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The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


Performance of biocide-free preservative-protective systems modified with organosilicon compounds
2013 - IRG/WP 13-30628
The objective of the research was to determine the influence of organosilicon compounds in preservative-protective systems on the selected properties of pine wood aimed for outdoor use. The investigations were made for biocide-free systems based on alkyd resin and natural oils modified with alkylalkoxy-, amino- and glycidoxysilanes. The special attention was paid on the influence of hydrophobic pr...
B Mazela, P Hochmańska, T Krystofiak


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Relevance of natural pre-weathering for laboratory decay tests with native, modified, and preservative-treated wood
2013 - IRG/WP 13-20522
The on-going development of new wood protection systems is hampered by the long term field tests currently in use. New accelerated test methods and novel methods for faster and more accurate evaluation of wood protection methods are requested. For both field decay tests and accelerated laboratory decay tests, limitations are imposed. This study is part of the research program ‘WoodBuild’, whic...
A Pilgård, C Brischke, L Meyer


Effect of Nano-silver and Nano-copper and Nano-zinc oxide on Paulownia wood exposed to white-rot fungus
2013 - IRG/WP 13-30635
Paulownia is known as a fast growing tree and it can be used in several applications. The present study investigated the effect of Nano-silver and Nano-copper and Nano- zinc oxide on resistance of Paulowina (Paulownia fortunei) wood against the white rot fungus (Coriolus versicolor). Wood specimens with a dry density of 0.37g/cm3 were impregnated with a 400 ppm aqueous suspension of micronized na...
M Akhtari, M Ganjipour


The effects of copper proximity on oxalate production in Fibroporia radiculosa
2014 - IRG/WP 14-10823
Copper remains a key component used in wood preservatives available today. However, the observed tolerance of several critical wood rotting organisms continues to be problematic. Tolerance to copper has been linked to the production and accumulation of oxalate, which precipitates copper into insoluble copper-oxalate crystals, thus inactivating copper ions. The purpose of this study was to assess d...
K M Jenkins, C A Clausen, F Green III


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Statistical analysis of 40 years of preservative in-ground stake testing in Australia
2014 - IRG/WP 14-20552
Wood is widely recognized as a valuable material, yet the natural durability of some wood species limits its use for certain outdoor purposes. For decades, a wide range of methods and chemicals have been developed to increase the resistance of wood against degrading microorganisms and termites. Preservative treatment has a long and widespread tradition in wood protection. Proper testing of the eff...
J Van den Bulcke, L J Cookson, I De Windt, W Li, J Van Acker


Field trials results of preservative treated ground contact stake conducted in Korea
2014 - IRG/WP 14-30640
The field trials results from Korea preservative treated ground contact stake are reported. There was two site which was in southern area(Anmeon) and east area (Jungsun) of Korea. The CUAZ, CCA and CBHDO preservatives were use in this study. The sapwood of Japanese red pine stake was treated with these preservatives according to Korea standard method and then installed in 2003. Every year the insp...
Dong Won Son, Won Jung Hwang, Hyun-mi Lee, Dong-heub Lee, Sang-bum Park


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Copper naphthenate treatment for wood crossties and timbers
2014 - IRG/WP 14-30647
Copper naphthenate (CuN) has a long history in wood preservation and is recently finding increased usage as a treatment for wooden crossties and timbers. One of the principal reasons that CuN has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity and environmental impact. CuN is a well proven non-restricted use pres...
J Brient


Visualization of gold/silver nanostars in wood by surface enhanced Raman spectroscopy
2014 - IRG/WP 14-30653
Nanotechnology is a fast growing up-to-date technology and ventures expeditiously in the wood preservative market. However, there is still a huge lack of understanding about the interaction and incorporation of nanoparticles (NSs) in wood. Surface-enhanced Raman scattering (SERS) offers unique advantages as an analytical tool with a high selectivity and sensitivity without matrix interference. Her...
C Geers, L Rodríguez-Lorenzo, M Placencia Peña, P Brodard, T Volkmer, B Rothen-Rutishauser, A Petri-Fink


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Copper and chromium leaching from wood impregnated with chromium-copper containing preservatives: Results of different studies
2014 - IRG/WP 14-50300
Copper and chromium based wood preservatives remained one of the most important ingredients for wood protection solutions for protection of wood in demanding applications all-over the world. Leaching of heavy metals from treated wood is important from two different aspects; firstly from performance point of view, and secondly from environmental issues. However, the importance of these studies is i...
M Humar, N Thaler, E Melcher


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Comparison of gauge and assay retention in crossties treated with copper naphthenate
2014 - IRG/WP 14-40667
Creosote has been the most widely used preservative for wooden railroad crossties or sleepers for over 100 years. Alternative preservatives such as copper naphthenate (CuN) have been shown to provide equivalent performance against decay fungi and wood destroying insects; however, the use and specification of CuN involves an education process for treaters and railroad customers alike. One differe...
J Brient, H Tomlinson, J Hughes


New Method for Pretreatment of Railroad Crossties
2014 - IRG/WP 14-40675
Creosote has been successfully utilized for nearly 150 years for the protection of railroad crossties (sleepers) in the USA and remains today as the most widely used wood preservative for this application. One of the few shortcomings of creosote as a preservative is its inability to penetrate many of the refractory hardwood species which make up the majority of crossties in the USA. Lack of full...
A S Ross, R W Clawson Jr


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Douglas-fir PSL Treated with Oilborne Copper Naphthenate – Treatment Experience & Efficacy
2014 - IRG/WP 14-40687
Treating characteristics, field stake efficacy and the results from treatment trials for oilborne copper naphthenate (CuNap) and Douglas-fir parallel strand lumber (PSL) are summarized in this paper. Treatment with a P9 Type-C based solution in laboratory tests showed full cross section penetration of large cross sections could be achieved. Commercial treatment trials using a P9 Type-A solution ...
G P Merrick


Evaluation of color and gloss in decorative applied to cases of Pinus radiata wood impregnated (D. Don) copper type C azole micronized
2015 - IRG/WP 15-20571
Six treatments (one control and five decoration coatings) were applied to radiata pine wood treated with micronized copper azole (uCA-C), for outdoor use (R3) at a rate of 3.08 kg/m3 retention (T2). One decoration coating was applied before impregnation treatment: Prestain P (T3), and two, were applied in mixture with the uCA-C preservative Black Cylinder (T5) and Red Cylinder (T4). Two varnish we...
R Garay, M Inostroza


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