wood treated with sorbitol and citric acid – first results from marine environment and termite exposure
2020 - IRG/WP 20-40901
Most European wood species are rapidly and severely degraded in termite-infested areas and the marine environment. There is a need for new solutions, especially in the marine environment, since we lack wood preservatives approved for marine applications in Europe. Several wood modification systems show high resistance against both marine borers and subterranean termites. However, the existing comm...
A Treu, L Nunes, E Larnøy


Durability against fungal decay of sorbitol and citric acid (SorCA) modified wood
2022 - IRG/WP 22-40928
Most European-grown wood species are susceptible to biological degradation, specifically, they suffer from a poor resistance against wood-destroying fungi. Therefore, prior to outdoor exposure, wood has to be treated either by applying a protective coating on its surface or by full-volume impregnation with antifungal chemicals. However, due to environmental and health concerns, the most frequently...
K Kurkowiak, L Emmerich, H Militz


CIOL®-protection of wood – an update
2022 - IRG/WP 22-40932
Most commercial wood species from the northern European region are of low natural durability. Products from these wood species for outside applications need therefore protection to increase their service life. This protection should be free of biocides, come from renewable resource, have great performance and hold a low consumer price. A mixture of water, sorbitol and citric acid has the potential...
A Treu, E Larnøy, J Biørnstad


Biocomposites based on PVA, cellulose nanofibrils and tannic acid
2022 - IRG/WP 22-40957
Biocomposite films based on a polyvinyl alcohol (PVA) with the addition of cellulose nanofibrils (CNF) as a reinforcing component and with the addition of the biologically active tannic acid (TA) were prepared. The influence of different additions of CNF and TA in the polymer matrix PVA on the mechanical properties, improvement of hydrophobicity of the prepared films was studied. In all cases, the...
U Osolnik, V Vek, I Poljanšek, Poven


Sensitivity of copper indicators for detecting preservative penetration
2023 - IRG/WP 23-20701
Chrome azurol S (CAS), 1-(2-pyridylazo)-2-naphthol (PAN), and rubeanic acid (RA) are the three copper indicators currently used by the timber industry to assess preservative penetration. Although only the American Wood Protection Association (AWPA) standards specify indicator sensitivity, it is unclear how those limits were developed. The sensitivity of each copper indicator was determined in solu...
T Yi, J Norton, S Meldrum, J J Morrell


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


Biological durability and wood-water interactions of sorbitol and citric acid modified wood – Effects on the expected service life
2023 - IRG/WP 23-40960
A high level of research activities on sorbitol and citric acid (SorCA) modified wood has been recognized in Europe over the last few years. As this treatment is close to entering an industrial-scale production, it is of interest to investigate how such treated wood performs upon long-term outdoor exposure. Hence, in this study Scots pine (Pinus sylvestris L.) sapwood was modified with aqueous sol...
K Kurkowiak, L Emmerich, H Militz


Investigating the fire properties of a composite material made of MDF-residues, citric acid and sorbitol
2023 - IRG/WP 23-40969
In times of climate change and a shortage of energy and raw materials, it has become apparent, that material reuse of wood in a cascade system can reduce the ecological impact of a material and be cost effective. A new composite material has been developed made from citric acid, sorbitol, water and waste MDF. Not only will there be a material reuse option for waste MDF but due to the small particl...
P T Lewandowski, W Perdoch, E Larnoy, H Militz


Suberinic acid from birch bark and its suitability in wood protection
2024 - IRG/WP 24-20708
This study investigated the effect of different concentrations of suberinic acid (SA) on the growth of two fungi species. Initial radial growth tests showed a slightly slower growth rate for brown rot, whereas white rot exhibited faster growth than the untreated reference. In contrast, a commercial wood preservative significantly reduced the radial growth of both fungi species. Evidence of cell wa...
A Treu, M Altgen, J Rizikovs


Effects of phosphoric acid and diammonium phosphate treatments on the physical and fire-retardant properties of five selected Nigerian wood species
2024 - IRG/WP 24-20713
Wooden products in buildings are major sources of fuel for fire outbreaks. Effects of phosphoric acid and diammonium phosphate treatments on the physical and fire-retardant properties of wood species commonly used in buildings were evaluated. The timber species utilized in this study were sourced from the sawmill sector located in Akure, Nigeria, encompassing Brachystegia laurentii, Khaya ivorensi...
J Owoyemi, T O Akinwamide, O M Ibrahim, E A Iyiola


Physical, durability and chemical characterization of Gmelina arborea (Roxb.) wood treated with lactic acid
2024 - IRG/WP 24-30803
The increase in demand for durable wood has drawn attention to the use of fast-grown plantation species across the globe. Chemical modification was used to treat Gmelina arborea wood with lactic acid for property enhancement. The treated samples were obtained from two different ages of 15 and 10 years and sawn into (20 x 20 x 60) mm and (20 x 20 x 20) mm for physical, durability and chemical chara...
T O Akinwamide, J M Owoyemib, E A Iyiolac


Citric acid and sorbitol treatment: A comparative study of Canadian and Norwegian species
2024 - IRG/WP 24-30806
Dimensional instability can reduce the competitiveness of wood in exterior applications such as cladding and decking. The objective of this work was to evaluate the dimensional stability of permeable and refractory softwoods from Europe and North America modified via a sorbitol and citric acid treatment. White spruce and Norwegian spruce, refractory species, and jack pine and Scots pine, relativel...
D Schorr, Erik Larnøy, R Stirling, G Boivin


A novel treatment for increasing UV stabuility of wood based on citric acid and urea
2024 - IRG/WP 24-30811
Wood, a fundamental material in the Built Environment, faces challenges related to durability and weathering, notably UV degradation leading to colour changes. This study explored a novel treatment method utilising citric acid and urea to enhance the UV stability of wood. The reaction between these compounds forms fluorescent species and insoluble nanoparticles upon thermal treatment. Two treatmen...
S Jué, A Scharf, C-F Lin, R Moutou Pitti, D Sandberg, D Jones


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