IRG Documents Database and Compendium


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The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Preservative treatment of strips of Bambusa balcooa by soaking process using Borax-Boric acid
2008 - IRG/WP 08-30478
Bamboo strips made from Borak bamboo (Bambusa balcooa) were treated with 10% borax-boric acid aqueous solution by soaking process. The moisture contents of the bamboo strips were 12%, 20% and 30%. The strips were soaked for one, two, three, four and five days. The penetration of the solution was investigated by colour test after soaking and drying. Full penetration was observed after three days ...
K Akhter, M W Sheikh, M M Rahman, T A Chowdhury, M H Chowdhury


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Measurement of wood decay by dynamic MOE in an accelerated soil contact test
2008 - IRG/WP 08-20390
Current laboratory and field testing of preservatives involves various techniques to determine the extent of fungal attack, including visual inspection, mass loss, and static bending and compression strength measurements. The objective of this study was to compare decay measurement by conventional compression strength versus dynamic MOE, employing small wood stakes in an accelerated laboratory so...
Gan Li, D D Nicholas, T P Schultz


Above Ground Field Testing – Influence of test method and location on the relative performance of various preservative systems
2008 - IRG/WP 08-20393
Standardized above ground tests such as the lap-joint or test deck methods can be very slow in producing useful information on the relative performance of wood preservative systems. It often requires many years for decay to develop in wood treated to sub-optimal concentrations of standardized preservatives, making relative comparisons of performance between new systems and established preservativ...
A Zahora


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Vacuum drying of European oakwood: Color, chemistry and anti-oxidant potency of wood. Improving appearance in forest value added products
2008 - IRG/WP 08-40432
In hardwoods used for decorative and appearance purposes, wood colour is one of the most important factors of wood quality; in addition colour is related with durability and biological decay of wood. Wood discolouration during drying is mainly affected by heat, light, physiological reactions, combinations of reactions, biochemical and chemical reactions, and micro-organisms attack. In freshly fell...
S Sandoval, W Jomaa, F Marc, J-R Puiggali


Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras


Discovering anti-fungal agents in New Zealand native plants for use in wood protection
2009 - IRG/WP 09-10692
Extracts from Hinau (Elaeocarpus dentatus) leaves were tested in the laboratory for antifungal activity. In addition, the anatomical structure of the leaf was also examined by a combination of light and scanning electron microscopy. Chemical characterisation of the extracts and investigation into potential use of its components for wood protection is underway. A combination of light microscopy (...
C Rickard, T Singh, A Singh, R Newman


Isolation and identification of stain fungi and mould fungi on bamboo wood in China
2009 - IRG/WP 09-10703
One hundred and seventeen isolations were isolated from 150 specimens of mildewed or stained bamboo wood and bamboo products from 9 locations in north, south and central China. The molecular (ribosomal DNA Internal Transcribed Spacer, rDNA-ITS) and morphological identification results showed these fungi could be categorized 2 phyla, 2 classes, 4 subclasses, 10 orders, 15 families, 22 genera, 56 sp...
Xingxia Ma, Mingliang Jiang, Daochun Qin


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Effect of Preservative Treatment on Fungal Colonization of Teak, Redwood, and Western Red Cedar
2009 - IRG/WP 09-20404
Fungal flora present in preservative treated samples or non-treated samples from sapwood and heartwood of teak, western red cedar, redwood, and southern yellow pine was assessed after 6 to 18 months of exposure near Hilo, Hawaii. The objectives were to compare fungal composition and diversity between treated and non-treated samples, and to examine the use of molecular techniques for assessing fung...
Y Cabrera, C Freitag, J J Morrell


Evaluation of Water Repellency of Treated Wood Using Several Alternative Methods
2009 - IRG/WP 09-20419
In this study, the results of water repellency testing using a digital swellometer method for water-borne organic-preservative systems with water repellent additives are reported. The findings suggest that the traditional method of using matched untreated controls as a reference developed from historic solvent-based treatments for determination anti-swelling efficacy (ASE) may underestimate the a...
L Jin, A F Preston


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Laboratory test of some formulations against stain and mould fungi isolated from bamboo wood
2009 - IRG/WP 09-30508
To screen the effective anti-mould formulations, fungicides such as carbendazim, tebuconazole, fludioxonil, difenoconazole, prochloraz, benomyl and 8-hydroxy-quinoline copper (copper oxine) were selected to conduct the laboratory test of fungicidal activity by method of inhibition zone against Botryodiplodia theobromae Pat., Fusarium sp., Alternaria tenuis Nees., Penicillium purpurogenum Stoll, Tr...
Xingxia Ma, Airui Sun, Mingliang Jiang, Daochun Qin


Synthesis of a rosin amide and its resistance to wood decay fungi
2009 - IRG/WP 09-30517
Rosin was reacted with diethyltriamine (DETA) after being modified by acryl acid with the weight ratio of 4.5:1 and a rosin amide (RA) derivative was produced at the conditions as follows: modified rosin and DETA mole ratio of 1:3.5, dimethylbenzene as water carrying agent, reaction temperature of 160-180°C, and reaction time of 8h. The chemical structure of the product as RA was identified by F...
Shuangyue Li, Shujun Li, Jing Wang


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect. Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Microwave Surface Modification of Radiata Pine Peeler Cores for Preservative Treatment
2009 - IRG/WP 09-40453
Radiata pine peeler cores are classified as a by-product derived from the cores of logs left over after the veneer peeling process. The core can be potentially developed for value added solid wood products as it is abundantly available and has a constant diameter. However, the core needs to be preservative treated because of low durability in ground contact. An additional problem is that the wood ...
K Sugiyanto, G Torgovnikov, P Vinden


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