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A physiological role of the glyoxylate and TCA cycles in fruitbody formation of the coppertolerant brown-rot fungus Fomitopsis palustris
2002 - IRG/WP 02-10430
Changes in activity of the representative enzymes involved in biosynthesis of oxalic acid (oxalate) and carbon metabolism of glucose were investigated in relation to the fruit body formation of the copper-tolerant brown-rot fungus Fomitopsis palustris. Changes in specific activities of the two glyoxylate (GLOX) cycle key enzymes (isocitrate lyase (ICL) and malate synthase (MS)), the two oxalate-fo...
Jeong-Jun Yoon, T Hattori, M Shimada


The role of oxalic acid in short fiber formation by the brown-rot fungus Postia placenta
1993 - IRG/WP 93-10028
The mechanism by which brown-rot fungi depolymerize wood and cellulose remains a perplexing problem. Current evidence favors oxidation by low-molecular weight, non-enzymatic fungal metabolites. During attack of cotton cellulose by Postia placenta MAD-698, the degree of polymerization (DP) decreases to limit of degree of polymerization (LODP) over a period of 5-6 weeks with relatively low weight lo...
F Green III, J M Hackney, C A Clausen, M J Larsen, T L Highley


The role of oxalic acid in tolerance to N’N-naphthaloylhydroxylamine in Tyromyces palustris
2006 - IRG/WP 06-10584
Certain wood decay fungi exhibit tolerance to one or more wood preservatives. Copper tolerance of brown-rot fungi has been studied in our laboratory for the past six years. We have observed some degree of tolerance to N’N-naphthaloylhydroxamine (NHA), a recently patented termite bait, by the brown-rot fungus Tyromyces palustris TYP-6137. In an effort to try and confirm this tolerance in other is...
R A Arango, C A Clausen, F Green III


Qualitative and quantitative assessment of chemicals used for wood durability improvement by Near Infrared Spectroscopy
2006 - IRG/WP 06-20349
The Near infrared spectroscopy (NIRS) could be a suitable technique to assess chemicals used for wood durability improvement in the forest products industry. NIRS methodology can be used to obtain results more quickly, less costly and without damaging the wood. In this study, wood samples selected from heartwood and sapwood of Maritime Pine (Pinus pinaster) were prepared to assess the artificial d...
S Zahri, F Charrier, H Baillères, B Charrier


Water analysis in chemicals, wood or chemically treated wood using a new analytical method for selective water detection
2006 - IRG/WP 03-30391
Water or moisture content analysis can be a challenging task in many applications. However, knowing accurately the type of water which can be found in a given sample or product can provide important information about a chemical compound used for wood treatment and especially about the treated wood sample. Moisture content in wood plays an important role in fungal growth and it needs to be extensi...
R Craciun, D Taylor


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


Performance evaluation of Borax: Boric Acid treated Green bamboo through new VAC-FRI and conventional processes
2006 - IRG/WP 06-40327
Amongst giant arborescent grass bamboo is the only versatile member containing lignocellulosic materials like wood. Therefore it offers almost parallel uses where wood is traditionally an established material. The wood scarcity, environmental role of our natural forests, longer rotation cycle of plantation species, ban in felling, the ever growing utilization demands of wood to the tune of 3.2 mil...
S Tripathi, S N Nautiyal


The Effect of Wick Action upon Moisture Distribution in Ellagate Treated Pinus radiata Wood
2006 - IRG/WP 06-40328
Sapwood stakes of Pinus radiata D. Don were treated with water-soluble tetraguanidinium, tetracholine and tetrakis-benzyltrimethylammonium ellagates. The effect of these treatments upon moisture distribution was investigated by wick action. Given that chemical reactions within the wood substrate between nutrients and treatment solutions may alter the properties of the wood with regard to moistur...
S R Przewloka, B J Shearer, J A Hann


Protection of wood for above ground application through modification with a fatty acid modified N-methylol/paraffin formulation
2007 - IRG/WP 07-40378
Hydrophobic chemical modification can be regarded as an alternative approach to conventional wood preservation using biocides in order to protect wood in hazard class 3 according the European Standard EN 335-1. A formulation containing fatty acid modified N-methylol/paraffin and an aluminium salt catalyst was used to change the material properties of wood in order to protect wood from fungal dec...
Nguyen Hong Minh, H Militz, C Mai


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating. Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi


Investigation into the antifungal properties of herbal remedies for potential use in the wood preservation industry
2008 - IRG/WP 08-30462
The efficacy of herbal remedies as potential antifungal agents was evaluated against two sapstain and three decay fungi. Sapstain fungi included Sphaeropsis sapinea, and Leptographium procerum, and decay fungi were Oligoporus placenta, Coniophora puteana, and Schizophyllum commune. Out of six herbal remedies tested, three showed moderate to high antifungal activity. Caprylic acid had high antif...
D O’Callahan


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Preservative treatment of strips of Bambusa balcooa by soaking process using Borax-Boric acid
2008 - IRG/WP 08-30478
Bamboo strips made from Borak bamboo (Bambusa balcooa) were treated with 10% borax-boric acid aqueous solution by soaking process. The moisture contents of the bamboo strips were 12%, 20% and 30%. The strips were soaked for one, two, three, four and five days. The penetration of the solution was investigated by colour test after soaking and drying. Full penetration was observed after three days ...
K Akhter, M W Sheikh, M M Rahman, T A Chowdhury, M H Chowdhury


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Multifactorial Antimicrobial Wood Protectants
2008 - IRG/WP 08-30484
It is unlikely that a single antimicrobial compound, whether synthetic or natural, will provide the ‘magic bullet’ for eliminating multiple biological agents affecting wood products. Development of synergistic combinations of selected compounds, especially those derived from natural sources, is recognized as a promising approach to improved wood protection. Recent adoption of effective fungici...
R D Coleman, C A Clausen


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Laboratory and above ground exposure efficacy of silicon-boron treatments
2009 - IRG/WP 09-30510
The study deals with silicon compounds, namely tetraethoxysilane (TEOS), phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) at concentrations of 23, 16 and 10% in combination with 1.2-1.5% boric acid. The aim with the study was to combine the chemical approach with the necessary biological tests of the impregnated wood. The tested silicon-boron combinations ensured mass loss less than ...
N Terziev, D Panov, A Temiz, S Palanti, E Feci, G Daniel


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Chemical mediated depolymerization of cotton cellulose for the understanding of non-enzymatic fungal decay
2010 - IRG/WP 10-10731
Small, low molecular weight non-enzymatic compounds have been linked to the early stages of brown rot decay as the enzymes involved with holocellulose degradation are found to be too large to penetrate the S3 layer of intact wood cells. The most pronounced of these which were analyzed in this study are hydrogen peroxide, iron, and oxalic. The compounds related to the Fenton reaction: the combinati...
A C Steenkjær Hastrup, B Jensen, F Green III


Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury


Antifungal and wood preservative efficacy of IPBC is enhanced by α - aminoisobutyric acid
2010 - IRG/WP 10-30544
There is currently a need to reduce the biocide content of wood preservatives, without decreasing efficacy. The nonmetabolised amino acid analogue α-aminoisobutyric acid (AIB) acts as a translocated inhibitor of mycelial spread in basidiomycete wood decay fungi, although it does not kill the organism. Factorial combinations of AIB with either the azole fungicide tebuconazole, or 3-iodo-2-...
P Bota, E Baines, A Mead, S C Watkinson


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


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