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Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Using an accelerated laboratory method to evaluate Aureobasidium pullulans colonization on painted surfaces and underlying wood substrate
2012 - IRG/WP 12-20480
Mold growth on painted surfaces can lead to premature paint film failure and is unsightly. Aureobasidium pullulans has been identified as a major cause of black stain on surfaces painted with acrylic or latex paints. In this study, an accelerated laboratory method developed by Zabel and Horner (1981) was used with modifications to the type of agar used and sample evaluation methods. A study was ...
C Schauwecker, L Burns, A Preston


Testing service life for use class 3: accelerated L-joint performance of commodities
2012 - IRG/WP 12-20500
Above ground testing is considered important for the assessment of treated wood intended for use class 3. Laboratory testing of efficacy of biocides as well as of natural durability focussing on such applications has to be linked to performance and service life. An accelerated L-joint test was some 15 years ago developed at the Ghent University to allow worst case assessment under semi-controlled ...
J Van Acker, J Van den Bulcke, I De Windt, L De Vetter


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Fixation and leaching characteristics of Malaysian tropical hardwoods treated with CCA-C
2012 - IRG/WP 12-50289
The fixation and leaching characteristics of 8 Malaysian tropical hardwood (MTH) species treated with chromated copper arsenate (CCA-C) wood preservative were examined. The species evaluated were Acacia (Acacia mangium), Bintangor (Calophyllum sp.), Geronggang (Cratoxylon arborescens), Medang (Litsea sp.), Meranti rambai daun (Shorea acuminata), Putat (Planchonia sp.), Ramin (Gonystylus sp.) and S...
S Salim, S Shahomlail, Z Ashaari, Yong-Seok Choi, Gyu-Hyeok Kim


Determination of the natural durability of solid wood against wood-destroying fungi - a European round-robin test
2013 - IRG/WP 13-20511
In Europe the durability of wood against wood-destroying basidiomycetes is tested according to CEN/TS 15083-1 (2005). Hitherto existing experience with this standard is quite heterogeneous and results from previous round-robin tests have stayed unreported or have been reported incompletely. In particular the need for natural pre-weathering of the test specimens to allow potential detoxification of...
C Brischke, C R Welzbacher, A Gellerich, S Bollmus, M Humar, K Plaschkies, W Scheiding, G Alfredsen, J Van Acker, I De Windt


Image analysis for mould and sapstain detection on wood
2013 - IRG/WP 13-20519
Laboratory tests for mould growth on wood products are time consuming and rely on visual assessments of specimens utilizing subjective rating systems. Accelerated laboratory methods are needed that can provide rapid, quantitative assessment of mould and sapstain growth on solid and composite wood products. Image analysis of scanned spore imprints from southern pine or oriented strandboard (OSB) sp...
C A Clausen, V W Yang


Accelerated H3 above-ground decay testing
2013 - IRG/WP 13-20520
An above-ground H3 fungal field trial was installed at two sites in Australia and one in New Zealand, as well as in two Accelerated Field Simulators. The aim was to find a method that would shorten the time required for evaluating new preservatives and protection systems. One-quarter H3 retentions were installed, as first results suitable for registration occur when these reach 70% soundness. Twel...
L J Cookson, D Page, T Singh


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


Colorimetric evaluation of three tropical woods after accelerated weathering
2014 - IRG/WP 14-20541
The use of wood in the furniture industry is directly associated with their physical, mechanical and organoleptic characteristics. The color of the wood is a major factor in the selection of forests species to employ in the furniture projects and is fundamental the maintenance of its colorimetric pigments over time. The objective of this study was to evaluate the colorimetric behaviour of three tr...
R Faustino Teles, A Florian da Costa


Selection of Wood-Rotting Basidiomycetes for Inoculation of an Accelerated Soil Bed Test
2014 - IRG/WP 14-20543
There is a need for a test method that guarantees exposure of treated wood to soil and preservative-tolerant wood-rotting basidiomycetes as standard field tests do not do this reliably. The ability of a range of selected wood-rotting basidiomycetes to grow through unsterile forest soil was investigated in a Mason jar test assembly. None of the white-rot fungi in test grew through this soil. Fou...
P I Morris, A Uzunovic, J Ingram


The development of accelerated test systems to evaluate the durability of framing timber
2014 - IRG /WP 14-20547
Various accelerated decay resistance trials including small simulated wall units, samples exposed in enclosed tanks and ‘I’ samples in stacks have been explored and used to test the durability of treated and untreated radiata pine framing at Scion since 2001. These testing methods have been established to determine the effectiveness of commercial formulations in preventing decay in framing sub...
T Singh, D Page, J van der Waals


A screening of factors that might influence the result of laboratory decay tests
2014 - IRG/WP 14-20548
Laboratory fungal decay tests provide important tools for performance testing of wood materials. But they are also hampered with some uncertainties regarding reproducibility. In addition to variation between fungal species and strains the test conditions are also believed to have some influence. The aim of this study was to screen the effect of a selection of test parameters that might influence t...
E Larnøy, G Alfredsen, A Treu, S Kolstad


Fire resistance of wood treated with potassium carbonate and silanes
2014 - IRG/WP 14-30657
This paper reports on the effect that organosilicon compounds and potassium carbonate and urea (PCU) have on wood flammability. The study focus on reducing wood flammability by promoting char formation through manipulation of the condensed phase decomposition chemistry. Potassium carbonate is known as an effective fire retardant, however it is easily leached out from wood and increases its hygrosc...
B Mazela, M Broda, W Perdoch


Copper and chromium leaching from wood impregnated with chromium-copper containing preservatives: Results of different studies
2014 - IRG/WP 14-50300
Copper and chromium based wood preservatives remained one of the most important ingredients for wood protection solutions for protection of wood in demanding applications all-over the world. Leaching of heavy metals from treated wood is important from two different aspects; firstly from performance point of view, and secondly from environmental issues. However, the importance of these studies is i...
M Humar, N Thaler, E Melcher


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