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Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


Tensile stress relaxation of wood impregnated in different ACQ formulations at various temperatures
2009 - IRG/WP 09-40456
The reactions between ammoniacal copper quat (ACQ) constituents and wood components were investigated by tensile stress relaxation approach. Small wood samples were stressed and impregnated in ACQ solutions with different formulation including the ethanolamine (MEA) to copper molar ratio, copper (as copper oxide) to quat (as DDAC) weight basis, treatment temperature and also the solution concentra...
Lili Yu, Jinzhen Cao


Barefoot-heat-impact of oil-heat-treated wood: An important thermal property of decking boards
2009 - IRG/WP 09-40458
In this study the phenomenon of sensual heat impression was examined, when walking with bare feet on sun exposed wood based decking boards. A suitable method for measuring the heat flux from decking boards into an artificial foot was developed. The method and measuring device is described as well as results from measuring three different decking board materials: Oil-heat-treated spruce (OHT), untr...
A O Rapp, C R Welzbacher, C Brischke


Biological Performance of Boron-based Chemicals Treated Wood Composites
2009 - IRG/WP 09-40464
In this study, the biological performance of wood-based composites panels treated with boron containing chemicals against to a fungus was determined. Boric acid, borax, zinc borate and agricultural borate (Tarım-bor™), developed and patented by National Boron Research Institute, were mixed with wood chips or fibers and then particleboard, medium strand board and middle density fiberboar...
Ü C Yıldız, H Kalaycıoğlu, S Yıldız, A Temiz, E Tomak Dizman, A Çavdar Dönmez


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Toward an assessment of copper bioavailability in treated wood
2010 - IRG/WP 10-20445
Many modern wood preservative systems rely on copper (Cu). Some oxalate-producing fungi detoxify Cu by immobilizing it in crystals, and this may decrease its physiological availability (bioavailability). Cu bioavailability may also decrease during wood treatment. Cu retention in wood, however, is typically measured as a weight-to-volume concentration without an estimate of its bioavailability and ...
J S Schilling, J J Inda


Mould growth on wood-based materials – a comparative study
2010 - IRG/WP 10-20455
Ten different wood-based materials - preservative-treated wood, fire retardant-treated wood, modified wood, WPCs and untreated references of pine sapwood and spruce - were tested for mould growth according to SP method 2899 during 42 days at 90% RH and 22°C. Even though the results must be interpreted carefully, they indicate significant differences in mould resistance between the materials tes...
P Johansson, J Jermer


The use of thermal desorption and pyrolysis combined with a semiconductor VOC detector for the on-site detection of preservative-treated wood
2010 - IRG/WP 10-20456
The purpose of this study was twofold; to identify possible marker molecules released from preservative-treated wood upon heat treatment and then develop a prototype detector for this marker. Two methods for heating the samples were used: Pyrolysis combined with Gas-Chromatography with IR-detection and Thermal Desorption combined with Gas-Chromatography with mass detection. A first prototype detec...
I Svensson, A Gonzalez, L Irusta, Mª J Fernandez-Berridi, O Munné


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Biological performance of wood treated with tar-oil recovered during slow pyrolysis of macadamia nut shells
2010 - IRG/WP 10-30523
This study evaluated decay and termite resistance of wood treated with tar oil obtained from a commercial pyrolysis process of macadamia nut shells. Vacuum-treated pine wood specimens were subjected to various brown and white rot fungi based on the soil-block test method specified by the American Wood Protection Association (AWPA) after leaching process. Treated specimens were also subjected to th...
S Nami Kartal, E Terzi, C Kose, J Hofmeyr, Y Imamura


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Accelerated L-joint performance testing of organosilicon treated wood
2010 - IRG/WP 10-30551
In this research Scots pine sapwood L-joints were treated with organosilicons and organosilicons in combination with biocides. These L-joints were prepared and exposed according to the accelerated L-joint method. They were inspected each season for fungal discolouration and removed from the rack after three years outdoor exposure. Subsequently the moisture content, mass loss and decaline uptake we...
L De Vetter, J Van Acker


The Effects of Natural Weathering on the Properties of Heat Treated Alder Wood
2010 - IRG/WP 10-40484
Heat treatment is an effective method to improve the dimensional stability and biological durability of wood. The heat treatment technology and the heat treated wood products were recently introduced to Turkey. However, only a few studies have been reported on the effect of natural weathering on the properties of heat treated wood in both Turkey and the world. In this study, heat treated alder (Al...
S Yildiz, Ü C Yildiz, E D Tomak


Development of markers to predict decay durability of heat treated wood
2010 - IRG/WP 10-40496
Effect of heat treatment temperature on elemental composition of Scots pine sapwood (Pinus sylvestris) has been investigated in the range of temperatures between 220 and 250°C. Results revealed an important increase of carbon content, while oxygen content significantly decreases. Independently of the heat treatment temperature, elemental composition is strongly correlated with the mass losses due...
Ž Šušteršic, A Mohareb, M Chaouch, M Pétrissans, M Petric, P Gérardin


An investigation on some physical properties of oil heat treated poplar wood
2010 - IRG/WP 10-40509
In this study some physical properties of small samples (20×20×20 cm) of poplar wood (Populus nigra var.pyramidalis) after oil heat treatment with linseed oil was investigated. Two time levels (4.5 & 6 hours) and three temperature stages (180,200 & 220°C) were selected. The results of this study showed significant differences in effects of treatment temperature on physical properties of wood....
B Bazyar, D Parsapajouh, H Khademiesalam


Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim


Climate change and wood protection, increasing demand of long life wood products and decreasing production of treated wood
2010 - IRG/WP 10-50269
Several new topics related to wood protection sector has appeared in Japan, as the awareness of climate change becomes bigger and bigger. The “Basic act for housing (2006)” and the “Long-life housing promotion act (2009)” were enforced to form a safe and high quality housing stock and to form a long-service-life housing respectively. Despite of the favorable background for wood protection ...
K Yamamoto, H Kato


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