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Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


Tests on the effectiveness of concentrated borate wood preservative
2009 - IRG/WP 09-30500
Tests were carried out to examine the toxicity of concentrated borate wood preservative to termites, fungi and mammals. The results showed that the preservative treated timber had high resistance to termite or decay and its acute oral toxicity belonged to low grade. The research shows that concentrated borate solution is an environmentally sound preservative and can be used in non-pressure treatin...
Su Haitao, Zhang Yanjun, Xie Guijun, Chen Lifang, He Xuexiang


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Copper based water-borne preservatives: The biological performance of wood treated with various formulations
1987 - IRG/WP 3451
Wood samples treated with the various components of CCA preservative singly and in combination were tested against a soft rot organism, a copper tolerant brown rot organism and in soil burial both unleached and after leaching. The results suggest that, of the elements tested, fixed copper is essential for preventing soft rot attack and fixed arsenic is essential for preventing attack by a copper t...
S M Gray, D J Dickinson


Lignin-copper, a new wood preservative without arsenic and chromium
1992 - IRG/WP 92-3702
A more environmentally sound treatment for wood with preservatives containing no arsenic or chromium, has been developed and studied on a laboratory scale. The method involves a first step impregnation with an aqueous solution containing modified, water-soluble kraft lignin followed by a second step involving impregnation with a copper salt solution to give fixation of the lignin into a water-inso...
B Ohlsson, R Simonson


A field test with anti-sapstain chemicals on sawn pine timber in Finland
1986 - IRG/WP 3368
Fourteen formulations, each in two concentrations, were tested for effectiveness against sapstain, mould and decay on Scots pine (Pinus sylvestris L.) in a field test in South-Finland. The trial was commenced in June 1985 and finished in October 1985. During the test the boards were infected mainly by mould fungi. In kiln dried boards the protective effects of nine and in green boards of four trea...
L Paajanen


The use of chlorothalonil for protection against mold and sapstain fungi. Part 1: Laboratory evaluation
1989 - IRG/WP 3515
Laboratory screening of chlorothalonil alone and in combination with other fungicides was conducted against six mold and sapstain fungi. The most promising treatments appear to be chlorothalonil supplemented with CCA or copper-8-quinolinolate. Field tests have been implemented....
J A Micales, T L Highley, A L Richter


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


The effective control of moulds on freshly impregnated wood
2004 - IRG/WP 04-30352
Beside natural timber it is known, that moulds can also groth at the surface of impregnated wood. This material shows “defects” like resistant dark spots or color changes and causes complaints. During the last years, the problem by moulds seems to increase. Laboratory studies were carried out to show the effect of impregnations against moulds. Wood samples (Pinus sylvestris L.) were impregn...
G Cofta, K Lutomski, P Jüngel


The Effect of Soil pH on the pH of Treated Southern Pine in Ground Contact after 12 Months
2011 - IRG/WP 11-50281
Southern pine samples treated with soluble and particulate copper solutions were subjected to three soils that had been amended to provide acidic, neutral and alkaline conditions. Wood pH was measured prior to, and after 6 and 12 months after being placed in the soil to determine the effect of soil pH on wood pH....
L Jin, C Schauwecker, C Vidrine, P Walcheski, A Preston


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


Emission of trimethyl borate and methanol from radiata pine (Pinus radiata D. Don)
1995 - IRG/WP 95-30088
Sawn and kiln dried radiata pine conditioned to 3, 6, and 12% moisture content was treated with trimethyl borate (TMB). The treated wood samples were placed in mini-desiccators maintained at 20 or 40°C. The air space within the mini-desiccator was analysed for TMB and methanol. An initial period of emission of TMB and methanol was observed. This was followed by a period of gradual dissipation of ...
F J Romero, P Vinden, J A Drysdale


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


The use of zirconium as an inert fixative for borates in preservation
2001 - IRG/WP 01-30256
Stand-alone borates have been used in internal protected situations as wood preservatives for about 60 years. They have not been deemed acceptable for external situations because of their leaching characteristics. Work carried out to reduce the leachability of borates has been reviewed briefly here, and a specific fixation agent based on zirconium has been tested in standard leaching and decay tes...
J D Lloyd, J L Fogel, A Vizel


Performance if internal remedial treatments to arrest fungal attack in poles and large timbers
2018 - IRG/WP 18-40834
Internal remedial treatments have been used to arrest internal fungal attack in utility poles and other large timbers. Water diffusible systems and volatile fumigants have both been used for this purpose. While both work, it is important to understand the performance attributes of each system. This paper reviews the literature on both systems and makes recommendations for future research....
J J Morrell


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Treatability of Siberian larch and spruce with chromated copper arsenate
1996 - IRG/WP 96-40060
Heartwood of Siberian larch (Larix gmelini) and spruce (Picea jezoensis) was pressure treated with chromated copper arsenate (CCA) Type B using a full cell process. Larch heartwood was somewhat difficult to treat than the spruce, although both species did not meet a minimum requirements of penetration and retention specified by the American Wood Preservers' Association (AWPA) for difficul...
Gyu-Hyeok Kim, Woo-Gue Jee, Jae-Jin Kim


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


Disposal of CCA treated waste wood by combustion - An industrial scale trial
1996 - IRG/WP 96-50068
Totally 272 m³ (62.7 t) of CCA treated utility poles were chipped and incinerated at Jalasjärvi Gasification Plant. In average the whole batch of chips contained 57 kg of elementary copper, 95 kg chromium and 76 kg arsenic. During the 56 h combustion trial the measured arsenic emission to the air was 76 g in total. Copper and chromium emission was less than 1 g. The condensing water from the coo...
A J Nurmi


Preliminary evaluation of borate baits and dusts for eastern subterranean termite control
1990 - IRG/WP 1433
Borates are of potential use in the development of baiting systems for subterranean termite control. In the 15-day laboratory assays reported here, the oral toxicity of disodium octaborate tetrahydrate to Reticulitermes flavipes (Kollar) was evaluated under choice and no-choice conditions. These assays suggest a range of 2500 to 5000 ppm to be applicable in developing baits, and that concentration...
J K Grace, A Abdallay, J M Sisson


The effect of steam conditioning on Southern yellow pine treated with copper naphthenate
1997 - IRG/WP 97-40086
The current study was undertaken to investigate the influence of steam conditioning on Southern yellow pine treated with copper naphthenate (Cu-N). Pre-steamed and /or kiln-dried Southern yellow pine were pressure treated with Cu-N. After treatment, one group of samples were post-steamed. It was found that samples changed color from green to dark-brown after post-steaming. To elucidate the effect ...
Jun Zhang, D P Kamdem, M H Freeman, R D Arsenault


Marine performance of preservative treated Southern pine panels. Part 2: Exposure at Mourilyan Harbour, Queensland, Australia
2000 - IRG/WP 00-10337
Southern yellow pine panels treated with ACQ type B, ACQ type A, CCA type C, creosote, and copper naphthenate have been exposed at Mourilyan Harbour, north Queensland, Australia for almost 6 years. These panels have been inspected and rated for fouling and attack by Teredinid, Limnoria, Martesia, and Sphaeroma during this exposure. After 70 months exposure, overall performance of ACQ type B was eq...
A R Zahora, A F Preston, K J Archer, S Kleinschmidt


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