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Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


Decay Resistance of MDF Manufactured with Huntite- Hydromagnesite and Zinc borate
2017 - IRG/WP 17-30710
The objective of this study was to evaluate the effectiveness of some mineral based fire retardants on decay resistance of Medium density fiberboard (MDF). Two mineral based chemicals containing (Huntite/Hydromagnesite) and zinc borate (ZB) were used at two different concentrations for panel manufacturing. Decay test of samples was performed according to EN 113 standard method. At the end of the t...
U E Başer, D Ustaömer, Ö Özgenç


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Treatability of beechwood railway sleepers with potential creosote substitutes
2017 - IRG/WP 17-40790
Maintenance of an efficient railway infrastructure still requires the use of wooden railway sleepers, particularly because wooden sleepers have more favourable properties for intensified vibrations than concrete or steel sleepers. Creosote, used for decades for the impregnation of railway sleepers, will possibly no longer be available for this application due to European legislation. This reveals ...
N Pfabigan, E Habla, R Gründlinger


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Uncertainty in life cycle assessment of preservative treated wood – copper and freshwater ecotoxicity
2017 - IRG/WP 17-50331
Life cycle assessment (LCA) is a method for quantifying the environmental impacts of a product over the life cycle. In the last years, there have been a growing application of LCA in developments of environmental product declaration (EPD), which is utilised by professional procurement of materials for buildings. For legislative issues, LCA have also been used to assess application of creosote to t...
L G F Tellnes


Five-year evaluation of a field trial of Eucalyptus grandis poles treated with zinc and boron
2017 - IRG/WP 17-30721
Round Eucalyptus wood treatment in sequential stages with inorganic borates and metal salts (zinc sulfate and boric acid+borax) was studied; the aims were to form an insoluble precipitate of zinc borate inside wood and to reduce treatment costs by performing the first treatment by simple ascent and diffusion of the preservative, at the same time as it was sought to impregnate the heartwood. The se...
C Ibáñez, A Camargo, C Mantero, M Rabinovich


Termite resistance of wood-plastic composites made with acetylated wood flour, coupling agent or zinc borate
2018 - IRG/WP 18-10917
There is little published scientific literature on the laboratory or field testing of wood-plastic composites (WPC) against termite attack. Therefore, the objective of this research was to investigate termite resistance (both laboratory and field) of 5 different extruded WPC blends of 50% western pine wood flour (WF) and high-density polyethylene (HDPE), and untreated pine solid wood. The study in...
R E Ibach, Y S Hadi, C M Clemons, S Yusuf


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


Influence of different triazoles as co-biocides in wood preservatives on efficacy and the environmental impact
2018 - IRG/WP 18-50333
In this study we investigated the efficacy and impact on the environment of different co-biocide triazoles in wood preservatives. Four different formulations (all containing 9.5% Copper) contained individual and combinations of cyproconazole, tebuconazole, propiconazole as co-biocides. Four formulations were tested according to EN 113 and EN 84 (ageing) to determine the brv for each formulation. T...
M Klamer, T Jensen, S Bang-Achton, E Morsing


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


COPPER NAPHTHENATE: A Product for All Seasons: Protecting the Americas’ Infrastructure for Over 100 Years and Potential for Expanded Usage in Europe
2019 - IRG/WP 19-30738
This paper is a brief review of the history and use of the wood preservative Copper Naphthenate, with a focus on use patterns within the USA and opportunities for expansion in Europe and Canada. This paper reviews how copper naphthenate has performed to preserve and protect cellulosic and wooden items essential to critical infrastructure, and why it is the ideal choice for use in the replacement o...
M H Freeman, J A Brient, M Manning


Relative efficacy of various oxine copper formulations against brown-rot fungi
2019 - IRG/WP 19-30741
This paper investigates the relative resistance of three different oxine copper formulations (oil-borne, water-borne, water-borne with pH-adjustment) as a preservative treatment for wood against brown-rot fungi. Impregnated southern pine sapwood cubes were exposed to R. placenta and G. trabeum cultures in a soil-block test. After eight weeks, the weight losses of the cubes were examined in relatio...
M Petruch, J Lloyd, A Taylor


Effect ofNano-Copper Oxide on Decay Resistance of Pistachio Twig-Plastic Composite
2019 - IRG/WP 19-30750
The goal of our study was to investigate the decay resistance of pistachio twig-plastic composite treated with nano-copper oxide against the white rot fungus Trametes versicoloer and the brown rot fungus Coniophora puteana. For this purpose, wood–polypropylene composites (WPCs) containing different loadings of nano-copper oxide, namely 0, 1, 2 and 3 percent (W/W), were made from pistachio (Pista...
M R M Farahani,S Pourabdollah


Preservative Treatment of CLT: An Example at Shimojishima Airport
2019 - IRG/WP 19-30748
Cross laminated timber (CLT) is a relatively new construction method that allows multi-storey construction using solid wood instead of concrete or steel. It is a method favoured by progressive architects and recognized for its much lower environmental footprint. Wood is an excellent construction material and is a long-term carbon sink that also performs well in the event of earthquakes and fire....
J Lloyd, N Yamashita, A Taylor


Effect of pretreatment of wood surfaces with a copper monoethanolamine solution on the natural weathering performance of semitransparent stains
2019 - IRG/WP 19-40881
Semitransparent stains for wood products are favored for outdoor applications in Japan because these finishes do not hide the wood grain. However, the photoprotective effects of wood surfaces are low, therefor there is a need to improve the weathering performance. We examined the natural weathering performance of semitransparent stains on wood pretreated with a copper monoethanolamine solution (Cu...
S Isaji, H Shibui, Y Hirabayashi


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Treatability of South African-grown Eucalyptus grandis with water-borne copper azole and disodium octaborate tetrahydrate wood preservatives
2021 - IRG/WP 21-40920
This study investigated the treatability of the sapwood and heartwood of sawn Eucalyptus grandis with copper-azole (CuAz) and disodium octaborate tetrahydrate (DOT) water-borne preservatives towards improving its durability for enhanced use in structural solid wood applications. The results obtained showed that, at a moisture content of 12 ± 1%, sawn E. grandis sapwood can be impregnated to a mea...
A A Alade, Z Naghizadeh, C B Wessels


Evaluation of Decay Resistance of Copper-based Preservatives Treated-Wood exposed to different field test sites in Korea
2022 - IRG/WP 22-20679
In Korea, preservative treated wood is required to have a stamp on the surface which contains information such as wood species, use categories, and the company that treated the wood. Such stamping is necessary to safely and appropriately use the treated wood. Since majority of treated wood is being used outdoor environment, the treated wood must have efficacy against wood decay fungi or termite. I...
W-J Hwang, S-M Yoon, Y Park, Y-S Choi, H-M Lee, J-W Kim


Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


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