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Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Douglas-fir PSL Treated with Oilborne Copper Naphthenate – Treatment Experience & Efficacy
2014 - IRG/WP 14-40687
Treating characteristics, field stake efficacy and the results from treatment trials for oilborne copper naphthenate (CuNap) and Douglas-fir parallel strand lumber (PSL) are summarized in this paper. Treatment with a P9 Type-C based solution in laboratory tests showed full cross section penetration of large cross sections could be achieved. Commercial treatment trials using a P9 Type-A solution ...
G P Merrick


Evaluation of color and gloss in decorative applied to cases of Pinus radiata wood impregnated (D. Don) copper type C azole micronized
2015 - IRG/WP 15-20571
Six treatments (one control and five decoration coatings) were applied to radiata pine wood treated with micronized copper azole (uCA-C), for outdoor use (R3) at a rate of 3.08 kg/m3 retention (T2). One decoration coating was applied before impregnation treatment: Prestain P (T3), and two, were applied in mixture with the uCA-C preservative Black Cylinder (T5) and Red Cylinder (T4). Two varnish we...
R Garay, M Inostroza


Performance of kiln-dried and air-dried anti-sapstain treated pallet timber under use scenarios against wood discolouring fungi
2015 - IRG/WP 30669
During their lifespan there is a high probability that wooden pallets and packaging material will be exposed to rainfall or rewetting conditions, increasing the risk of growth of discolouring fungi. Kiln-drying of wooden pallets and packaging material without anti-sapstain treatment does not give efficient protection against wood discolouring fungi during rewetting periods. However additional temp...
A Steitz, E Stoyanova, N Pfabigan, R Gründlinger


Search for an anti-sapstain treatment for fresh radiata pine wood in compliance with European BPD norms: Field Tests
2015 - IRG/WP 15-30673
In response to the impending restrictions on the use of pesticide active ingredients developed to control the staining of fresh wood, as a result of regulation issued in 2009 by the European Union, a project was proposed to test an alternative anti-sapstain treatment that meets both the European restrictions and the performance required for an export-quality radiata pine fresh wood treatment. A se...
P Montes C, T Hanke W


Polyamidoamines (PAA) functionalized with siloxane fragments as potential wood preservatives
2015 - IRG/WP 15-40708
Polyamidoamines (PAAs) utilized in this research were obtained by the reaction between N,N-methyl-bis-acrylamide (MBA) and Ethanolalmine (EtA) and/or aminopropytriethoxysilane (APTES). Different combinations between them were tested as wood preservatives against fungal decay. First, in situ impregnations of PAAs, with the reagents above described in different ratio, were performed and the effectiv...
S Palanti, G Predieri, E Feci, L Bergamonti


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


Environmental Fate of Micronized Copper
2015 - IRG/WP 15-50310
The environmental fate of wood preservatives is an important aspect to estimate the health and environmental impact. Although biocides from treated wood may be released into the soil, water or air, the latter pathway is frequently neglected in favour of leaching studies. Nonetheless, wood dust is well known to cause a variety of adverse health effects, in particular diseases to the respiratory tra...
C Civardi, L Schlagenhauf, J Benz, C Hirsch, J Van den Bulcke, M Schubert, J Van Acker, P Wick,


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


The copper-transporting ATPase pump and its potential role in copper-tolerance
2016 - IRG/WP 16-10859
Copper-tolerant brown-rot decay fungi exploit intricate mechanisms to neutralize the efficacy of copper-containing preservative formulations. The production and accumulation of oxalate is the most widely recognized theory regarding the mechanism of copper-tolerance in these fungi. The role of oxalate, however, may be only one part of a series of necessary components required for this complex mecha...
K M Ohno, C A Clausen, F Green III, G Stanosz


Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


A non-VOC approach of solvent-based wood preservatives for remedial treatment
2016 - IRG/WP 16-30681
Solvent-based wood preservatives are the workhorses in the field of remedial treatment. Due to new European regulations on the indoor air quality there is an increasing pressure on the VOC-content on these solvent-based product types. The transfer of these European regulations into national law is left up to each European member state and handled in different ways. E.g. France has introduced a VO...
M Pallaske, S Hellkamp, P Jüngel


Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick


Activity of wood preservatives against mould fungi
2016 - IRG/WP 16-30695
The resistance of experimental and commercial wood preservatives to mould fungi was determined using a method recommended by the Building Research Institute Instruction. The research of the inhibiting actions of the growth of fungi was carried out on the Scots pine wood Pinus sylvestris L. and beech Fagus sylvatica L. The most active compounds against mould were experimental herbicidal ionic li...
J Zabielska-Matejuk, A Stangierska


Influence of pressure phase impregnation time on the uptake and distribution of wood preservatives in Scots pine material of diverse treatability
2016 - IRG/WP 16-40752
In spite of the general opinion that Scots pine sapwood is easy to impregnate considerable variations in treatability are reported. In order to study impregnation results of diverse Scots pine sapwood treated with increasing process times, Scots pine sapwood from two different predefined treatability groups was impregnated. A copper solution was used as impregnation agent in ten different vacuum p...
K Zimmer, B Kerfriden


Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Guidance on the European Biocidal Products Regulation Concerning Efficacy of Wood Preservatives
2017 - IRG/WP 17-20627
In Europe wood preservatives belong to Product Type 8 (PT8) of the Biocidal Products Regulation (BPR, EU n. 528/2012), which regulates the authorisation of biocidal active substances and products in the European market. The applicant, who aims to obtain authorization to place a product onto the European market, needs to submit data to substantiate the label claims for the intended uses. Label cla...
I Stephan, M Kutnik, E Conti, M Klamer, L Nunes, J Van Acker, R Plarre


Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl


Efficacy of Erythropleum suaveolens (potrodom) and Distemonanthus benthamianus (bonsamdua) water extractives on the durability of five Ghanaian less used timber species of varying perviousness and retentiveness
2017 - IRG/WP 17-30705
Conventional wood preservatives are not only toxic to target bio-deterioration organisms but also to humans, other organisms and the environment. In an effort to find preservatives that are less toxic or non-toxic to man, other organisms and the environment, efficacy of branch bark and heartwood water extracts (0.65 g/ml) of Erythropleum suaveolens (potrodom) and Distemonanthus benthamianus (bonsa...
A Asamoah, K Frimpong-Mensah, C Antwi-Boasiako


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


The Protective Effect of Different Tree Bark Extractives against Decay Fungi
2017 - IRG/WP 17-30707
There are various modification methods which increase the resistance of wooden materials. Due to recent environmental regulations, there is a need for new and environmentally-friendly wood preservatives. In this study, six different tree bark extractives were evaluated for their wood resistance against fungal degradation. For this purpose, the white rot fungi (Tramates versicolour) and brown rot f...
Ö Özgenç, S Durmaz


Anti-fungal activity of rutin and rutin-metal complexes as wood protectants
2017 - IRG/WP 17-30708
The anti-fungal activity of Rutin, a flavonoid, alone or complexed with copper or zinc was investigated in a petri dish test with Gloeophyllum trabeum and Trametes versicolor as the test fungi. Rutin and the Rutin-metal complexes showed significant inhibition against each fungus. Rutin-Cu and Rutin-Zn strongly inhibited the brown rot fungus, G. trabeum, while Rutin and Rutin-Zn inhibited T. versic...
Li Yan, J J Morrell, Jie Zhong, Xiuzhu Mao


Liquefaction of woody waste: A novel approach in wood protection from CNSL based liquefied wood polyols
2017 - IRG/WP 17-30711
Liquefaction of lingo-cellulosic biomass is one of the thermo-chemical conversion processes for developing new materials, adhesives, preservatives and energy systems. The process also provides an opportunity to utilize waste wood such as saw-dust, woody wastes, branches and twigs for the development of value added products. Thus, this research paper deals with an investigation of antifungal and a...
A Kumar, G B.Nagarajappa, S Singh Chauhan


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