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Design, synthesis, characterisation and effectiveness of ‘Locked-in-Boron’ chemicals for H3.2 level of wood protection
2011 - IRG/WP 11-30577
Boratrane molecules with five-membered and six-membered molecular ring systems, and with various ring substituents were synthesised, characterised and formulated for wood treatment for accelerated laboratory bioassays using wood decay fungi as test organisms. Six-membered ring boratranes showed lower efficacy in laboratory assays than five-membered ring boratranes. One alkyl-substituted boratran...
R Franich, H Kroese, S Gallagher, S Hill, B Kelly, G Billett, R Meder, W Rae


Ambient-temperature borate dip-diffusion treatment of green railroad crossties
2011 - IRG/WP 11-40556
In the USA, borates are increasingly being applied prior to air seasoning and creosote treatment of railroad ties (railway sleepers). Borates are typically applied to green ties by vacuum pressure application at 1 to 10% disodium octaborate tetrahydrate (DOT) concentration or by traditional dip-diffusion treatments at elevated temperatures. Higher temperatures are used to maintain the 30 to 50% so...
Jae-Woo Kim, A M Taylor, C Köse


Performance of boron diffused wood products used indoors for 144 months in Bangladesh
2012 - IRG/WP 12-30581
In this service performance study of boron diffused hardwoods, boron in the form of boric acid (H3BO3) was applied separately through paste and through wet cloth. The born diffused woods were kept indoors for 144-months in Bangladesh to ascertain the performance of treated wood against wood destroying insects. The new easy application processes of cost effectual boric acid have been found effectiv...
A K Lahiry, T Lahiry


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


Preparation of Copper Rosinate Emulsion and Its Resistance against Wood Decay Fungi
2013 - IRG/WP 13-30619
A leaching-resistant water-borne copper preservative was prepared by means of the following three steps: (1) Gum rosin was saponified with potassium hydroxide. (2) The soap reacted with copper sulfate to form copper rosinate. (3) The copper rosinate was emulsified with a mixture of Tween 20 and Span 80. Poplar (Populus ussuriensis) wood was impregnated with 0.5%, 1.0%, 1.5%, or 2.0% of the copper ...
Mingxin Zhang, Shujun Li, Qian Wang, Bo Li, Qiong Wu


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Potential for using boron for mitigation of Phytophthora ramorum in Douglas-fir logs
2014 - IRG/WP 14-30643
Phytophthora ramorum is a relatively newly described pathogen present in the forests of Northern California and southwest Oregon in the United States. This organism has an extremely wide host range, including a number of commercial important conifers, among them Douglas-fir (Pseudotsuga menziesii). The continuing expansion of the range of P. ramorum will result in an increasing quarantine area w...
J M Hulbert, J J Morrell E M Hansen


Potential for migration of boron from fused boron rods used as internal remedial treatments of utility poles
2014 - IRG/WP 14-50301
The distribution of boron in Douglas-fir utility poles and in the surrounding soil was assessed over a 54 month period following application of fused boron rods. Boron levels in the wood never reached the levels that might be predicted if diffusion were to produce a uniform chemical distribution, nor did levels in the soil suggest that boron was becoming more concentrated. The results suggest th...
M Konkler, C Freitag, C S Love, J J Morrell, J Renfroe


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Leachability and Dimensional Stability of Nanosilver-Steamed Densified Poplar
2014 - IRG/WP 14-40684
This study was aimed to investigate leachability and dimensional stability of nanosilver impregnated poplar (Popolus alba), steamed before hot compression. Wood samples were impregnated with nanosilver suspension (200 and 400 ppm) under pressure of 4 bar for 20 minutes. Steam treatment was carried out at 150°C for 2 hours. Then samples were compressed (33%) radially in a hot press at 170°C for 3...
G Rassam, A Talaei, A Ahmadi


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Remedial treatment of difficult to access timber in buildings
2015 - IRG/WP 15-40691
The quest to understand remedial treatment for timber framing begun following the ‘leaky building crisis’ in New Zealand which came to prominence in 2000. Several in-situ remedial treatment products are used in New Zealand. However, effectiveness of these treatments is still unclear particularly in situations where not all faces of the timber can be assessed. This research was conducted to det...
T Singh, I Simpson, D Page


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


The durability of manufactured structural building materials
2016 - IRG/WP 16-40718
The projected market potential for Engineered Wood Products such as CLT (cross laminated timber) is very positive however, potential prolonged rain leakage or moisture exposure during construction and in-service could pose considerable concern for its durability and reputation. This research was conducted to assess the decay resistance of CLT and OSB (oriented strand board) in an accelerated trial...
T Singh, D Page


State of Nanocopper Fixation by Steam-Densification
2016 - IRG/WP 16-40723
This study was aimed to investigate the effect of steam treatment before densification on leachability and dimensional stability of nanocopper impregnated poplar (Popolus alba). Wood samples were impregnated with nanocopper suspension (200 and 400 ppm) for 20 minutes under 4 bar pressure. Steaming process was done before densification at 150°C for 2 hour. Radial densification (33%) was done conse...
G Rassam, A Talaei, A Ahmadi


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Copolymers of tannin extracts as wood protection agents
2017 - IRG/WP 17-30709
Wouldn´t be a dream to preserve wood with the substances which the nature already synthesizes for protecting itself? The idea we would like to pursue is simple: Increase the concentration of these substances, the tannins, trying to fix them properly in wood. It appears easy but it is not. Sensibility against leaching, fungal decay and weathering were observed. In this paper new flavonoid co-polym...
G Tondi, L Sommerauer, A Oberle, A Petutschnigg, M-F Thevenon


Five-year evaluation of a field trial of Eucalyptus grandis poles treated with zinc and boron
2017 - IRG/WP 17-30721
Round Eucalyptus wood treatment in sequential stages with inorganic borates and metal salts (zinc sulfate and boric acid+borax) was studied; the aims were to form an insoluble precipitate of zinc borate inside wood and to reduce treatment costs by performing the first treatment by simple ascent and diffusion of the preservative, at the same time as it was sought to impregnate the heartwood. The se...
C Ibáñez, A Camargo, C Mantero, M Rabinovich


Effects of wood protecting biofinish and linseed oil on fire behaviour and leachability of the fire retardant
2018 - IRG/WP 18-30728
A wood protecting biofinish is based on a protective and decorative fungal-based coating and a linseed oil impregnation (called Xyhlo biofinish). This biofinish enables the long-term use of wood in outdoor applications without using toxic chemicals. The fire resistant properties of materials used in buildings are very important. Since Xyhlo biofinish is relatively new, only little information is ...
S Rensink, E J van Niewenhuijzen, M F Sailer


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