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Determination of total fluoride and boron in preservative-treated wood fluoride by ion selective electrode without steam distillation, and boron colorimetrically using azornethine-h
1998 - IRG/WP 98-20135
An analytical method was developed to determine total fluoride and boron in wood treated with aqueous or solid diffusing fluoride or borate-fluoride formulations. Ground wood was mixed with 30% sodium hydroxide solution and oven-dried for 2 hours before furnacing at 600° C for 1 hour. The cool fused product was dissolved in hot water, transferred to a plastic beaker and neutralised. Fluoride was ...
P A Collins, M J Kennedy


Bending & tensile properties of vapor boron-treated composites
2002 - IRG/WP 02-40228
North American composites including laminated veneer lumber, oriented strandboard, and medium density fiberboard were treated by vapor boron technology and subsequently tested in static bending. Tensile properties were also determined for the two composite boards. The study was designed as 3 x 2 factorial with three treatment levels and two mill locations for each composite type. In general, mil...
H M Barnes, R J Murphy, B K Via


Comparison of the effects of borate, germanate and tellurate on fungal growth and wood decay
1992 - IRG/WP 92-1533
The tetra-hydroxy borate ion is known to undergo complexation with polyols and has been shown to inhibit dehydrogenase enzymes in this way. It has been previously suggested that this complexation is responsible for the inhibition of fungal growth and the protection of boron treated timber. Other ions that have the ability to complex with polyols have also been shown to inhibit dehydrogenase activi...
J D Lloyd, D J Dickinson


A chemical and mycological evaluation of fused borate rods and a borate/glycol solution for remedial treatment of window joinery
1983 - IRG/WP 3225
The possibility of using fused borate rods (Impel Borpatron) and a borate/glycol solution (Boracol-40) for depot impregnation of window joinery has been examined in a co-operative project between The Swedish Forest Products Research Laboratory, The Swedish University of Agricultural Sciences and Prolignum AB. The fused Impel rod is a glassy rod composed of disodium octaborate which readily dissolv...
M-L Edlund, B Henningsson, A Käärik, P-E Dickèr


Chemical evaluation of borate treated pine sapwood attacked by the subterranean termite Coptotermes acinaciformis
1993 - IRG/WP 93-20003
Sapwood of hoop (Araucaria cunninghamii Ait. ex D. Don) and slash (Pinus elliottii Englem.) pines were treated by Vacuum Pressure Impregnation (VPI) to provide test specimens. The concentration of boron was defined by chemical analyses of the timber, in the zone of primary attack by the termite being bioassayed. A common method of definition of preservative retention, weight uptake of preservative...
A R Moffat, B C Peters


Field testing of alkylammonium wood preservatives
1983 - IRG/WP 3248
The field test performance of five alkylammonium wood preservatives is described. The relative effectiveness of three unmodified formulations was determined by calculation of a Performance Index. Of the three, didecyldimethylammonium chloride was found to be superior to octyldecyldimethylammonium chloride, and both were more effective than alkyltrimethylammonium chloride. However, none were consid...
J N R Ruddick


Inorganic preservatives in wood dust - Cause of nasal cancer?
1997 - IRG/WP 97-50085
Since 1985 dust particles from beech and oak trees have been classified by the Senate Commission of the German Research Council (DFG) as being ,,working materials which are definitely carcinogenic to humans". All other wood dusts, including those from softwoods, are classified as being materials ,,with reasonable suspicion of carcinogenic potential". The carcinogenic principle of action continues ...
A O Rapp, K Brandt, R-D Peek, U Schmitt


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


Observations on the performance of copper-based wood preservatives in fungal cellar (soil-bed) tests
1994 - IRG/WP 94-20047
Fungal cellar (soil-bed) tests are considered to be an important tool for the evaluation of the performance of ground contact wood preservatives. Facilities of this type have been established world wide although caution has been exercised in their introduction into standard testing methods for the approval of wood preservatives. This is the result of concerns over the variability in the biological...
G R Williams, D Rudolph, M E Hedley, J A Drysdale, R F Fox


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Preservative effect of cellulose insulation material against some mould fungi and brown rot fungus Coniophora puteana in pine sapwood
1991 - IRG/WP 1484
The influence of mineral wool and loose-fill cellulose wool on biodeterioration of pine sapwood was studied. The test fungi were mould fungi Aspergillus versicolor, Cladosporium sphaerospermum, Penicillium sp. and Aureobasidium pullullans and brown rot fungus Coniophora puteana. Cellulose wool inhibited the growth of mould fungi on the face of wood contacted with insulation material at RH of 97 an...
H Viitanen


Soil bed studies of the dimensional stability of composite products
1999 - IRG/WP 99-40134
The influence of boron and isocyanate resin on the dimensional stability of high moisture resistant particleboard was assessed after burial in a soil bed for one month. The samples were treated with two levels of a boron compound and coated in isocyanate resin. The samples were randomly placed in a fungal cellar in soils of two different water holding capacities. Weight differences and dimensional...
K M Filcock, P Vinden


Bait box technique for remedial subterranean termite contro
1995 - IRG/WP 95-10115
The bait box technique, as described in this paper, was first used as a method to apply the dust toxicant, arsenic trioxide, to large numbers of aggregated subterranean termites. Over the last twelve years or so the technique has been refined, and in recent years, gained acceptance as an alternative subterranean termite control measure by members of the Australian pest control industry. This baiti...
J R J French, B M Ahmed, D M Ewart


Boron treatment methods for lyctid susceptible hardwoods growing in Tasmania
1998 - IRG/WP 98-30168
A survey of existing boron plants that treat to protect hardwoods from attack by lyctids in Australia showed that hot and cold bath, and vacuum pressure impregnation (vpi), were the two most common methods employed. In experimental work, two of the treatment methods, vpi and dip diffusion, were used to treat seasoned and green messmate (Eucalyptus obliqua) and blackwood (Acacia melanoxylon). The t...
L J Cookson, D Scown, K McCarthy


Volatile organic compounds (VOC) measured during drying of impregnated timber
2004 - IRG/WP 04-50216
Discussion about drying of impregnated timber has taken place in the Nordic countries under eighties and nineties and goes on nowadays. The drying increase the value of production and the customer gets fewer problems when handles the timber. This introduces a positive attitude to the impregnation as a process and its products. Beside the important information about the advantages of impregnated ti...
N Terziev, V Djokic


Application of (n-a)-radiography for determination of boron in wood impregnated with boron-containing antispetics
1975 - IRG/WP 351
The method of (n-a)-radiography for quantitative determination of boron is based on creation of defective regions (tracks) in a polymer (the detector), which form during passage of a particles through the detector, these particles being produced in the reaction 10B(n, a)7Li when the test specimen in contact with the detector is irradiated with neutrons. Etching of the detector with an appropriate ...
N A Dubinskaya, M Ya Tsel'millere


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Steam/hold/APM boron treatment - Treatability trials with green gauged radiata pine
1987 - IRG/WP 3439
Freshly sawn 100 x 50 mm radiata pine was green gauged, steam conditioned and preservative treated with a mixture of borax and boric acid using a modified Alternating Pressure Method (APM) treatment schedule. A 12 hour holding period between steam conditioning and treatment resulted in the necessary moisture loss and moisture re-distribution to facilitate treatment to NZ Timber Preservation Author...
P Vinden


Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Estimation of oral toxicity of boron as a bait toxicant and the trophallactic effects between individual members of termite colonies.
2003 - IRG/WP 03-10495
In recent years, because of the favourable environmental characteristics of boron, researchers in the wood preservation industries have refocussed on the use of boron as a major wood preservative against wood-destroying insects. Currently the greatest use of boron compounds is in remedial treatments. Boron has been found to have slow-acting toxicity against subterranean termites. Because of thi...
B M Ahmed


Distribution of copper/chrome/boron preservative in light red meranti (Shorea leprosula) before and after exposure test for 72 months
1995 - IRG/WP 95-20073
Copper/chrome/boron (CCB) preservative at 6% w/w was impregnated into light red meranti (Shorea leprosula) by full cell process. The quantitative analysis for copper, chrome and boron contents in treated wood samples was carried out by Inductive Couple Plasma (ICP). Electron Probe Microanalyser (EPMA) was used to monitor the distribution of copper, chrome and boron in the various treated wood tiss...
S Salamah, S Ani


Effectiveness of the new chemical wood preservative Borosol 9? against a house longhorn beetle Hylotrupes bajulus
2004 - IRG/WP 04-30355
Chemical wood preservative Borosol 9, consisting of boric acid - alkanolamine complex, is a new wood preservative with proven efficacy against wood decay fungi. However, we were interested in its efficacy against larvae of house longhorn beetle (Hylotrupes bajulus). Thus, experiment according to the EN 46 procedure was performed. Specimens made of Norway spruce wood (Picea abies) were ...
G Babuder, M Petric, F Cadež, M Humar, F Pohleven


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


Combustion properties of Alder wood treated with some new environment friendly natural extractives. Part 1. Effect of Natural Tannins on the Combustion Properties
2002 - IRG/WP 02-40234
Powders of the brutia pine bark, sumach leaves, acorn, gall-nut and boric acid and borax which are known as potential environment friendly wood preservatives were impregnated according to ASTM D 1413-88 in order to determine their combustion properties. A commercial treatment compound, Tanalith-CBC, was also used for comparison. The results indicated that the natural extractives did not have an...
Ü C Yildiz, A Temiz, E D Gezer, S Yildiz


Borates as wood preservatives - an environmental, health and safety perspective
1993 - IRG/WP 93-50001-03
Boron compounds are highly effective wood preservatives and have an established safe use in the timber treatment industry. Their widespread background occurrence in nature, low acute mammalian toxicity and useful properties make them versatile active ingredients within today's environmentally aware society. A critical review of health, safety and environmental data on the borates, their u...
J B Rainer


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