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Gas chromatographic determination of 1,8-naphthalimide, N-Hydroxy-1,8-naphthalimide (N,N-naphthaloylhydroxylamine) and the sodium salt of N-Hydroxy-1,8-naphthalimide
2003 - IRG/WP 03-20259
A number of naphthalimide (NI) derivatives are used as efficient laser dyes, in medicine or in scanning electron microscopy. Only N,N-naphthaloylhydroxylamine (NHA) has been shown to be an effective wood preservative against wood decay fungi and termite damage. However, limited information is available concerning the analytical detection of NI-derivatives in treated timber. There is a clear need ...
E Melcher, F Green III


Proposed model for the penetration and decay of wood by the hyphal sheath of the brown-rot fungus Postia placenta
1989 - IRG/WP 1391
Scanning electron microscopy (SEM) of Pinus sp. decayed by the brown-rot fungus Postia placenta confirmed the existence of extracellular membranous structures previously described by transmission electron microscopy (TEM). These structures appear to be an integral part of the hyphal sheath and assume a variety of forms including lamellar sheets, fibrils, and vesicles. These structures were observe...
F Green III, M J Larsen, L L Murmanis, T L Highley


Early detection of brown-rot decay in southern yellow pine using immunodiagnostic procedures
1990 - IRG/WP 2356
Immunodiagnostic procedures have been used to detect incipient decay of southern yellow pine by six common brown-rot fungi. Rabbit polyclonal antibodies were raised to liquid culture fractions of the six fungi. The antibodies, after preadsorption to sawdust, were tested in particle agglutination assays, immuno-dot blot, and ELISA for their·ability to detect the decay organisms when they were grow...
C A Clausen, F Green III, T L Highley


Prevention of creosote bleeding from treated Scots pine poles
1970 - IRG/WP III 3B
Creosote, the most widely used preservative for pressure treatment of Electricity Board and GPO transmission poles in the United Kingdom has, when correctly applied, given good performance over a long period of time. Perhaps its only disadvantage as a preservative in the above fields is its tendency to exude or 'bleed' from a proportion of treated poles upon exposure to solar hea...
Anonymous


Protection of southern pine using N,N-Napthaloylhydroxylamine: Field tests, soft-rot cellars and aquatic bioassay leach testing
1999 - IRG/WP 99-30204
Recent environmental restrictions are limiting the use of broad-spectrum biocides for wood preservation. There is an urgent need for new, sharply targeted, environmentally benign wood preservatives. N'N-Napthaloylhydroxylamine (NHA), a water-soluble calcium-precipitating agent, has been shown to inhibit decay by brown-rot and white-rot fungi in soil-block tests and prevent damage by Easte...
D M Crawford, F Green III


Hemicellulosic induction of oxalic acid in Postia placenta
1994 - IRG/WP 94-10060
Most studies suggest that enzymes produced by brown-rot fungi are too large to penetrate sound wood structures, even after decay begins. Thus, nonenzymatic agents have been proposed to initiate brown-rot decay. We have reported that the brown-rot fungus Postia placenta MAD-698 initiates a 2-fold decrease in wood pH within 7 days of colonization which is mediated by production of oxalic acid. Strai...
F Green III, M Larsen, T L Highley


The long road to understanding brown-rot decay. A view from the ditch
1995 - IRG/WP 95-10101
Interest in understanding how brown-rot fungi decay wood has received increasing interest in recent years because of a need to identify novel targets that can be inhibited for the next generation of antifungal wood preservatives. Brown-rot fungi are unique in that they can degrade holocellulose (cellulose and hemicellulose) in wood without first removing the lignin. Furthermore, they degrade holoc...
F Green III, T L Highley


The effect of water storage on the cell-structure of Sitka spruce (Picea sitchensis) with reference to its permeability and preservation
1970 - IRG/WP III 3A
Commercial treatment trials with full sized transmission poles have shown that water storage considerably improves the permeability of Sitka and Norway spruce. These results were confirmed by laboratory measurements which showed that in the sapwood of ponded Sitka spruce there is a vast improvement in permeability in all three grain directions. Heartwood permeability does not seem to be affected t...
J A Dunleavy, A J McQuire


Targeted inhibition of wood decay (Using everything but the kitchen sink)
1997 - IRG/WP 97-10203
Low molecular weight oxidative decay agents have been implicated in the degradation of wood by brown-rot decay as evidenced by chemical analysis of brown-rotted wood and detection of oxalic acid and hydroxy radicals. Fenton chemistry (H2O2 / Fe++) is often proposed as the mechanism for generating hydroxy radicals. Previous authors have shown iron to enhance the brown-rot hydrolysis of wood, while ...
F Green III, T A Kuster, T L Highley


Mechanisms of Protection by NHA Against Fungal Decay
2002 - IRG/WP 02-10429
Treating wood with the water-borne sodium salt of N'-N-naphthaloylhydroxylamine (Na-NHA) protects wood against decay and termite damage. Initial testing indicated little or no inhibition of sapstain fungi, molds, or soft-rot fungi by Na-NHA, suggesting that the mechanism by which this compound protected wood was complex and not that of a broad-spectrum biocide. Previously, we (Green et...
F Green III, W Henry, T Schultz


Targeted inhibition of wood decay fungi: degradation of cotton cellulose
1999 - IRG/WP 99-10321
Brown-rot decay is responsible for 80% of the damage and replacement of wood in service. For nearly thirty years, researchers have postulated a one-electron oxidase system combining Fe+2 oxalic acid, and H2O2 in the production of hydroxy radicals which ultimately oxidize cellulose in situ. Recently, researchers have been investigating antioxicants, in combination with biocides (Schultz, et al.,199...
F Green III, T A Kuster


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


Fire retardant treated wood and plywood: A comparative study Part III. Combustion properties of treated wood and plywood
2002 - IRG/WP 02-40236
The fire retardant treated and untreated plywood and alder wood samples were prepared with the aim to investigate the effects of the way of treatment on the combustion properties. Alder wood was used for the preparation of plywood. Boric acid and borax were used as fire retardant. The plywood samples were impregnated by using three different methods; first group samples were impregnated by soaki...
S Çolak, A Temiz, Ü C Yildiz, G Çolakoglu


Detection of increased metal cations after wood decay using Chromeazurol-S
1997 - IRG/WP 97-20112
Chromeazurol-S (CAS) is a dye used for the spectrophotometric determination of metals, mainly aluminum (Al), berillium (Be) and copper (Cu). CAS has been widely used for determining the penetration of copper containing preservatives like CCA (AWPA A3-96). Additional uses include: i) detection of utility pole decay (Esyln, 1979), ii) a chemical spot test for aluminum in wood (Kukachka and Miller, 1...
F Green III, U Srinivasan, R B Miller


A quantitative weathering study of wood surfaces modified by chromium VI and iron III compounds
1989 - IRG/WP 2330
Thin veneers of Pinus radiata were treated with dilute aqueous solutions of chromium VI and iron III compounds and exposed to natural weathering for 35 days. Zero-span tensile strength and weight losses of treated veneers were compared with losses observed in untreated specimens In a study designed to demonstrate the applicability of strength and weight loss measurements to the rapid quantitative ...
P D Evans, K J Schmalzl


Hydrolysis of bordered pits during colonization of conifers by brown-rot fungi
1995 - IRG/WP 95-10103
Brown-rot decay results in rapid reduction in degree of polymerization (DP) of holocellulose with concomitant strength loss (MOR) without removing lignin. Development of new methods of wood protection will require focusing on early events in the sequence of depolymerization. Bordered pit membranes (sapwood) represent a readily available source of non-lignified carbohydrate, ie. pectin and cellulos...
F Green III, J L Tschernitz, T A Kuster, T L Highley


Accidental mold/termite testing of high density fiberboard (HDF) treated with borates and N’N-naphthaloylhydroxylamine (NHA)
2003 - IRG/WP 03-10462
High density fibreboard (HDF) was made from beech and pine furnish (50:50) and treated with boric acid (0.1-3%), borax (0.1-3%) or N'-N-(1,8-naphthalyl) hydroxylamine (NHA) (0.1-1%) prior to gluing with urea formaldehyde (UF) resin in order to determine resistance to Eastern subterranean termites (Reticulitermes flavipes Kollar), the most economically important termite species in North Am...
S N Kartal, H H Burdsall Jr, F Green III


Immuno-scanning electron microscopic localization of extracellular polysaccharidases within the fibrillar sheath of the brown rot fungus Postia placenta
1991 - IRG/WP 1497
Extracellular polysaccharidases of the brown-rot fungus Postia placenta were localized using colloidal gold labeled monoclonal antibodies to the B-1,4-xylanase (32-36kDa) fraction of Postia placenta. Postia placenta was grown from agar onto glass coverslips, immunolabeled with or without prior fixation, and examined by SEM. Enzymes were localized on the hyphal surface and on the clumped fibrillar ...
F Green III, C A Clausen, M J Larsen, T L Highley


Oral toxicity of a slow-acting insecticide Amdro® to the Formosan subterranean termite
1982 - IRG/WP 1162
The use of toxic baits to control the Formosan subterranean termite Coptotermes formosanus Shiraki requires an insecticide that is non-repellent and sufficiently slow acting that poisoned termites leave treated areas before dying. Of the many insecticides screened, only Amdro® exhibited these characteristics. The oral toxicity (LD 50) of Amdro® to Coptotermes formosanus was estimated at 12.33 µ...
N-Y Su, M Tamashiro, J R Yates III


Distribution of boron from fused borate rods in Douglas-fir transmission poles
1996 - IRG/WP 96-30112
The diffusion of boron from fused borate rods (disodium octaborate tetrachydrate) was monitored over 42 months in CCA-treated Douglas-fir transmission poles. The boric acid equivalent was estimated by the curcumin/salicylic acid color test on increment cores removed from the poles. Moisture content of the poles was quite variable but was always above 20 percent. The percent of increment core lengt...
T L Highley, F Green III, W F Finney


Borate diffusion from fused borate rods in douglas-fir transmission poles
1994 - IRG/WP 94-30042
Pressure-treated utility poles have given many years of excellent service, but their lifetime is often shortened by internal decay of the untreated heartwood center, particularly in refractory species, such as Douglas-fir. This paper reports the distribution of boron from fused borate rods installed in CCA-treated Douglas-fir transmission poles. The boric acid equivalent was roughly monitored by t...
T L Highley, W Finney, F Green III


Creosote for wood preservation. (Reissued from earlier OECD draft)
1970 - IRG/WP III 1A
The literature on this subject is extensive and, to some extent, repetitive so that for pratical reference purposes it is essential that selective surveys and bibliographies be prepared. Many of these exist and, as an example, the reports issued by The Coal Tar Research Association (Numbers 0156, 0292 and 0396) may be quoted. The following bibliography, listing the more important sources of inform...
Anonymous


The role of oxalic acid in short fiber formation by the brown-rot fungus Postia placenta
1993 - IRG/WP 93-10028
The mechanism by which brown-rot fungi depolymerize wood and cellulose remains a perplexing problem. Current evidence favors oxidation by low-molecular weight, non-enzymatic fungal metabolites. During attack of cotton cellulose by Postia placenta MAD-698, the degree of polymerization (DP) decreases to limit of degree of polymerization (LODP) over a period of 5-6 weeks with relatively low weight lo...
F Green III, J M Hackney, C A Clausen, M J Larsen, T L Highley


The role of oxalic acid in tolerance to N’N-naphthaloylhydroxylamine in Tyromyces palustris
2006 - IRG/WP 06-10584
Certain wood decay fungi exhibit tolerance to one or more wood preservatives. Copper tolerance of brown-rot fungi has been studied in our laboratory for the past six years. We have observed some degree of tolerance to N’N-naphthaloylhydroxamine (NHA), a recently patented termite bait, by the brown-rot fungus Tyromyces palustris TYP-6137. In an effort to try and confirm this tolerance in other is...
R A Arango, C A Clausen, F Green III


Seasonal response of feeding, differentiation, and growth in the eastern subterranean termite Reticulitermes flavipes (Kollar) in Wisconsin
2007 - IRG/WP 07-10604
In termites, differentiation plasticity in undifferentiated Reticulitermes progresses with growth stages from larvae to workers, which may then differentiate into soldiers, winged nymphs, or neotenics. Although studies have been done on seasonality of the termite life cycle, data appears to vary from location to location. Reticulitermes populations in Wisconsin appear to behave slightly differentl...
R A Arango, F Green III, G R Esenther


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