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Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Microdistribution of Copper in Copper-Ethanolamine (Cu-EA) Treated Southern Yellow Pine (Pinus spp.) related to density distribution
2004 - IRG/WP 04-40270
The relationship between copper absorption and density distribution in wood cell walls was investigated in this study. The density distribution on layer level was obtained from two approaches: (1) calculation by using data obtained from literature; (2) microdistribution of carbon and oxygen atoms in the wood cell. The microdistribution of carbon and oxygen in untreated southern yellow pine (Pinus ...
Jinzhen Cao, D P Kamdem, E Pasek


CCFZ, a new type of water-borne wood preservative for vacuum pressure impregnation
1991 - IRG/WP 3643
By combination of CCF-Salt types with zinchexafluorosilicate a remarkable improvement of efficacy is achieved. In the same time the ecotoxicoligical data become more save. As well as the efficacy against wood-destroying organisms (Basidiomycetes, Soft rot and Long horn beetle) the basic data to evaluate the ecotoxicological behaviour of a CCFZ-Salt are described and compared with the properties of...
W Metzner, D Seepe, H-W Wegen


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


Determination of bis-(N-cyclohexyl-diazeniumdioxy)-copper in different matrices by photometer, thermal energy analyzer and HPLC
1999 - IRG/WP 99-20179
For the quantitative analysis of bis (N-cyclohexyl-diazeniumdioxy)-copper (Cu-HDO) three analytical methods are used. The employment of the different methods depends on the matrices involved. For several years now, the colorimetric determination of Cu-HDO by photometer has been applied to solutions and concentrates of wood preservatives. In principle, the technique consists of a quantitative conve...
J Wittenzellner, W Hettler, M Maier


Working plan: Second international collaborative field trial
1995 - IRG/WP 95-20056
This paper describes the scope, objectives, and approaches to be used in the second international collaborative field trial approved by the Scientific Programme Committee for partial funding in 1994. The trial is designed to develop a broad data base on causal mechanisms, interactions, and factor affecting the performance of treated wood in ground contact. The trial encompasses 12 different field ...
H M Barnes, T L Amburgey


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


A comparison of the leaching resistance of copper 2-ethanolamine and copper ethylenediamine treated Scots pine
2000 - IRG/WP 00-30233
The depletion of copper from copper 2-ethanolamine and copper ethylenediamine treated Scots pine blocks was investigated. A greater leaching resistance was found for copper 2-ethanolamine, which retained ca. 86% and ca. 50% copper after water and buffer leaching, respectively. Leached amine treated blocks also contained significant residual amine. This was consistent with other observations linked...
Xiao Jiang, J N R Ruddick


Comments on soft rot attack in timbers treated with CCA preservatives: A document for discussion
1982 - IRG/WP 1167
This paper is not based on any particular results but rather on several observations of soft-rot during many years of studies, and on a review of the existing literature. The short time available has unfortunately not permitted a detailed review of the literature. Data and knowledge of important facts are lacking for several aspects of soft-rot attack and for reactions occurring in the wood as a r...
T Nilsson


Some fundamental thoughts on the prediction of field performance from lab-testing based on comparison of lab and field test results of some copper-free materials
2003 - IRG/WP 03-20269
In the paper results from lab testing (ENV 807 and EN 113) are compared with field results (EN 252) of differently treated wood. Depending on the type of the organic biocide containing material and depending on type of soil and type of decay differences were found in suitability of the lab methods to predict field performance. The attempt is made to interpret the found differences. Furthermore it ...
A O Rapp, U Augusta


Evaluation of the protective means of some wood preservatives by means of accelerated tests
1973 - IRG/WP 232
In site conditions of the eastern site in the forest-steppe part of the Krasnovarsk region, the relative effectiveness of a series of wood preservatives was obtained by means of field tests. To obtain a more accurate evaluation of the protective qualities of these accelerated tests were carried out in laboratory conditions. In 9 boxes filled with non-sterile soil taken from the site, 72 samples of...
I A Petrenko


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


Biological resistance of electrolessly plated wood (1). Preliminary report
1994 - IRG/WP 94-40024
Surface metal coating is considered to improve biological resistance of wood as some metal ions are fungitoxic. Six wood species (three softwoods: Cryptomeria japonica, Tsuga heterophylla and Larix spp; three hardwoods: Fagus crenata, Acer mono and Betula platyphylla) were electrolessly plated with nickel or copper, and those were served for laboratory evaluation of their resistance against decay ...
M Hasegawa, K Tsunoda, T Yoshimura


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Recycling and disposal of timber treated with waterborne copper based preservatives
1993 - IRG/WP 93-50008
Recycling and disposal technologies are briefly reviewed. Details are given of chemical extraction techniques suitable for recovery of copper from timber treated with a new copper based preservative, and traditional chromium based products. Details of thermal decomposition tests according to the DIN 53436 protocol under flaming and non-flaming conditions are given. The decomposition products were ...
J A Cornfield, S Vollam, P Fardell


An appraisal of anti-sapstain chemicals in Queensland, Australia
1985 - IRG/WP 3331
Eleven formulations were tested in the field for effectiveness against sapstain, mould and fungi on Pinus elliottii in Queensland. The commercially used sodium pentachlorophenoxide (0.5% a.i.) and Captafol (0.2% a.i.) performed well. Busan 1009 (0.3% a.i.), Protek T (5.0% a.i.), Woodgard E.S. and E.C. (0.8% a.i.), together with sodium tetrachlorophenoxide (0.5% a.i.) offer potential as anti-sapsta...
L E Leightley


Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


Modelling of copper emission fron treated wood leached according to NEN 7345 and ENV 1250.2
1996 - IRG/WP 96-20097
A series of water leaching experiments is carried out investigating pine and spruce treated and fixed using different copper-containing preservative solutions and process technologies. Water changes took place as prescribed in the Dutch standard NEN 7345 and the European test method ENV 1250.2, each of the leachates being chemically analysed for their copper content. Irrespective of the preservati...
G M F Van Eetvelde, S G L Michon, M Stevens


Preservatives stains as exterior wood finishes
1977 - IRG/WP 389
For many years wood preservatives and paints have been used as the only treatment for exposed wood surfaces. Because of the inherent color of the preservatives, such as creosote, the wood surface was stained as well as protected from attack by micro-organisms. Paints protect surfaces from weathering, but recently, with an increased interest in maintaining the more natural appearance of exterior wo...
D W French


Inter-laboratory comparison of assessment methods for wood preservatives against subterranean termites: Determination of protection threshold limits for CCA
1999 - IRG/WP 99-10317
In 1996, several institutes conducted laboratory bioassays on the efficacy of unleached Pinus radiata specimens treated with copper-chromium-arsenic (CCA) and copper naphthenate (Cu Naph) at retentions of 0.5, 1.0, 2.0 and 4.0 kg/m3 (total salt for CCA; elemental copper for Cu Naph) against a range of species of subterranean termites (IRG/WP/96-10174). Each participant employed the standard test m...
J W Creffield, M Lenz


A field test on susceptibility of wood-based board materials to moulds
1989 - IRG/WP 3545
A field test on susceptibility of wood-based board materials to mould growth was carried out under practical, but severe, service-conditions. A total of 19 commercially available composite boards were investigated. It was found that all board materials tested were not completely immune to mould attack. Test results revealed that among the three main categories of wood-based boards involved, partic...
Qiao Wang, B Henningsson


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