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On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Borates as wood preserving compounds: The status of research in the United States
1989 - IRG/WP 3542
This paper describes the extensive, on-going cooperative research effort among government and university research laboratories and industry to fully evaluate the potential for borates as wood preservatives in the United States. Research is discussed in terms of laboratory evaluations, field testing and mill trials, pilot plant pressure treatment studies, and remedial treatments. Future research pl...
H M Barnes, T L Amburgey, L H Williams, J J Morrell


Animal blood protein as a component of new, non-toxic wood preservatives fixing organic active compounds in wood
2003 - IRG/WP 03-30312
Application of natural organic compounds and simple physico-chemical treatments in wood conservation has, as its objective, not only its protection against biological agents but, equally importantly, protection of natural environment by gradual abandonment of toxic constituents still applied commonly on a wide scale. The introduction into wood of new, non-toxic impregnation agents manufactured on ...
B Mazela, I Polus


Persistence and residual activity of organophosphorus termiticides in soil and prevention against the degradation of chlorpyrifos
1991 - IRG/WP 1518
The persistence and the residual activity of four comercial organophosphorous termiticides, Chlorpyrifos, Fenitrothion, Tetrachlorvinphos, Pyridaphenthion, in soil were studied under laboratory conditions. The persistence and the residual activity of four organophosphorous termiticides in two types of soil decreased with the lapse of time. These termiticides were mostly degraded by microorganisms ...
T Iijima, M Tanaka, M Higaki


The importance of blue stain attack for the colonization by wood-rotting fungi of wood not in contact with the ground
1988 - IRG/WP 1349
When used in constructions not in contact with the ground, wood has been shown often to proceed from blue stain to moulds. The appearance of wood rotting fungi is normally delayed. Solid wood artificially inoculated with the blue stain fungus Pullularia pullulans was shown to permit germination of Pycnoporus cinnabarinus basidiospores. This was demonstrated by the use of an indirect and a direct b...
J Bjurman


Preliminary observations on tributyltin treated Scots pine sapwood using 119Sn (Mössbauer and NMR) spectroscopic techniques
1984 - IRG/WP 3312
119mSn Mössbauer data are presented for bis(tributyltin) oxide, tributyltin ethanesulphonate, bis(tributyltin) carbonate and tris(tributyltin) phosphate, both in the pure form and in Scots pine sapwood. The structures proposed for these compounds, in the solid state, are supported by 119Sn nuclear magnetic resonance spectroscopy.
R Hill


Chemical and biological investigations of double-vacuum treated windows after 7½ years in service
1985 - IRG/WP 3339
Earlier investigations of double-vacuum treated windows after five years in service have shown that tributyltin oxide (TBTO) degrades to di- and monobutyltin compounds and that the resistance of the wood against decay decreases. An investigation 2.5 years later of the same windows shows that the degradation of TBTO proceeds fast. After 7.5 years in service only 15-35% of the remaining organotin co...
M-L Edlund, J Jermer, B Henningsson, W Hintze


Environmental characterisation of retification process by-products (liquid and gaseous wastes)
2005 - IRG/WP 05-50224-10
In order to reduce environmental risks during the service life of the treated wood and to find new alternative developments on the durability of wood, some research and technology development have been made on thermal treatment. The retification process is one of these processes. The retification process induces chemical modification of the lignin and cellulosic components and modifies the intrins...
G Labat, E Bucket, S Legay, C Yriex, P Marchal, E Raphalen, M Vernois, R Guyonnet, H Besset, E Fredon), G Vilarem, L Rigal, C Raynaud


Surface protection of wood with titanium, zirconium and manganese compounds
2005 - IRG/WP 05-30376
Thin radiata pine veneers were treated with a range of titanium, zirconium and manganese compounds and exposed to natural weathering. Veneer weight and tensile strength losses were used to assess the protective efficacy of the compounds. The oxidative manganese compounds potassium permanganate and manganic acetate restricted both weight and tensile strength loss of treated wood veneers during weat...
K J Schmalzl, P D Evans


The action of siderophores isolated from Gloeophyllum trabeum on the structure and crystallinity of cellulose compounds
1991 - IRG/WP 1479
Low molecular weight, high affinity iron-binding compounds (siderophores) were isolated from the brown-rot fungus Gloeophyllum trabeum. The compounds were shown to be inducible by iron starvation and could be purified by ultra-filtration, ethyl acetate extraction, column chromatography and preparative HPLC. The isolated compounds were shown by analytical and immunological techniques to be produced...
J Jellison, V Chandhoke, B Goodell, F Fekete, N Hayashi, M Ishihara, K Yamamoto


A field evaluation of modified and unmodified alkylammonium compounds
1987 - IRG/WP 3436
Laboratory soil block studies of alkylammonium compounds (AAC's) at Forintek and other research establishments have shown that they can prevent decay by standard wood-destroying fungi. Their performance in field tests, however, has been disappointing. Following investigation of possible causes for this poor field performance, stakes treated with modified AAC's were installed at W...
J N R Ruddick


Partial characterization of inhibitors extracted from pine (Pinus sylvestris) sapwood active against germination of wood rotting fungi
1988 - IRG/WP 1351
Germination inhibitors in pine sapwood could be extracted and separated with the aid of solvent partitioning and chromatography on silicic acid. The inhibitory action was tested by three different bioassays. Active fractions have been characterized by TLC and HPLC. Inhibitory activity could be correlated with phenolic compounds. The minimum active concentration of inhibitors have been determined....
J Bjurman


Soft rot - Soil burial - Tests. Influence of the addition of nitrogen compounds to the soil on wood decay by soft rot
1972 - IRG/WP 213
The decay of wood specimens buried in soil is influenced by various factors. Decisive are the water content, the content of organic substances, the pH-value, the content of mineral nutritive salts, nitrogen content, etc. of the soil. These tests were carried out in order to investigate if the decay of wood in the soil will be influenced by additions of various nitrogen-compounds in different conce...
O Wälchli


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


New method to find out the volatile organic compounds (VOC) of wooden material
2000 - IRG/WP 00-20189
Volatile organic compounds (VOC) of pine, spruce and larch wood were studied using a new technique developed at VTT Chemical Technology. 50 mg of crushed wood material was placed into glass tubes. The tubes were closed with a glass wool, which is pressed with a tube cap. Wood samples were analysed with a gas chromatograph after thermal desorption using four different temperatures (50°C, 100°C, 1...
H Viitanen, K Villberg, K Saarela


Diazenes and some organic complexes of boron as potential fungicides for preservation of wood
1999 - IRG/WP 99-30197
Screening for fungicidal activity represents the first step in searching for new active components with enhanced environmental profile in comparison with traditional wood preservatives. Diazenes, their salts, and the salts of the corresponding semicarbazides, as well as several complexes of boron, were screened for fungicidal activity against wood decay fungi Trametes versicolor, Coniophora putean...
M Petric, B Paradiz, J Stern, F Pohleven, S Polanc, B Stefane, R Lenarsic


The influence of cement and calcium compounds on the performance of CCA preservatives
1983 - IRG/WP 3221
The influence of cement and calcium compounds on the durability of untreated and CCA treated wood is considered. Calcium compounds were found to reduce the toxicity of a CCA preservative to a soft rot fungus at copper to calcium ratios of 1:1 and 1:10 using a cellulose filter paper technique. Further studies are outlined and some possible mechanisms by which cement and calcium compounds may affect...
R J Murphy


Alkyl dimethyl benzyl ammonium chloride: toxicity to Coniophora puteana when formulated in water and organic solvent
1986 - IRG/WP 2250
Results from agar block tests using Coniophora puteana demonstrate that the biological activity of alkyl dimethyl benzyl ammonium chloride is affected by the nature of the carrier solvent in which it is applied. In contrast to some earlier work, an alkyl ammonium compound in organic solvent formulation was identified that had significantly greater activity than its aqueous equivalent. A simple sol...
D P Blow


Biological resistance of didecyl dimethyl ammonium tetrafluoroborate (DBF)-treated wood in soil-bed and Basidiomycetes tests
2006 - IRG/WP 06-30393
This study evaluated the decay resistance of treated wood with a new quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) in laboratory soil bed and Basidiomycetes tests. Treated sugi sapwood specimens with DBF at various concentration levels were first subjected to soil bed tests using two types of soil. The specimens subjected to soil bed tests were then used for Basidi...
S N Kartal, C Brischke, A O Rapp, Y Imamura


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


Effect of fire retardants (monoammonium phosphate and diammonium phosphate, mixture of monoammonium phosphate and borax and ammonium sulphate) on beech wood with dipping and Lowry methods
2006 - IRG/WP 06-40350
In this study, the possibilities of using four kinds of chemicals as fire retardants with 12% concentration for beechwood (Fagus orientalis Lipsky) was surveyed. Providing testing samples that are related to the measurement of fire resistance properties according to JIS A-1321-1975 standard were evaluated. Wood samples were impregnated with Lowry and dipping methods. In this study, samples impregn...
M Akhtari, D Parsapajouh, M Arefkhani


The response of the Formosan subterranean termite (Coptotermes formosanus Shiraki) to different boron compounds
2007 - IRG/WP 07-10609
Although boric acid and other boron compounds have been used since the 1800s as insecticides, their mode of action is not well understood. Borate salts, in particular sodium and zinc formulations, are effective wood preservatives and are used extensively in Hawai’i to protect building materials from both drywood (Kalotermitidae) and subterranean (Rhinotermitidae) termites. The Formosan subterra...
M C Gentz, J K Grace


Effect of fire retardants (monoammonium phosphate and diammonium phosphate, mixture of monoammonium phosphate and borax and ammonium sulphate) on beech wood with dipping and Lowry methods
2006 - IRG/WP 06-40350
In this study, the possibilities of using four kinds of chemicals as fire retardants with 12% concentration for beechwood (Fagus orientalis Lipsky) was surveyed. Providing testing samples that are related to the measurement of fire resistance properties according to JIS A-1321-1975 standard were evaluated. Wood samples were impregnated with Lowry and dipping methods. In this study, samples impregn...
M Akhtari, D Parsapajouh, M Arefkhani


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Efficacy of chitosan in combination with GRAS (Generally Recognised As Safe) compounds as a potential wood preservative
2007 - IRG/WP 07-30414
In vitro studies were undertaken to evaluate the synergy between chitosan and selected GRAS (Generally Recognised As Safe) compounds against two sapstain fungi Sphaeropsis sapinea and Leptographium procerum. Bioassays performed on nutrient medium suggested that some of the GRAS compounds tested including sodium benzoate, potassium sorbate and ascorbic acid had a synergistic effect when combined w...
C Chittenden, K Thämelt, T Singh


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