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Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg


Laboratory aquaria evaluation of CDDC (copper dimethyldithiocarbamate) against marine borers
1998 - IRG/WP 98-10262
The performance of CDDC (copper dimethyldithiocarbamate) and CCA (copper chrome arsenic) treated timber blocks was examined in a 1.5 year aquaria bioassay against the marine borers Limnoria tripunctata Menzies and Lyrodus pedicellatus (Quatrefages). Three timbers, southern yellow pine (SYP), Pinus radiata D. Don and Eucalyptus regnans F. Muell were treated with CDDC to retentions of 16, 32, 48 and...
L J Cookson, C R McIntyre, D Scown


Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek


Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Inadequacies in preservative retention and formulation as contributory causes of premature failure of CCA-treated vineyard posts
1984 - IRG/WP 3280
Analyses of severely decayed or failed vineyard posts and examination of stake test data on effectiveness of copper-chrome-arsenate (CCA) preservatives have suggested two contributory causes of premature failure of vineyard posts: 1. Preservative retentions in posts are such that after 15 years' exposure some decay is inevitable. 2. The high arsenic, low chrome formulations with which the...
M E Hedley


Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz


Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching. According to BPD hazard assessment has to be carried out f...
N Morsing


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Distribution of copper/chrome/boron preservative in light red meranti (Shorea leprosula) before and after exposure test for 72 months
1995 - IRG/WP 95-20073
Copper/chrome/boron (CCB) preservative at 6% w/w was impregnated into light red meranti (Shorea leprosula) by full cell process. The quantitative analysis for copper, chrome and boron contents in treated wood samples was carried out by Inductive Couple Plasma (ICP). Electron Probe Microanalyser (EPMA) was used to monitor the distribution of copper, chrome and boron in the various treated wood tiss...
S Salamah, S Ani


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


A note on the distribution of copper-chrome-boric (CCB) along the culm length of freshly felled bamboo treated by modified Boucherie process
2005 - IRG/WP 05-40317
Preservative treatment of green and dry bamboo poses severe problems. A number of bamboo/ wood preservatives (Chemical formulations) for the destroying organism like fungi, borers and termites etc. In this paper we reported preliminary results of treatment of fresh green round bamboo attached with baranches by modified Boucheri process. Sample full length of an Indian species of bamboo Dendrocalam...
R Lal, C N Vani


A survey of the incidence of decay in copper-chrome-arsenate treated trellis support posts used in horticulture in New Zealand
1984 - IRG/WP 1225
Copper-chrom-arsenate treated softwood posts used as trellis support structures in 5 major horticultural districts of New Zealand were systematically examined for presence of decay. Principal crops on properties examined were grapes and kiwifruit; a minority of properties grew hops, boysenberries, and dwarf apples. Occurrence and severity of decay were variable within specific age classes of posts...
M E Hedley, J A Drysdale


Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis


Preservative treatment of different thatching materials for low cost housing
1999 - IRG/WP 99-40144
Preservative treatment were made in seven different roofing materials with Copper-Chrome-Boron (CCB) at different concentration by soaking process. These were paddy straw, wheat straw, jute stick, sungrass, ulu grass, sugercane leaf and Nipa fruticans. It was observed that retention of preservative chemicals varies from species to species at the same concentration. From the service test it was obs...
K Akhter, M Younusuzzaman, M H Chowdhury


Characterization of checks and cracks on the surface of weathered wood
2000 - IRG/WP 00-40153
The surface roughness of unweathered and untreated pine; unweathered copper chromium arsenate type C (CCA) - treated pine; weathered CCA-treated pine; and weathered CCA-plus-water-repellent (WR) - treated pine was evaluated by a stylus tracing method. Surface roughness parameters Ra, Rz, Rmax, Rk, Rpk, and Rvk were measured. Ra, Rpk, and Rvk were the most appropriate parameters for describing modi...
D P Kamdem, Jun Zhang


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Update
1994 - IRG/WP 94-20032
It was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthenate) against t...
J R J French


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


Performance of preservative-treated timber against biodeterioration in Indian waters
1984 - IRG/WP 4106
Results on the investigation on the durability of panels of 32 timber species, pressure-treated with various preservatives and exposed along the Indian coast for varying periods upto a maximum of 15 years, are summarised. Panels of even non-durable timber gave excellent results against biodeterioration after treatment. Their life was comparable to that of treated durable timber. The preservative t...
L N Santhakumaran, J C Jain, M C Tewari


Preservative treatment of Golpata (Nypa fruticans) using CCA (Chromated Copper Boric Acid)
1999 - IRG/WP 99-40131
Golpata (Nypa fruticans) leaves provide a cheap but practical source of roof thatches. This study was carried out to determine whether the life span of Golpata could be extended by using CCB (Chromated Copper Boric Acid) treatment. Both leaves and midribs of Golpata , with different moisture contents ranging 16.63% to 70.67%, at the start of the experiment were treated with four different concentr...
G N M Ilias, F Abdullah, M O Hannan, S M Feroz


Oxine copper (NYTEK® GD) for the control of mould and sapstain on lumber in North America
1989 - IRG/WP 3517
NYTEK® GD is a new, water-based, micro-dispersible formulation of oxine copper registered in the United States and Canada for control of mold and sapstain-causing fungi. NYTEK GD is noncorrosive and of low hazard to applicators and people handling treated lumber, when used according to the label. The product is an effective wood protectant applied as a dip or spray treatment at concentrations of ...
D F Myers, J M Fyler, C H Palmer, G D Rosebery


Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura


Lignin degradation by a non-enzymatic system supposed to be active in white rot fungi
2000 - IRG/WP 00-10340
Electron microscopic investigations have shown that ligninolytic enzymes of white-rot fungi are only able to penetrate the wood cell wall in late stages of degradation. Thus, the selective degradation of lignin of certain white-rot fungi can only be explained on the basis of a low molecular weight, highly diffusible system. A system, consisting of copper, a coordination compound and either H2O2 or...
P Lamaipis, W Gindl, T Watanabe, K Messner


Tolerance of Wood Decay Fungi to Commercial Copper Based Wood Preservatives
2002 - IRG/WP 02-30291
Due to the use of copper based preservatives like CCB or CCA for more than a century, copper tolerant fungi have appeared in some European countries in recent times. It is therefore important to find out whether this phenomenon is specific for only classical copper ingredients, or generally for all copper based formulation. Thus, we tested the tolerance of three commercial copper based pres...
F Pohleven, M Humar, S A Amartey, J Benedik


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