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Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Field evaluation of the above-ground susceptibility of Pinus heartwood and untreated or treated sapwood to two species of Australian subterranean termites
1996 - IRG/WP 96-10147
Plantation-grown Pinus elliottii, Pinus caribaea and Pinus radiata specimens containing heartwood and untreated or preservative-treated sapwood were exposed above ground to the subterranean termites Coptotermes acinaciformis or Mastotermes darwiniensis near Sydney (NSW), Brisbane and Townsville (Qld), and Darwin (NT), using a variety of exposure techniques. Heartwood of Pinus elliottii and Pinus c...
M J Kennedy, J W Creffield, R H Eldridge, B C Peters


Determination of boron levels in solution and in treated wood
1994 - IRG/WP 94-20041
Four methods of measuring boron levels in solutions were investigated. The methods compared included the azomethine-H method which is commonly used in soils and plant tissues, the methods outlined in the Australian Standard AS 1605 (1974) and in Wilson (1958), and the atomic absorption spectrophotometry method. Defect-free radiata pine (Pinus radiata D. Don) sapwood and wood flakes were treated to...
F J Romero, P Vinden, P Kho


Soil treatment tests with the three products of boric acid for the prevention of the hyphal growth of Serpula lacrymans
1992 - IRG/WP 92-3693
Laboratory soil treatment tests were conducted for the evaluation of fungicidal or fungistatic effect of boric acid products against Serpula lacrymans. Boric acid products tested were the following three: a thickened boric acid solution in triethanolamine, boric acid-silica gel complex granules, and a nonwoven fabric laminated with a polypropylene film and coated with boric acid granules on one si...
S Doi, A Yamada, Y Mineki, M Mori


An environmental aspect relating to leachability of CCA from hardwood and softwood poles in Bangladesh
2001 - IRG/WP 01-50167
Leachability of CCA and the service performance of 8 softwood and 5 heartwood poles in service after 5 to 17 years in Bangladesh have been studied. The study included determination of retention of CCA-C in outer 6 mm zones at groundline (GL) and above groundline (AGL) along with the observation of decay and conditions of soils. The mean leaching of CCA-C derived from retention differential at GL a...
A K Lahiry


Five years leaching of Boron
1999 - IRG/WP 99-30195
The diffusibility of Boron in wood and thus its leaching behaviour in water contact is known since long. Nevertheless quantitative data on the long-term leaching behaviour are rare. Consequently, field exposure tests were started with beam-segments treated with pure boric acid and with poles treated with CCB. Detailed data of more than five years of field exposure are now available. Pure boron tre...
A Peylo, H Willeitner


Reduction of preservatives leaching from wood by the application of animal proteins
2005 - IRG/WP 05-30387
The investigations consisted in the estimation of the effectiveness of protein borates and protein propionates in wood preservation against Coniophora puteana. The estimation was made on the basis of mass losses caused by the test fungus action against treated wood which was subjected to leaching with water. The investigations were performed for Scots pine wood (Pinus sylvestris L.) treated with p...
B Mazela, I Ratajczak, M Bartkowiak


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Formation of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) during the combustion of impregnated wood
1995 - IRG/WP 95-50040-19
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) a...
T Salthammer, H Klipp, R-D Peek


The influence of drying and chemical stress on the lignin degradation in aspen by Phanerochaete chrysosporium
1992 - IRG/WP 92-1573
Wood wafers of Populus tremuloides sapwood were incubated on common media with the white rot fungus Phanaerochaete chrysosporium (wild isolate) and subjected to cyclic drying or chemical agents (low levels of borate or trifluoperazine [a calmodulin antagonist]). After a mass loss of approximately 5.5%, wafers were dried and analyzed for acid-insoluble lignin. Those wafers containing chemical agent...
E L Schmidt, Y-L Lin


Preservative treatment of rubber wood (Hevea brasiliensis) to increase its service life
2005 - IRG/WP 05-40320
Rubber wood (Hevea brasiliensis) possess excellent properties for interior designing, wood working and furniture making. But it is very much susceptible to sap stain and mould fungi which decreases the service life. For profitable uses , it is necessary to increase the service life of rubber wood. To protect the rubber wood from wood degrading agents, the sawn timber were treated with Borax – b...
K Akhter


Influence of surface coating on the leachability of boric acid and bifluorides from spruce wood
1995 - IRG/WP 95-50050
In the Netherlands, window joinery made from non-durable timber species (spruce) are widely protected with preservative rods. These rods contain non-fixing wood preservatives (e.g. bifluorides or boric acid). This reseach was performed to show the possible influence of a coating system to hinder the leaching of the active ingredients. The results of the leaching tests show, that bifluorides and ev...
W J Homan, H Militz


Microemulsion formulations for wood protection chemicals
1993 - IRG/WP 93-30030
A microemulsion is a thermodynamically stable oil-water dispersion system. As a formulation it provides many unique features such as water compatibility for water-insoluble chemicals, formulation stability, good bioavailability and environmental acceptance. This paper discusses the major criteria for the formulations of water-insoluble wood biocides and the comparison in properties between convent...
Bing Yu, L E Leightley


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Decay and termite resistance of wood treated with boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
2004 - IRG/WP 04-30334
This study evaluates the decay and termite resistance of surface-treated wood with didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin emulsion. DBF is a quaternary ammonia compound and contains boric tetrafluoride (BF4-) as a counter ion in its chemical structure. In the study, DBF was incorporated with an acryl-silicon type resin to increase water-resista...
S N Kartal, W J Hwang, K Shinoda, Y Imamura


Effect of thickened boron in preventing conidial germination of sapwood-inhabiting fungi
1994 - IRG/WP 94-30059
We evaluated the efficacy of thickened boron preservative "Diffusolä" in preventing conidia germination of sapwood-inhabiting fungi using plate bioassay, Southern Yellow Pine and sweetgum block tests, and green pine log sections. The test fungi were sapstain fungi Ceratocystis coerulescens, Ceratocystis minor, and Aureobasidum pullulans and mold fungi, Aspergillus niger, Penicillium spp, and Tric...
S C Croan


BG- an easiest preservative paste and its effective diffusibility in timbers for indoors and outdoors uses
2001 - IRG/WP 01-30253
After application of a newly formulated paste "BG-1" on all surfaces of air-dried lumbers, the boron have been found diffused completely in permeable and impermeable hardwoods at the rate of 12 mm radial thickness per week. The new paste may be a solution to protect lumbers being used or to be used under cover where timber is susceptible to termite and borer attack. The new cost effective paste wa...
A K Lahiry


The efficacy of polymer/preservative treatments in soil-bed exposure
1992 - IRG/WP 92-3729
Southern pine was treated with CCA, CCB, sodium borax/boric acid, or disodiumoctaborate, alone or in combination with an acrylic polymer system containing a water repellent. Treated samples were subjected to an unsterile soil burial test. The addition of polymer reduced the weight loss in borontreated samples at the lower retentions but not at the higher retention. Results with borates indicate th...
R J Murphy, H M Barnes, S M Gray


Leaching of Boron - more than 3 years of field exposure
1997 - IRG/WP 97-30143
The diffusibility of Boron in wood and thus the ability of its leaching is known since long. Nevertheless quantitative data on this process are only rarely available. To overcome this lack of information field exposure tests were started with beam-segments treated with pure boric acid and poles treated with CCB. In addition some of the beam-segments were surface-treated with a varnish to investiga...
A Peylo, H Willeitner


Dip diffusion treatments in the tropics. A preliminary report
1973 - IRG/WP 316
Diffusion treatments based on the use of boric acid alone or in combination with other preservatives are widely used in Australasia (see IRG/WP/310). As part of a general survey covering both temperate and tropical countries, a survey of diffusion treatments in South East Asia, Southern Asia and the South Pacific was carried out, and the results of this survey are reported here. The survey is far ...
C R Levy


Protection of rubberwood timber. Part 1: Impregnation with boron preservatives
1989 - IRG/WP 3551
Rubberwood (Hevea brasiliensis) were treated with a 3% proprietary mixture of borax/boric acid using three different treatment schedules i.e. full-cell, full-cell to refusal and full-cell with 12 cycles of vacuum/pressure. Freshly cut samples had mean preservative retentions of 187 kg/m³, 214 kg/m³ and 178 kg/m³ respectively. Pre-air dried samples for one week had retentions of 252 kg/m³, 308 ...
L T Hong, C C K Liew


Gaseous boron treatments of wood and wood products
1992 - IRG/WP 92-3691
Treatment of wood and wood products by gaseous organoborates has now been under study for about 5 years. This technique has potential for boron treatment of a wide range of substrates from solid wood through to wood composite materials such as particleboard or wet and dry formed fibreboards. The vapour treatment technique is proving to be very flexible in that it can be adapted to integrate into a...
A J Bergervoet, R Burton, K Nasheri, D R Page, P Vinden


Fire retardant treated wood and plywood: A comparative study Part III. Combustion properties of treated wood and plywood
2002 - IRG/WP 02-40236
The fire retardant treated and untreated plywood and alder wood samples were prepared with the aim to investigate the effects of the way of treatment on the combustion properties. Alder wood was used for the preparation of plywood. Boric acid and borax were used as fire retardant. The plywood samples were impregnated by using three different methods; first group samples were impregnated by soaki...
S Çolak, A Temiz, Ü C Yildiz, G Çolakoglu


Development of threshold values for boron compounds in above ground exposures: Preliminary trials
1998 - IRG/WP 98-30179
Boron is increasingly used both as an initial and remedial treatment for protecting wood against fungal and insect attack. While establishing lethal dosages for boron against insects through feeding tests is relatively simple, establishing thresholds for fungal attack poses more of a challenge. Tests using boron dispersed in agar artificially surround the fungus with both boron and excess nutrient...
J J Morrell, C M Freitag, S Unger


Economical schedule for boron treatment of rubber wood: Pilot plant investigations
1993 - IRG/WP 93-40002
An economical treatment schedule (15 minutes initial vacuum of 85 kPa; 15 minutes pressure of 1000 kPa; 5 minutes final vacuum of 85 kPa) was arrived at for treating air-dried rubber wood (Hevea brasiliensis) in a pilot plant cylinder. Treating with 3% BAE (boric acid equivalent) solution resulted in a dry salt retention of 13.1 kg/m³. Also, the study showed that green rubber wood can be treated ...
R Gnanaharan, T K Dhamodaran


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