IRG Documents Database and Compendium


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The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


The present status of wooden catamarans of the Indian Coast
1997 - IRG/WP 97-10231
Catamarans (a.k.a. kattumarams) are the most widely used fishing craft in India, and hundreds of thousands of poor, traditional fishermen depend on these vessels for their livelihood that are almost made entirely of wood. In recent years, acute shortages and phenomenal increases in prices of timber species used in catamaran fabrication have been reported, causing great hardship to the user communi...
K S Rao


Effectiveness of wood preservatives and treatments against marine borers in Philippine waters
1976 - IRG/WP 416
A 5-year exposure test was conducted on the effectiveness of wood preservatives and treatments against marine borers in Philippine waters. Air-dried heartwood samples of apitong (Dipterocarpus grandiflorus) 76.2 x 88.9 x 609.6 mm³ (3 x 3.5 x 24 in³) in size were pressure treated with coal tar creosote and two types of CCA (copper/chrome/arsenic) and CuCZA (copperized chromated zinc arsenate) wat...
F R Siriban, M G Laxamana, P G Mata


IRG/COIPM INTERNATIONAL MARINE TEST - To determine the effect of timber substrate on the efectiveness of different preservatives in sea-water: Coding scheme
1976 - IRG/WP 420
It was agreed in Wildhaus on 15 May 1976 that preparations for the test detailed in Document No: IRG/WP/414 should commence immediately, but that initially only two water-borne preservatives should be used - a copper/chrome/arsenic (CCA) and a copper/chrome/boron (CCB) formulation respectively. PRL, England (R Cockcroft) would be responsible for supplying only the reference species treated with th...
Anonymous


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


Quantification of creosote and fluoride in remedially-treated poles
1997 - IRG/WP 97-40097
Three creosoted transmission poles were put into service in 1961 and they were subsequently remedially-treated with a proprietary fluoride remedial paste formulation in 1981. The poles were removed from service in 1996 and their ground-contact regions were analysed for creosote and fluoride contents. It was found that the poles were undecayed. Creosote retentions decreased down the profiles of the...
B P Hill


A bioassay of remedially treated pole material
1987 - IRG/WP 3453
Stubs prepared from treated and untreated utility poles were installed in a test plot and pressure spade treated at the groundline with one of four preservative greases. At one and three year intervals, core samples were removed from the stubs and the improvement in the preservative efficacy due to the greases was assessed. The bioassay investigation showed that only bis(tributyltin) oxide (TBTO) ...
J N R Ruddick, L Parker


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


The effect of oil-borne preservative treatments on the shear strength of FRP/wood composite adhesive bonds
2003 - IRG/WP 03-40265
Reinforcement of structural wood components with Fiber Reinforced Polymer (FRP) will enhance the beam’s strength, but actual data on long-term durability is sparse, not well documented or not readily accessible. In this study, bond properties of FRP-wood composite materials were investigated following treatment with creosote or copper naphthenate preservatives. The properties investigated inclu...
B Herzog, B Goodell, R Lopez-Anido


A review of the current status of the estimation of emissions from preserved wood and their use in the environmental risk assessment of wood preservatives under the Biocidal Products Directive
2005 - IRG/WP 05-50224-7
A review and update of the status of the issues concerning the estimation of emissions from preserved wood (e.g. amendments to the proposed ‘OECD Guidelines’), and the environmental risk assessment of wood preservatives under the Biocidal Products Directive (e.g. compartmental sizes, emissate ecotoxicity testing)....
E F Baines


The use of organic wood preservatives in ground contact and the suitability of laboratory test procedures to determine their efficacy
1999 - IRG/WP 99-20175
Organic fungicides, such as propiconazole, have proven to be highly effective when used as a co-biocide in recently developed wood preservative formulations. They have however been ineffective when used as a stand alone preservative, particularly when used in ground contact (European Hazard class 4). Previous research, using the test methods of ENV 807 (1993), provided conflicting evidence regardi...
I J Herring, D J Dickinson


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Co-operative tests concerning the influence of solvent and drying method on the toxic limit of wood preservatives against Coniophora cerebella
1972 - IRG/WP 216
In the working group II of the IRG it was agreed that more knowledge was necessary concerning the influence of the solvent on the toxic limit of organic solvent types of wood preservatives against Basidiomycetes. A test program was drawn up and after discussion in the mentioned working group the final program was accepted by the co-operating institutes in 1969. In the test program two fungicides, ...
T Hof


Bethoguard; A new wood protecting fungicide for use in metal free ground contact wood preservatives
2002 - IRG/WP 02-30301
Research has identified the limitations in both the spectrum of activity and permanence of organic biocides placed in wood in high hazard environments, particularly in the absence of heavy metals such as copper. More specifically, the control of soft rot decay in wood in soil contact has proven to be most problematic. The new organic biocide, Bethoguard; an oxathiazine, has demonstrated excellen...
S C Forster, G R Williams, M Van Der Flaas, M Bacon, J Gors


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Wood preservation in Croatia
2004 - IRG/WP 04-30360
Croatia, as all the other countries in transition, however also because of its specific and well-known reasons, is on a path to gradual drawing nearer to the European standards. Only the scientists working at the Faculty of Forestry in Zagreb are engaged in scientific work relating to wood preservation. The construction and wood industry, which should enhance the chemical industry, also have subs...
R Despot, M Hasan


Suitability of different termite species for laboratory testing
1982 - IRG/WP 1159
Different termite species were tested in the laboratory to evaluate the effectiveness of insecticides and wood preservatives in wood against termite attack. Determined were the optimum group size and composition, the matrix (vermiculite) volume and its moisture content. Choice feeding tests with fully impregnated wood blocks which are carried out according to a modified EN 117 procedure for Reticu...
U Kny, H Kühne


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


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