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X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Quantification of wood decay effects by HPLC analysis
1992 - IRG/WP 92-1576
The present work quantified the effects of the white rot basidiomycetes Coriolus versicolor and Phanaerochaete chrysosporium, and also those of the brown rot fungi Coniophora puteana and Lentinus lepideus, on Pinus patula and Eucalyptus grandis. Wood colonisation was quantified by Kjeldahl nitrogen determinations converted to biomass assays, and degradation was quantified by weight losses produced...
V Singh, M Tarin, G D Shelver, A A W Baecker


Analysis of contaminants in waste wood
2001 - IRG/WP 01-50179
Waste wood is increasingly used as fuel in Sweden. It is of Swedish origin as well as imported, Mainly from Germany and the Netherlands. The major chemical contaminants are surface treatments (paints etc) and wood preservatives. The surface treatments contribute in particular to contaminants of zinc and lead. In some cases zinc has been found to cause severe deposits in the furnaces. Surface treat...
J Jermer, A Ekvall, C Tullin


Laboratory evaluation of chlorothalonil against the Formosan subterannean termite
1992 - IRG/WP 92-1559
The fungicide chlorothalonil was evaluated as a wood preservative to prevent attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Southern yellow pine wafers treated with chlorothalonil (CTL) in P9 oil, CTL + chlorpyrifos in P9 oil, or CTL in xylene were conditioned by evaporative aging at 40° C for 4 weeks and exposed to termite attack in a mod...
J K Grace, P E Laks, R T Yamamoto


Pyrolysis GC-MS as a tool for lignin analysis
1987 - IRG/WP 2201
Pyrolysis-GC-MS is a rapid process for analysis of rather complex organic compounds. The method has great application to petroleum shale oil and wood lignin. Small powdered samples (several mg) are placed in silica capillary tubes and rapidly heated in an inert atmosphere such as He or N2. Breakdown products of the pyrolysis are then trapped and held for an allocated time in an injector attached t...
L Doimo


A reliable spot test for TCMTB in wood
1992 - IRG/WP 92-2391
Test specimens of slash pine (Pinus elliottii) and spotted gum (Eucalyptus maculata) were treated with aqueous emulsions of Busan 30WB and Busan 31, containing the fungicide TCMTB (2-(Thiocyanomethylthio)benzothiazole), or with solutions of TCMTB in toluene. These and matching untreated specimens were subjected to a wide range of procedures in an attempt to reveal TCMTB penetration patterns. Most ...
D E Ferlazzo, M J Kennedy


Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Non-destructive stress wave measurement of decay and termite attack in experimental wood units
1986 - IRG/WP 2256
The purpose of this study was to determine if stress wave analysis could be used to monitor the degradation of wood specimens exposed to the brown-rot decay fungi (Gloeophyllum trabeum) and of wood specimens subjected to attack by subterranean termites. One hundred fifty 3/4 by 3/4 by 12 in. Southern pine specimens were used for exposure to brown-rot decay fungi and two hundred twenty-five 3/4 by ...
R F Pellerin, R C De Groot, G R Esenther


A note on te seasoning, preservative treatment and suitability of debdaru (Polyalthia longifolia Benth & Hooker.) for poles
1995 - IRG/WP 95-40056
The main work is to determining the suitability of Debdaru (Polyalthia longifolia Benth.) as poles from Government and Village forests are investigated. The poles of Debdaru are easily treatable with CCA preservative by full-cell pressure method, but difficult to dry (air & kiln). Proper quality control must be maintain from procurement to treatment, specially during physical selection & d...
G N M Ilias, M D Rokib-ul-Hafiz


Kiln drying of poles as a means of solving the problems of pre-treatment decay in poles
1985 - IRG/WP 1263
The concept that pre-treatment decay can cause wide variation in the treatability of wood and especially wood poles has caused much discussion and debate in wood preservation circles. Yet it seem only logical that if decay has effected the strength characteristics of the wood and caused a differential moisture content in the wood the treatment of the end product will be highly variable and the lon...
J A Taylor


The wood-attacking insects in wooden houses of an old open air museum in southern Finland
1989 - IRG/WP 1409
Harmful insects of wood in a open-air museum were investigated in 1985-1988 by order of the National Board of Antiquities and Historical Monuments of Finland in nine old log houses. Many thousands of insects and altogether 1073 anobiids (Coleoptera, Anobidae) were obtained by window and light traps. The most common Anobiidae-species were Hadrobregmus confusus (Kraatz) 60.3%, Hadrobregmus pertinax ...
H Viitanen, M Pulkkinen


The effect of pretreatments on the impregnation of air-dried sawn Belgian spruce
1988 - IRG/WP 3490
In general the impregnation of airdried spruce results in a variable treatment and limited penetration. This is the result of pit aspiration that occurs during drying of the spruce sapwood and heartwood. Spruce timber is becoming of greater importance in Belgium and hence research for better treatment of this vulnerable wood species is needed. Squared airdried timber of different dimensions were e...
J Van Acker, M Stevens


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


The effect of preservative distribution in small blocks of Pinus sylvestris on the toxicity of tributyltin oxide to Reticulitermes santonensis Feytaud
1971 - IRG/WP 206
Small blocks of Pinus sylvestris (50x25x15 mm³) were treated by a full-cell method with various concentrations of tributyltin oxide in benzene. Replicate blocks were then freeze dried, rapidly air dried or slowly air dried and exposed to surface attack by the subterranean moistwood termite Reticulitermes santonensis Feytaud. At all concentrations it was found that the freeze-dried blocks were mor...
M P Levi, D N R Smith


Natural durability transfer from sawmill residues of white cypress (Callitris glaucophylla). - Part 4: Analysis of extracts and treated wood for active components
2000 - IRG/WP 00-20215
In order to facilitate the commercial implementation of a large project aimed at recovering 'waste' durability components from sawmill residues of Callitris glaucophylla, it has been essential to develop analytical methodology for the important bioactive components of the heartwood extract. This methodology will be used 1) to standardise the activity of successive production batc...
Hui Jiang, M J Kennedy, L M Stephens


Fungal colonisation of the keelson and associated structures of a nineteenth century wooden frigate: Concepts of community structure and development
1994 - IRG/WP 94-10072
The early stages of microbial colonization and succession of wooden surfaces exposed to the sea have been extensively studied as have the community structures of archaeological timbers subjected to submergence and then retrieval from the sea. The frigate UNICORN, a largely intact 19th century wooden ship based in Dundee, Scotland, provides the microbial ecologist with a unique opportunity to study...
N A White, J W Palfreyman, G M Smith


A preliminary comparison of GC, HPLC and ELISA analysis of resin acids in pulp mill effluents
1997 - IRG/WP 97-20120
Resin acids are naturally occurring diterpenoid carboxylic acids present in most Canadian softwoods. There are eight common resin acids that are classified into two groups; the abietanes and the pimaranes. During processing of wood products they can be released into the environment where they are of concern because of their acute toxicity toward fish and other aquatic life. Traditionally resin aci...
A N Serreqi, K Stark, Xiumei Feng, J N Saddler, C Breuil


Detection of wood decay fungi in wood using a PCR-based analysis
1998 - IRG/WP 98-10279
We have developed a DNA-based assay to reliably detect brown rot and white rot fungi in wood at different stages of decay. DNA, isolated by a series of CTAB and organic extractions, was amplified by the polymerase chain reaction using published universal primers and basidiomycete-specific primers derived from ribosomal DNA sequences. We have surveyed 7 species of brown rot fungi, 7 species of whit...
C Jasalavich, A Ostrofsky, J Jellison


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


Surface retentions of PCP, TCMTB and MTC obtained during a field trial of antisapstain formulations
1993 - IRG/WP 93-20002
Formulations containing NaPCP or TCMTB and MTC were included as reference products in a recent field trial of antisapstain formulations in Queensland. Retentions of these actives on the surface of treated sawn Pinus elliottii were monitored by ultrasonic solvent extraction of excised samples and analytical determination by high performance liquid chromatography. Distribution of actives with depth ...
D E Ferlazzo, M D Needham, M J Kennedy


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Tributyltin compounds in wood preservation: Health and safety aspects
1986 - IRG/WP 3396
The toxicity of organotin compounds of the general formula RnSnX(4-n) depends strongly on the type of organic substituent R and on the degree of substitution n. The residues X, not bound through a tin-carbon bond, are however of much smaller influence. Furthermore, there is evidence that hydrolysis of tributyltin esters will occur under environmental as well as under physiological conditions to TB...
H Schweinfurth, P Günzel, H A B Landsiedel, R Lang, R Reimann, C Schöbel, F Siegmund


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