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Buffered Amine Oxide Treatment Systems for Ammonical Copper Wood Preservatives
2014 - IRG/WP 14-40685
Wood is the most versatile, practical and sustainable building material in the world. In modern countries, wood is a well-managed renewable resource that has a small carbon footprint. Wood does suffer from a lack of durability against invasive organisms such as insects and fungi. Steel, aluminum and composites have emerged as viable alternative building materials. These sectors market the defi...
R W Clawson Jr


Buffered Amine Oxide Treatment Systems for Imparting Water Based Azoles/Insecticides in Douglas Fir and Eucalyptus
2015 - IRG/WP 15-40707
In today’s world, wood remains the most versatile, practical and sustainable building material. In contemporary countries, wood is a well-managed renewable resource that has a remarkably small carbon footprint compared to those of steel, aluminium, composites, and concrete. These alternative materials have continued to emerge as viable building materials given the durability issues of untreate...
R W Clawson Jr


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


Above-ground performance of a buffered amine oxide treatment system against Mastotermes darwiniensis
2016 - IRG/WP 16-10855
Above-ground H2 field tests against Mastotermes darwiniensis were conducted in far north Queensland to assess the efficacy of buffered amine oxide treatments in the softwoods Pinus sylvestris and P. radiata, and the hardwoods Eucalyptus regnans and E. diversicolor. Untreated hardwoods and slash pine bait wood (P. elliottii) were severely attacked or destroyed, while untreated P. sylvestris was mod...
L J Cookson, R W Clawson Jr


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


The impact of catalyst on the properties of furfurylated beech wood
2016 - IRG/WP 16-40748
European beech (Fagus sylvatica L.) is a major tree species of European forest that is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic ...
P S Sejati, A Imbert, C Gérardin, S Dumarçay, E Fredon, E Masson, D Nandika, T Priadi, P Gérardin


A Treatability Study of Western Wood Species with Water Based Azoles and Insecticides Using Buffered Amine Oxides
2016 - IRG/WP 16-40766
The use of Western U.S. Wood Species remains small in today’s global wood product market when compared to the use of other commercially available softwoods. One reason that other fiber sources, those that may be less naturally durable or exhibit slightly inferior mechanical properties, are utilized is ease of treatment. In an attempt to ensure adequate penetration in commercially important an...
R W Clawson Jr, C N Cheeks, K A Cutler


Prevention of fungal damage of oil and date palm wood by organic acids
2017 - IRG/WP 17-10877
Felled palm trunks are susceptible to fungi as long as their moisture content is above fibre saturation. During this period, palm wood has to be protected against mould and rot fungi. Environmental-friendly organic acids are suitable. Small samples of oil palm (Elaeis guineensis) and date palm (Phoenix dactylifera) wood were treated with 1 to 10% solutions of acetic acid and propionic acid, respec...
M Bahmani, O Schmidt


Evaluating the role of Actinobacteria in the gut of wood-feeding termites (Reticulitermes spp.)
2017 - IRG/WP 17-10880
Nitrogen has been shown to be a limiting nutrient across a range of xylophagous insects. These insects often rely on symbiotic microorganisms in the gut for nitrogen acquisition, via fixation of atmospheric nitrogen or break down of other available nitrogenous substances. In phylogenetically lower, wood-feeding termites, the role of nitrogen fixing bacteria has been well studied. However, there is...
Evaluating the role of Actinobacteria in the gut of wood-feeding termites (Reticulitermes spp.)


Treatability of beechwood railway sleepers with potential creosote substitutes
2017 - IRG/WP 17-40790
Maintenance of an efficient railway infrastructure still requires the use of wooden railway sleepers, particularly because wooden sleepers have more favourable properties for intensified vibrations than concrete or steel sleepers. Creosote, used for decades for the impregnation of railway sleepers, will possibly no longer be available for this application due to European legislation. This reveals ...
N Pfabigan, E Habla, R Gründlinger


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Encapsulation of chlorothalonil with polylactic acid using nanoprecipitation method for rubberwood preservation
2018 - IRG/WP 18-30722
Wood is a very beneficial material for humankind. The current trend is employing organic biocides as wood preservatives to inhibit the wood from biodeterioration caused by fungi and termite. However, these organic biocides are facing some shortcomings when being introduced into the wood using conventional water-based treatment due to their poor water solubility. Polylactic acid (PLA) was employed ...
T-J Teng, M N M Arip, R Kadir, E-P Ng, H-L Lee


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


Wood Protection Through Diffusion: Dimensional Stabilisation with Amine Oxides
2019 - IRG/WP 19-30747
Wood is a phenomenal construction material. In addition to its great physical properties and its beautiful appearance, it possesses many environmental-friendly virtues like the sequestration of carbon dioxide. It is however subject to dimension changes when submitted to fluctuating moistures levels, which can lead to warps, cracks and the peeling of paints. Many water repellents can slow down the ...
S Pepin, P Blanchet, V Landry


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


A summary of decay performance with citric acid and sorbitol modification
2020 - IRG/WP 20-40898
Application of wood-based products as construction materials is one piece of the big puzzle to mitigate climate change. Wood is susceptible to biological deterioration. Environmentally motivated legislation is making the use of biocides less attractive from a commercial perspective. Ideally, a wood modification technology should be of low cost, water based and make use of thermal curing. This rese...
G Alfredsen, E Larnøy, G Beck, J Biørnstad, L R Gobakken, C A S Hill, A Treu


Macro biological degradation of wood treated with sorbitol and citric acid – first results from marine environment and termite exposure
2020 - IRG/WP 20-40901
Most European wood species are rapidly and severely degraded in termite-infested areas and the marine environment. There is a need for new solutions, especially in the marine environment, since we lack wood preservatives approved for marine applications in Europe. Several wood modification systems show high resistance against both marine borers and subterranean termites. However, the existing comm...
A Treu, L Nunes, E Larnøy


Analysis of wooden shingles after seven years of exposure
2022 - IRG/WP 22-20690
Wood is a traditional roofing material in the Alpine regions. In the 17th century, wooden roofing was typically used on more important buildings. Still, today it is predominately used on huts and houses in the hilly regions of northern and north-western Slovenia. Because wooden roofing is expensive, we investigated the possibility of extending the service life of the roofing through impregnation a...
M Humar, B Lesar, D Kržišnik, E Keržič, B Jemec


Durability against fungal decay of sorbitol and citric acid (SorCA) modified wood
2022 - IRG/WP 22-40928
Most European-grown wood species are susceptible to biological degradation, specifically, they suffer from a poor resistance against wood-destroying fungi. Therefore, prior to outdoor exposure, wood has to be treated either by applying a protective coating on its surface or by full-volume impregnation with antifungal chemicals. However, due to environmental and health concerns, the most frequently...
K Kurkowiak, L Emmerich, H Militz


CIOL®-protection of wood – an update
2022 - IRG/WP 22-40932
Most commercial wood species from the northern European region are of low natural durability. Products from these wood species for outside applications need therefore protection to increase their service life. This protection should be free of biocides, come from renewable resource, have great performance and hold a low consumer price. A mixture of water, sorbitol and citric acid has the potential...
A Treu, E Larnøy, J Biørnstad


Biocomposites based on PVA, cellulose nanofibrils and tannic acid
2022 - IRG/WP 22-40957
Biocomposite films based on a polyvinyl alcohol (PVA) with the addition of cellulose nanofibrils (CNF) as a reinforcing component and with the addition of the biologically active tannic acid (TA) were prepared. The influence of different additions of CNF and TA in the polymer matrix PVA on the mechanical properties, improvement of hydrophobicity of the prepared films was studied. In all cases, the...
U Osolnik, V Vek, I Poljanšek, Poven


Sensitivity of copper indicators for detecting preservative penetration
2023 - IRG/WP 23-20701
Chrome azurol S (CAS), 1-(2-pyridylazo)-2-naphthol (PAN), and rubeanic acid (RA) are the three copper indicators currently used by the timber industry to assess preservative penetration. Although only the American Wood Protection Association (AWPA) standards specify indicator sensitivity, it is unclear how those limits were developed. The sensitivity of each copper indicator was determined in solu...
T Yi, J Norton, S Meldrum, J J Morrell


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


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