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Effect of 4 Preservatives on Physical, Mechanical and Mold-Resistant Properties of Bamboo Oriented Strand Boards
2010 - IRG/WP 10-40483
This study investigated the effects of 4 preservative systems on physical, mechanical and mold-resistant properties of bamboo oriented strand board (OSB) panels bonded with urea formaldehyde resin. Preservative A (Zinc Borate), B (IPBC), C (AAC+Borate) and D (carbendazim + prochloraz) were incorporated with strands during blending at three loading levels. The results showed that the mechanical and...
Juwan Jin, Daochun Qin, Wanshu Wei, Kuan Fan


Chemical protection of historic timber structures: Results and future needs
2010 - IRG/WP 10-40487
The paper concentrates on the analysis of the effectiveness of chemical protection for timber structures in the Russian State Museums “Kizhi” (Karelia) and “Vitoslavlitsy” (Novgorod). The condition of historic timber was tested at the monuments treated with PCP, borax, potassium carbonate, boric acid, Pinotex chemicals in the 1970-80. Long-term analysis revealed that in many cases the...
M Kisternaya, V Kozlov


Reconstruction and Restoration of some Zagreb’s Wooden Heritage buildings
2010 - IRG/WP 10-40498
In the last ten years, the huge amount of wooden buildings houses and objects of Zagreb’s cultural heritage were restored with fine workmanship. As the wood was one of the most used construction materials, the scientists and specialists from the Faculty of Forestry also took part in those restoration and reconstruction processes. The aim of this article is to inform and advice the restorers on t...
R Despot, M Hasan


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick


Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


Gene expression analysis of a copper-tolerant brown rot fungus on MCQ-treated wood
2011 - IRG/WP 11-10748
Most brown rot fungi are copper-tolerant, which makes them difficult to control with copper-based wood preservatives like MCQ. To better understand what biological processes are regulated, we used our model species, Antrodia radiculosa, to examine expression of genes on MCQ-treated wood. Our hypothesis was genes that decreased copper bioavailability would be up-regulated early, when wood showed ...
J D Tang, A Perkins, S V Diehl


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The potential for using CuO nanoparticles as a wood preservative
2011 - IRG/WP 11-30569
The potential for using nano-copper particles for wood protection was investigated using mini-agar slant and wood block tests with Gloeophyllum trabeum or Trametes versicolor. Nano-copper was more effective against G. trabeum than T. versicolor, although neither of these fungi would be considered copper tolerant. Nano-copper solutions were stable over a 17 week storage period, but precipitated w...
I S Weitz, K Knani, M Maoz, C Freitag, J J Morrell


The study of fungicidal values und sorption processes of ionic liquids- potential wood preservatives on soils
2011 - IRG/WP 11-30572
In the paper, the fungicidal activity of new ionic liquids structures, N,N-dimethylalkylamines derivatives, containing a spacer built of 7 or 10 methylene groups with nitrate(V) and tetrafluoroborate anions, didecyldimethylammonium and benzalkonium nitrate(V) were presented. The research was also conducted on the sorption of cations of ammonium ionic liquids on five types of podzolic, humic alluvi...
W Przybylska, J Zabielska-Matejuk, A Stangierska, A Skrzypczak


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Performance of Creosote/Chlorothalonil Preservatives
2011 - IRG/WP 11-30580
The addition of chlorothalonil to P2 creosote was found to increase the durability of southern pine in a series of ground contact stake tests. At retentions lower than those specified in the AWPA Standards, performance was increased when the creosote was amended with chlorothalonil. This indicates that lower creosote retentions may be required for as good or better ground contact when the amende...
H M Barnes, M G Sanders, G B Lindsey, T L Amburgey


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


The Technical Criteria on Biological Evaluation of Wood Preservatives for Use Category C4.1 in Southern China
2012 - IRG/WP 12-20481
According to the Regulations on Pesticide management of the People's Republic of China, wood preservatives belong to agrochemicals. The establishment of registration system on wood preservatives would be benefit to management of preservatives, including the market entrance and safety insurance to the human beings, livestock and the environment associated by the application of these preservati...
Xingxia Ma, Mingliang Jiang


Determination of Izod Impact Strength on Wood: A Suitable Method to Detect Fungal Decay in Protective Effectiveness-Screenings of Wood Preservatives
2012 - IRG/WP 12-20484
For testing a large number of different substances regarding fungicide properties, the reduction of the decay test duration is advantageous. In the present paper the suitability of a method for testing plastics using an impact testing machine was examined. The results clearly show that the fungal attack of European beech by the white-rot fungus Trametes versicolor leads to a decrease of izod imp...
H Delenk, M Zauer, A Wagenführ


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


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