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Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Aesthetic changes of coated thermally modified wood after artificial weathering
2017 - IRG/WP 17-40819
The thermal modification process affects the chemical configuration of the wood matrix improving some physical properties and durability. In addition, the distinctive dark tones of thermally modified timber increase the economic value of several light-coloured species. However, heat-treatment alters the substrates and it could influence in the application of coating products, necessaries to mainta...
R Herrera, J Sandak, E Robles, J Labidi


Long-time efficacy of some soil termiticides tested according to “Modified Ground Board Test”
2018 - IRG/WP 18-10935
Field trials of efficacy of soil termiticides available in Thailand were started back in the 1980s at four different locations representing different unique weather types of the country. The method used in the trials (Modified Ground Board Test) is the compulsory test for every soil termiticides aiming to be registered for termite control in Thailand. The ongoing record reveals that some particula...
C Vongkaluang, K Charoenkrung, N Same Rain


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo


The Study of the Preparation of Overlaid MDF with the Flame Retardant Impregnated Paper
2018 - IRG/WP 18-40848
The preparation of overlaid medium density fiberboard (MDF) was studied. The flame retardant impregnated papers (FRIP) were overlaid on the surface of the MDF for the fire protection. The results showed that: 1) The production of the FRIP was based on the technology of melamine-impregnated paper, which required the viscosity of the impregnated resin lower than 20s. However, with the addition of th...
W Qu, M Wu, Y-Z Wu


Hydroxyl accessibility - A brief review of deuterium exchange studies on modified wood
2019 - IRG/WP 19-20656
Wood modification imparts dimensional stability and decay resistance. The mechanism(s) by which this occurs are thought to be related to the bulking of the wood cell wall and subsequent moisture exclusion. Hence, quantification of accessible hydroxyl (OH) groups is of great interest when evaluating and increasing the understanding of the performance of modified wood. The aim of this study was to b...
G Beck, C Hill, G Alfredsen


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


Durability classification of preservative treated and modified wood
2019 - IRG/WP 19-20659
EN 350 (2016) allows formally to determine durability classes (DC) for wood products and wood-based materials, which was previously only possible for untreated wood in the form of natural durability. In a first study, the University of Goettingen carried out the durability classification of chemically modified (modified with 1,3-dimethylol-4,5-dihydroxyethyleneurea, DMDHEU) and preservative-treate...
S Bollmus, L Bachle, C Brischke, H Militz


Performance of modified wood in service - multi-sensor data fusion and its multi-way analysis
2019 - IRG/WP 19-20660
Recent developments in the field of electronic sensors and analytics provide new opportunity for accurate characterization of materials often based on portable and non-destructive methods. By using several complementary techniques, the material description is precise and complete. The data provided by multiple equipment, however, are often not directly comparable due to different resolution, sensi...
A Sandak, J Sandak, M Cocchi


Facile in-situ growth of Ag-TiO2 nanoparticles on polydopamine modified bamboo with excellent mildew-proofing
2019 - IRG/WP 19-30734
Bamboo with good mechanical properties, fast growth rate and low growth cost is one of very utilitarian structural material from forest resources only less important than wood. But it is especially easy to mildew during outdoor service resulting in appearance mould scattering and corrosion. In this work, a facile method was developed to increased mildew-proofinging capability of bamboo. Mussel-ins...
J Hu, Z Lu, G Liu, S Chang, Y Liu, X Li


Use of resin obtained from Italian guayule crops for wood preservation purposes: some preliminary results
2019 - IRG/WP 19-30736
The potential of guayule (Partenium argentatum Gray) as a source of anti-termite, anti-fungal and insect repellent products to be used in wood preservation, has been largely explored in the past. The fact that such products are obtained as byproducts in the process of natural rubber extraction from this plant, thus increasing the profit of the process, together with the ability of this crop to gr...
S Palanti, E Conti, M Russo, F Stefani, C Querci


Biosourced hybrid phenolic resins as coatings for the protection of wood and wood composites
2019 - IRG/WP 19-30745
Biosourced phenolic resins, based on the phenol-formaldheyde (PF) type, were prepared for their application as coating for wood and wood composites protection, especially against fire. The resins were synthesized by combining an organic polymeric matrix with another inorganic phase. The organic phase was prepared substituting phenol by natural phenolic compounds such as lignin and tannins. The ino...
P L de Hoyos-Martínez, R Herrera, J Labid, F Charrier El Bouhtoury


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


The anti-weathering mechanism of extractives in thermally modified Scots pine
2019 - IRG/WP 19-40880
Results from the electron spin-resonance spectroscopy (ESR) analysis indicated that thermally modification of wood can inhibit the generation of phenoxyl radicals during UV irradiation and consequently lead to the increase of the color stability of wood. In order to clarify the evolution and role of extractives in thermally modified wood during the process of weathering, the compositions of aceton...
H Shen, J Cao


Penetration pathway of oilborne preservative in heartwood of Japanese larch (Larix kaempferi)
2019 - IRG/WP 19-40886
The liquid permeability of Japanese larch (Larix kaempferi) wood is extremely low, especially in the heartwood. It is difficult to achieve the penetration of wood preservatives, which is specified by standards, with pressure treatment of waterborne preservatives. Recently, the protection treatment with an oilborne preservative called “deeper penetration treatment” is commercially available, wh...
H Shibui, T Miyauchi, T Shigeyama, M Ikeda, Y Sugai


Studying amount, location and state of water in modified wood at moisture levels relevant for fungal degradation
2020 - IRG/WP 20-40889
Water is an essential parameter for fungal degradation of wood, but degradation primarily occurs at high moisture levels at water potential in the range of -4 to -0.1 MPa, which corresponds to 97-99.9% relative humidity. At these moisture levels, water is present in the wood structure both in and outside of cell walls. The majority of previous studies on the interaction between wood and water for ...
M Fredriksson, E Engelund Thybring, Ramunas Digaitis


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


Evaluation of chemical densification of three hardwood species through in-situ electron beam polymerization
2020 - IRG/WP 20-40893
Hardwoods are the most suitable species for wood flooring for their appearance as well as their hardness. Yet, improving hardness can provide substantial benefit for the wood flooring market. Chemical densification of wood and in-situ polymerization through electron beam technology was chosen to increase hardness of three hardwoods (Yellow birch (YB) (Betula alleghaniensis Britt.), Sugar maple (SM...
J Triquet, P Blanchet, V Landry


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Development of procedures for sampling, testing, and classification to determine the biological durability of wood and wood products
2020 - IRG/WP 20-20676
This paper informs about a research project, which deals with several shortcomings and a lack of clarity within EN 350:2016. The project started in January 2020, will run for 3 years, and is operated by the Institute of Wood Technology Dresden (IHD) and the University of Goettingen (UGOE). Determination and classification of durability of wood and wood products against wood-destroying organisms ...
W Scheiding, K Jacobs, S Bollmus, C Brischke


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