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Treatment of Green Logs infested by Exotic Pest: Case Study of the Emerald Ash Borer: Agrilus planipennis Fairmaire
2007 - IRG/WP 07-10628
Invasive alien insect species periodically infest forests in the United States causing the destruction of plant species and decimating populations, resulting in significant economic and ecological losses for areas involved. The Emerald Ash Borer (EAB) was first discovered on North American soil in the summer of 2002 near Detroit, Michigan and has since spread to several other Midwestern states and...
P Nzokou, S Tourtellot, D P Kamdem


Developments in Borate Treatment of Canadian Species for Decay and Termite Resistance
2007 - IRG/WP 07-30443
The increased interest in boron treatment of wood over the past 20 years is mainly due to its environmental acceptability, potentially deep penetration in wood, and its efficacy against decay and termites. Based on Forintek’s research in the past two decades, the boron penetration and retention requirements for decay and termite protection in various national and international standards for Cana...
Jieying Wang, P Morris, S McFarling, T Byrne


Performance of softwood preservative treated stakes after 4 years exposure in-ground to decay fungi and termites in tropical Australia
2008 - IRG/WP 08-10643
This field study was based on the 1993 IUFRO method and designed as a graveyard (in-ground) test in the tropical region of the Northern Territory to examine the efficacy of novel preservative formulations developed as alternative protection for softwood timber against decay fungi and termites for Hazard Class 3 and 4. This study was supported by the Forest and Wood Products Research and Develop...
B M Ahmed (Shiday), J R J French, S R Przewloka, P Vinden, J A Hann, P Blackwell


Soft Rot Determines Service Life of L-joints with Low Borate Loading
2008 - IRG/WP 08-30470
As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and amabilis fir) in 1990. The treated material had a low initial retention of only 0.2% boric acid equivalent and analysis after 5 years revealed no detectable borate close to the tenon. Nev...
P I Morris, J Wang, J K Ingram


The effects of zinc borate treatment of wood strands on some technological properties of oriented strandboard (OSB)
2008 - IRG/WP 08-40419
In this study, influences of zinc borate treatment on some technological properties of oriented strandboard (OSB), from aspen wood (Populus euroamericana cv.) were evaluated. Therefore, a total of nine panels with dimensions of 40 cm by 40 cm by 1.8 cm and with an average target density of 0.65 g/cm3 were manufactured under the laboratory conditions. Experimental panels were manufactured at two di...
A D Çavdar, H Kalaycioglu, G Nemli


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi


Laboratory and field evaluation of Laminated Strand Lumber treated with Borogard® ZB against termites
2009 - IRG/WP 09-30498
A laboratory bioassay and subsequent field trial was undertaken to determine the termiticidal effectiveness of a Laminated Strand Lumber (LSL) composite when treated with Borogard® ZB. The bioassay and field trial were conducted against two of Australia’s most economically important species of termite, Mastotermes darwiniensis and Coptotermes acinaciformis. Against both species of termite, LSL ...
D K Scown and J W Creffield


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Vinyl Benzoate Photostabilizes Wood Whereas Vinyl Cinnamate and Vinyl 4-T-butylbenzoate are Less Effective
2009 - IRG/WP 09-40452
Thin wood veneers were esterified to different weight gains with three different aromatic vinyl esters, vinyl benzoate, vinyl cinnamate and vinyl 4-T-butylbenzoate and the photostability of the modified wood was examined. There was a linear relationship between the level of esterification of wood with vinyl benzoate and the photostability of the modified veneers exposed to natural weathering. Viny...
M Jebrane, G Sèbe, I Cullis P Evans


Performance of Fasteners in Treated Wood: A Comparative Study
2009 - IRG/WP 09-40465
Fastener performance is an important property for treated wood. Published data on screw and nail performance for different preservative systems currently on the market are, however, limited. In this study, screw and nail withdrawal strength for southern pine wood treated with ACQ (above ground and ground contact), MCQ (above ground and ground contact), borate (disodium octaborate tetrahydrate – ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Ten Year Field Tests of Borate-Treated Wood Against Subterranean Termites
2011 - IRG/WP 11-30557
In the mid 1990s, Forintek Canada Corp. initiated a study of the termite resistance of borate-treated lumber above ground, protected from rain in Canada, Japan and Hawaii. Predominant termite species at three test were Reticulitermes flavipes in Canada, and Coptotermes formosanus in both Japan and Hawaii. The material included hemlock and amabilis fir lumber treated with disodium octaborate tetrah...
P I Morris, J K Grace, K Tsunoda


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Effectiveness of Water Based Bentonite-Borate Slurry for In-situ Remedial Protection of Historic Wooden Piles: The Eurobor Protocol, Part 2
2011 - IRG/WP 11-30574
The study of the biocide product Eurobor®, water mixture of boric acid, borax and sodium bentonite, aimed to verify previous findings regarding borates penetration from a clay-water mixture of foundation timber. The product was applied on samples from 100 year old timber foundation from the city of Göteborg. Although in ground for this long the timber was in acceptable god condition due to groun...
M. Theorin, K. Fimmerstad, K-M. Bandh


Ambient-temperature borate dip-diffusion treatment of green railroad crossties
2011 - IRG/WP 11-40556
In the USA, borates are increasingly being applied prior to air seasoning and creosote treatment of railroad ties (railway sleepers). Borates are typically applied to green ties by vacuum pressure application at 1 to 10% disodium octaborate tetrahydrate (DOT) concentration or by traditional dip-diffusion treatments at elevated temperatures. Higher temperatures are used to maintain the 30 to 50% so...
Jae-Woo Kim, A M Taylor, C Köse


Performance of Zinc Borate-Treated Oriented Structural Straw Board against Mold Fungi, Decay Fungi and Termites–A Preliminary Trial
2011 - IRG/WP 11-40571
The performance of zinc borate (ZB)-treated oriented structural straw board (OSSB) against mold fungi, decay fungi and termites was examined in standard laboratory evaluations. OSSB was fabricated with split wheat straw and diphenylmethane diisocyante (pMDI) resin. The ZB was added during panel manufacture to achieve preservative levels (wt.%) of 1.0%, 1.5%, 2.0%, and 3.0%. Untreated (0.0% ZB) OSS...
Guangping Han, M Manning, Wanli Cheng, E Pierre, W Wasylciw


Life Cycle Assessment Comparison of Treated Wood to Alternate Materials – Overview, Results and Lessons
2011 - IRG/WP 11-50282
Life Cycle Assessment (LCA) has proven useful in documenting the “green” benefits of various treated products compared to the commonly used alternates. To date, six LCA comparisons have been done or are nearing completion using ISO14040 and 14044 principles and data from US EPA databases. In almost all cases, the impact indicators for treated wood products show considerably smaller adverse e...
T Stephen, P E Smith, C R McIntyre


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Biological performance of wood- and bamboo-polypropylene composites: Effects of particle content, particle size and Zn borate
2012 - IRG/WP 12-40577
Particle content and size of wood material in wood plastic composites (WPCs) can affect efficacy of WPCs against fungi and termites. This study evaluated fungal and termite resistance of WPCs manufactured by using two different levels of particle content (50 and 70%) and three different particle sizes (30, 60, and 100 mesh). In fungal resistance tests, Tyromyces palustris, a standardized test fung...
S N Kartal, S Aysal, E Terzi, T Yoshimura, K Tsunoda


Pre-treatment decay and strength loss of railroad ties, and their prevention
2013 - IRG/WP 13-30610
Evidence of fungal decay in air-drying, untreated railway crossties is referred to as ‘stack burn’ in the industry. The deleterious consequences of stack burn on tie mechanical properties was confirmed by evaluating the impact bending toughness of wood samples taken from untreated tie stock air dried in the southern United States. These results suggest that careful consideration should be give...
A M Taylor, B Jordan, J D Lloyd


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


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